MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PermaClean PC-99 REVERSE OSMOSIS CLEANER 03-Jan-02

PRODUCT NAME: APPLICATION: Date issued: COMPANY IDENTIFICATION

CHINA: INDIA: INDONESIA: KOREA: MALAYSIA: THE PHILIPPINES: SINGAPORE: THAILAND:

ONDEO NALCO SUZHOU (CHEMICAL) CO. LTD ONDEO NALCO CHEMICALS INDIA LTD PT NALCO PERKASA ONDEO NALCO KOREA LIMITED ONDEO NALCO (MALAYSIA) SDN BHD ONDEO NALCO (PHILIPPINES) INC. ONDEO NALCO PACIFIC PTE LTD ONDEO NALCO (THAILAND) LTD

TEL: 86-512-8255001 TEL: 91-33-2172066 TEL: 021-8753175 TEL: 82-2-789-6961 TEL: 6035569 4118 TEL: 063-49-5451550 TEL: 65-861-4011 TEL: 66-38-955-160

FAX: 86-512-8251030 FAX: 91-33-2296858 FAX: 021-8753167 FAX: 82-2-786-3140 FAX: 603-5569 5955 FAX: 063-49-5453442 FAX: 65-862 0850 FAX: 66-38-955-166

See Section 16 for address information. EMERGENCY TELEPHONE NUMBER : See section 16, for Emergency Telephone Numbers.

2.

COMPOSITION/INFORMATION ON INGREDIENTS
Potassium hydroxide, phosphate, organic acid derivative, water.

CHEMICAL DESCRIPTION:

Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). CHEMICAL NAME Tetrapotassium pyrophosphate Potassium hydroxide Other ingredients determined not to be hazardous, including water CAS NO 7320-34-5 1310-58-3 % (w/w) 5.0 - 10.0 5.0 - 10.0 balance

3.

HAZARDS IDENTIFICATION

HUMAN HEALTH HAZARDS - ACUTE EYE CONTACT Corrosive. Will cause eye burns and permanent tissue damage. SKIN CONTACT Corrosive; causes permanent skin damage. INGESTION Corrosive, causes burns to gastro-intestinal tract. Nausea, vomiting and stomach pain may occur. In severe cases blood may be vomited. INHALATION Corrosive to respiratory system. HUMAN HEALTH HAZARDS - CHRONIC 1/9

MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
No adverse effects expected other than those mentioned above.

4.

FIRST AID MEASURES

EYE CONTACT PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical attention. SKIN CONTACT PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get immediate medical attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use. INGESTION DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medical attention. INHALATION Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.

FIRE FIGHTING MEASURES

Not flammable

FLASH POINT :

EXTINGUISHING MEDIA Not expected to burn. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARDS Gives off hydrogen by reaction with metals. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING In case of fire, wear a full face positive -pressure self contained breathing apparatus and protective suit.

6.

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Spill may be slippery. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). 2/9

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PERMACLEAN PC-99

LAND SPILLS Keep public and other shipping traffic away. ENVIRONMENTAL PRECAUTIONS Do not contaminate surface water.

7.

HANDLING AND STORAGE

HANDLING Do not take internally. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Avoid generating aerosols and mists. Do not mix with acids. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Keep the containers closed when not in use. Ensure all containers are labelled. STORAGE CONDITIONS Store in suitable labelled containers. Store the containers tightly closed. Store separately from acids.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
Substance(s) POTASSIUM HYDROXIDE OCCUPATIONAL EXPOSURE LIMITS ACGIH/TLV Malaysia OSHA/PEL Philippines Singapore STEL (mg/m3) 2 (ceiling) 2 2 2 2 PEAK / CEILING (mg/m3)

ENGINEERING MEASURES General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapour. RESPIRATORY PROTECTION An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. If significant mists, vapours or aerosols are generated an approved respirator is recommended. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION Nitrile gloves, Rubber gloves, Butyl gloves, Neoprene gloves, PVC gloves. SKIN PROTECTION Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible. EYE PROTECTION Wear a face shield with chemical splash goggles. HYGIENE RECOMMENDATIONS Eye wash station and safety shower are necessary. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. 3/9

MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99

9.

PHYSICAL AND CHEMICAL PROPERTIES

Liquid Clear, colourless Mild Not flammable 1.09 Complete 14 -2.2 C 1(Air = 1)

PHYSICAL STATE APPEARANCE ODOUR FLASH POINT SPECIFIC GRAVITY SOLUBILITY IN WATER pH ( 100% ) MELTING POINT VAPOR DENSITY

Note: These physical properties are typical values for this product and are subject to change.

10.

STABILITY AND REACTIVITY

STABILITY Stable under normal conditions. HAZARDOUS POLYMERIZATION Hazardous polymerization will not occur. CONDITIONS TO AVOID Freezing temperatures. MATERIALS TO AVOID Gives off hydrogen by reaction with metals. Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapours. HAZARDOUS DECOMPOSITION PRODUCTS Under fire conditions: Oxides of phosphorus Oxides of carbon Oxides of nitrogen

11.

TOXICOLOGICAL INFORMATION

ACUTE TOXICITY DATA No toxicity studies have been conducted on this product. SENSITIZATION This product is not expected to be a sensitizer. CARCINOGENICITY None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

12.

ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS No toxicity studies have been conducted on this product.

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MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99

PERSISTENCY AND DEGRADATION Total Organic Carbon (TOC): 25300 mg/L

13.

DISPOSAL CONSIDERATIONS

Dispose of in accordance with local, state, and federal regulations. Triple rinse (or equivalent) all containers and offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities. NATIONAL REGULATIONS, CHINA Dispose of unused product in accordance with the Hazardous Wastes (Management and Handling) Rules 1989 and local and State legislation, as applicable. NATIONAL REGULATIONS, INDIA Dispose of unused product in accordance with the Hazardous Wastes (Management and Handling) Rules 1989 and local and State legislation, as applicable. NATIONAL REGULATIONS, INDONESIA Dispose of unused product in accordance with Government Regulation No.19/1994 On the Treatment of Dangerous And Toxic Waste (and amendments) as applicable. NATIONAL REGULATIONS, KOREA Waste disposal should comply with the Waste Control Act. NATIONAL REGULATIONS, MALAYSIA Dispose of in accordance with the Environmental Quality (Scheduled Wastes) Regulation 1989 and other guidelines issued by DOE and/or local authorities. NATIONAL REGULATIONS, PHILIPPINES Dispose of in accordance with Presidential Decree No. 984-1976 ("The Pollution Control Law"); DENR Department Administrative Order No.29-92 ("The Implementing Rules or Regulations of RA6969") and Presidential Decree No.825. NATIONAL REGULATIONS, SINGAPORE Dispose of waste in accordance with the Environmental Health Act (Chapter 95, Rg 11), Environmental Public Health (Toxic Industrial Waste) Regulations 1990 Ed. NATIONAL REGULATIONS, THAILAND Dispose of hazardous waste in accordance with the "The Notification of the Ministry of Industry No. 6B.E. 2450, subject : Disposal of Wastes or Unusable Materials ", "The Notification of the Ministry of Industry No. 1B.E. 2451, subject : Disposal of Wastes or Unusable Materials ".

14.

TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are: LAND TRANSPORT Proper Shipping Name UN/ID No

POTASSIUM HYDROXIDE SOLUTION UN 1814

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MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
Hazard Class - Primary Packing Group HAZCHEM CODE: NATIONAL REGULATIONS, CHINA Comply with local regulations. NATIONAL REGULATIONS, INDIA Transport in accordance with the Central Motor Vehicles Rules 1989. NATIONAL REGULATIONS, INDONESIA Transport in accordance with all government regulations, including "Regulation of the Minister of Health No.453/Man.Kes/PER/XI/1983 on Dangerous Substances", as applicable. NATIONAL REGULATIONS, KOREA Land transport should comply with the Ministerial Decree of Toxic Chemicals Control Law and the Regulations Regarding the Fire Fighting Techniques Standards, as applicable. NATIONAL REGULATIONS, MALAYSIA There are no regulations specifically governing the transport of chemicals. Use best practice. NATIONAL REGULATIONS, PHILIPPINES Transport in accordance with the following legislation (as applicable): Presidential Decree No. 1185, 1977 ("Fire Code of the Philippines") and implementing rules and regulations; Presidential Decree No. 856, 1975 ("Code of Sanitation"); Republic Act No 6969, 1990 ("Toxic Substances and Hazardous and Nuclear Wastes Control Act") and implementing rules and regulations. NATIONAL REGULATIONS, SINGAPORE Land Transport complies with the Environmental Pollution Control (Hazardous Substances) Regulations 1999, which follows the "Specification for Caution Labelling for Hazardous Substances" - Singapore Standard 286 (1984). NATIONAL REGULATIONS, THAILAND The product should be transported in accordance with "Hazardous Substances Acts B.E.2535", "Notification of Ministry of Public Health Re: Label and level of Toxicity of Dangerous Articles Which are Under the Responsibility of Food and Drug Administration 2534 (If applicable)" and "Notification of land transportation department, subject : label of truck which contain hazardous material, Notification date : 14 November B.E.2543 (14 November 2000)". AIR TRANSPORT (ICAO/IATA) Proper Shipping Name UN/ID No Hazard Class - Primary Packing Group IATA Cargo Packing Instructions IATA Cargo Aircraft Limit IATA Passenger Packing Instructions IATA Passenger Aircraft Limit MARINE TRANSPORT (IMDG/IMO) IMDG Page Proper Shipping Name UN/ID No Hazard Class - Primary Packing Group 8214 POTASSIUM HYDROXIDE SOLUTION UN 1814 8 II POTASSIUM HYDROXIDE SOLUTION UN 1814 8 II 813 30 L Y809 / 809 0.5 L / 1 L 8 II 2R

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MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
EmS-Nr. MFAG-Nr. 8-06 705

15.

REGULATORY INFORMATION

NATIONAL REGULATIONS, EUROPE AND MALAYSIA European: HAZARD SYMBOLS:

CLASSIFICATION:

CORROSIVE / C

Contains: POTASSIUM HYDROXIDE RISK PHRASES: R35 R41 Malaysian: HAZARD SYMBOLS: Causes severe burns. Risk of serious damage to eyes.

CLASSIFICATION:

CORROSIVE / C

Contains: POTASSIUM HYDROXIDE RISK PHRASES: R35 R41 Causes severe burns. Risk of serious damage to eyes.

SAFETY PHRASES: S26 S28 S36/37/39 S45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

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MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
INTERNATIONAL REGULATIONS : NFPA RATING HEALTH : 3 FLAMMABILITY : 0 REACTIVITY : 0 OTHER : 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme INTERNATIONAL CHEMICAL CONTROL LAWS: TOXIC SUBSTANCES CONTROL ACT (TSCA) The chemical substances in this product are on the TSCA 8(b) Inventory (40 CFR 710). EUROPE All substances in this product comply with the notification requirements of the European Commission Directive 67/548/EEC and amendments and are listed on the European Inventory of Existing Commercial Substances (EINECS). AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS) and are listed on the Australian Inventory of Chemical Substances (AICS). CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) All substances in this product are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL).

16.

OTHER INFORMATION

This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. ADDRESSES AND CONTACT POINTS: ONDEO NALCO SUZHOU (CHEMICAL) CO. LTD; 88 Ta Yuan Road, Suzhou New Development Zone, Jiangsu 215011 PRC Contact: Sam Chen, 86-512-8255001. ONDEO NALCO CHEMICALS INDIA LTD; 20/A Park St, Culcutta 700016 India. PT NALCO PERKASA; Jl Pahlawan Desa Karang Asem Timur. Citerup, Bogor. ONDEO NALCO KOREA LIMITED; 11th Fl, 63BLDG, 60, Yoido-dong Young Deung Po-Gu, Seoul, Korea. ONDEO NALCO (MALAYSIA) SDN BHD; 1 Jalan Jururancang U1/21, Section U1 Hicom-Glenmarie Industrial Park, 40150 Shah Alam, Selangor Darul Ehsan, Malaysia. ONDEO NALCO (PHILIPPINES) INC.; Barrio Real, Calamba, Laguna, Philippines. ONDEO NALCO PACIFIC PTE LTD; 21 Gul Lane, Jurong Town, Singapore 629416.

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MATERIAL SAFETY DATA SHEET PRODUCT

PERMACLEAN PC-99
ONDEO NALCO (THAILAND) LTD; Rayong Plant, 109/19 M00 4, Eastern Seaboard Industrial Estate, Soi ESIE 6, T. Pluakdaeng, A. Pluakdaeng Rayong 21140 Thailand. EMERGENCY TELEPHONE NUMBER: CHINA: KOREA: INDIA: INDONESIA: MALAYSIA: THE PHILIPPINES: SINGAPORE: THAILAND: 0-512-8255001 0-789-6961 0-33-6740395 021-8753175 6035569 4118 063-49-5451550 65-861-4011 038-955-160

Prepared By ONDEO Nalco Pacific EH&S, Product Safety Specialist; Telephone (02) 9316 3162 Date issued: 03-Jan-02 Replaces: 03-Sep-01

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