Summary Report: Surface Area
Summary Report: Surface Area
Page 1
Model: BK112 Method: static volumetric method
Project: FEB 2023--Sample Lab. Sample: s310123_750_90_300
Adsorbate: N2 Charge Number: #2
Bath Temperature: 77.35 K Sample Weight: 0.1142(g)
Operator: SC-SD Degas Conditions: 300
Started: 2023-02-09 11:30:38 Completed: 2023-02-09 14:17:22
Surface Area
Single Point Surface Area at p/po=0.20000: 474.933 (m2/g)
BET Surface Area: 417.486 (m2/g)
Langmuir Surface Area: 576.397 (m2/g)
t-Plot Micropore Area: 407.207 (m2/g)
t-Plot External Surface Area: 10.279 (m2/g)
BJH Adsorption Cumulative Surface Area: 16.391 (m2/g)
BJH Desorption Cumulative Surface Area: 9.370 (m2/g)
Pore Volume
Total Pore Volume at p/p0 = 0.99000: 0.220 (cm3/g)
t-Plot Micropore Volume: 0.207 (cm3/g)
BJH Adsorption Cumulative Volume: 0.016 (cm3/g)
BJH Desorption Cumulative Volume: 0.012 (cm3/g)
DR Micropore Volume: nan (cm3/g)
Pore Size
Average Pore Diameter (4V/A): 2.107 (nm)
BJH Adsorption Average Pore Diameter (4V/A): 3.817 (nm)
BJH Adsorption Most Frequent Pore Diameter (dV/dD): 2.120 (nm)
BJH Desorption Average Pore Diameter (4V/A): 5.308 (nm)
BJH Desorption Most Frequent Pore Diameter (dV/dD): 2.075 (nm)
HK/SF Micropore Analysis (< 2 nm)
Micropore Volume: 0.209 (cm3/g)
Most Frequent Pore Diameter: 0.541 (nm)
Median Pore Diameter: 0.171 (nm)
Isotherm Plot
Adsorption Desorption
156.59
140.93
125.27
Quantity Adsorbed(cm3/g STP)
109.62
93.96
78.30
62.64
46.98
31.32
15.66
0.00
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
p/p0
0.00278
0.00247
0.00216
0.00185
1/[V(p0/p-1)]
0.00154
0.00123
0.00093
0.00062
0.00031
-0.00000
0.000 0.031 0.061 0.092 0.122 0.153 0.183 0.214 0.244 0.275 0.305
p/p0
0.00023
0.00020
0.00018
0.00015
p0/p/V
0.00013
0.00010
0.00008
0.00005
0.00003
0.00000
0.00 0.00 0.01 0.01 0.01 0.02 0.02 0.02 0.03 0.03 0.03
p/p0
t-Plot Report
t-Plot
151.9
136.7
121.5
Quantity Adsorbed(cm3/g STP)
106.3
91.2
76.0
60.8
45.6
30.4
15.2
0.0
0.000 0.070 0.140 0.209 0.279 0.349 0.419 0.489 0.559 0.628 0.698
t (nm)
Kelvin Equation
rk = -0.414/ln(P/Po)
Broekhoff-de Boer Equation
log(p/p0) = 0.1682 exp(-0.1137t) - 16.11/t^2
0.00559
0.00497
0.00435
0.00373
dV/dD
0.00311
0.00248
0.00186
0.00124
0.00062
-0.00000
1e+0 1e+1 1e+2
D (nm)
0.02727
0.02424
0.02121
0.01818
dV/dlogD
0.01515
0.01212
0.00909
0.00606
0.00303
0.00000
1e+0 1e+1 1e+2
D (nm)
0.01548
0.01376
0.01204
sum_dV(cm3/g)
0.01032
0.00860
0.00688
0.00516
0.00344
0.00172
0.00000
1e+0 1e+1 1e+2
D (nm)
0.00390
0.00347
0.00304
0.00260
dV/dD
0.00217
0.00173
0.00130
0.00087
0.00043
0.00000
1e+0 1e+1 1e+2
D (nm)
0.02055
0.01827
0.01599
0.01370
dV/dlogD
0.01142
0.00913
0.00685
0.00457
0.00228
0.00000
1e+0 1e+1 1e+2
D (nm)
0.01231
0.01094
0.00958
sum_dV(cm3/g)
0.00821
0.00684
0.00547
0.00410
0.00274
0.00137
-0.00000
1e+0 1e+1 1e+2
D (nm)
DA Equation
dV/dr = 6 * Vo * (Ks/E)^2 * r^(-7) * exp^[-(Ks/E)^2 * r^(-6)]
r(nm) dV/dr
0.40000 nan
0.45000 nan
0.50000 nan
0.55000 nan
0.60000 nan
0.65000 nan
0.70000 nan
0.75000 nan
0.80000 nan
0.85000 nan
0.90000 nan
0.95000 nan
1.00000 nan
2.00000 nan
3.00000 nan
0.000
0.000
0.000
0.000
dV/dD
0.000
0.000
0.000
0.000
0.000
0.000
0.000 0.217 0.435 0.652 0.870 1.087 1.304 1.522 1.739 1.957 2.174
DD (nm)
0.184
0.164
0.143
sum_dV(cm3/g)
0.123
0.102
0.082
0.061
0.041
0.020
0.000
0.000 0.217 0.435 0.652 0.870 1.087 1.304 1.522 1.739 1.957 2.174
DD (nm)
3.108
0.210
0.187
0.163
sum_dV(cm3/g)
0.140
0.117
0.093
0.070
0.047
0.023
0.000
0.000 0.311 0.622 0.932 1.243 1.554 1.865 2.175 2.486 2.797 3.108
DD (nm)