Typical Properties
Appearance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . White liquid Total Solids, % by weight . . . . . . . . . . . . . . . . . . . . . 49.551.5 pH Value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10.310.5 Weight per Gallon, lb . . . . . . . . . . . . . . . . . . . . . . . . . . 8.58.7
The physical property data listed are considered to be typical properties, not specifications.
The binder efficiency of a latex emulsion has a direct bearing on paint film quality, especially at high pigment loadings found in traffic paints. Efficient binders, such as UCAR Latex DT 250, permit higher pigment loadings without cracking or loss of film quality. The ability to produce thick paint films without cracking is espeCrack Resistance of UCAR Latex DT 250 Traffic Paint cially important in traffic striping, as line UCAR Latex DT 250 Commercial A Commercial B thickness can vary depending on spraying and road surface conditions. Paint films up 59 to 20 mils wet can be applied to prolong the life of the line. Figure 1 compares UCAR Latex DT 250 with two commercial acrylic fast-dry traffic latexes. The results show that while the commercial fast-dry traffic latexes perform well at standard PVC, UCAR Latex DT 250 traffic latex produces much better paint films at higher pigment loadings.
Binder Efficiency
Figure 1
Paint PVC
65
70
Water Resistance
15
Minutes to Dry
30
45
60
Figure 2
3
Water Film Wash-Off on Glass Resistance Figure 3 provides the results of a film wash-off test simulating rain soon after paint application.
continued Fifteen wet mil drawdowns on glass were air dried for 30 minutes and subjected to running water at a flow rate of 150 to 180 gallons per hour. UCAR Latex DT 250 and the two leading commercial fastdry latexes were tested at three PVCs. The results show that films containing UCAR Latex DT 250 remain intact at all three PVCs tested, improved compared to Commercial Latex A and significantly better than Commercial Latex B. This data shows that UCAR Latex DT 250 based traffic stripes develop early rain resistance as fast or faster than the leading fast-dry traffic paints used today. Figure 3 Film Wash-Off of UCAR Latex DT 250 Paint UCAR Latex DT 250 Commercial A Commercial B
59
Paint PVC
65
70
15-mil drawdowns on glass, 30-minutes dry time, 5-minute running water exposure at 150 gal/hr.
Scrub Resistance
Scrub resistance, which is conducted using ASTM method D 2486, is used by some traffic latex suppliers, traffic paint companies, and DOTs to quantitatively evaluate the wet erosion resistance of traffic paints in the lab. By scrubbing traffic paints of similar film thickness that are coalesced under the same drying conditions, this test seeks to simulate and predict field performance of traffic markings on long-term exposure to tires traversing or skidding across line markings. Figure 4 shows the improved scrub resistance of UCAR Latex DT 250 in both methanol-containing and methanol-free traffic paint formulations. Figure 4
4
Methanol Free
Methanol Containing
Water Resistance
continued
Table I Commercial B
0 0 100 0 100 90 0 0 0
No Track Time," often referred to as "No Pick-up Time" (ASTM D 711) seeks to determine the drying time of traffic paints in the lab. A steel cylinder with rubber o-rings for "wheels" is rolled over a paint film drawn down over a glass plate. The film thickness is typically 14-16 mils. The time at which no paint film is picked up by the o-ring wheels is considered passing. Federal and most state specifications have a 10minute maximum that generally indicates a drying time in the field of one to two minutes. Figure 5 depicts the improved "No Track" performance of UCAR Latex DT 250 versus a competitive second-generation fast-dry all-acrylic traffic emulsion.
No-Track Performance
Figure 5
UCAR Latex DT 250 is one of few products that allow alcohol-free formulation of waterborne traffic markings. It can be formulated with or without methanol. Most waterborne traffic paints contain 2-3 percent methanol, which contributes to the overall VOC level of a formulation and can generate a measurable flash point in finished paints. When combined with other volatile solvents, methanol can also contribute to excessive paint skinning and nozzle plugging during warm weather. Methanol-free formulations may result in slightly longer dry times.
A MethanolFree Option
Road Performance
While laboratory tests are useful tools in screening latex emulsions for waterborne traffic paints, they are not a substitute for rigorous road performance testing. Dow traffic latexes have been used in numerous traffic paints applied to AASHTO test decks and individual state test decks over the past several years.
Commercial A
Wheeltrack durability tests also illustrate that UCAR Latex DT 250 outperforms other commercial 100% and premium acrylic traffic paints. Pennsylvania DOT (PENNDOT) 2001 NTPEP data in Figures 7 and 8 show that UCAR Latex DT 250 has better wheel track durability with greater line retention on both asphalt and concrete. Figure 7 UCAR Latex DT 250 Wheel Track Durability on Asphalt
100 90 80 70 % Line Retained 60 Yellow Paint Yellow Paint Yellow Paint White Paint White Paint White Paint 50 40 30 20 10 0 UCAR Latex DT 250 100% Acrylic Premium Acrylic % Line Retained
Figures 9, 10 and 11 show durability results from the 2000/2001 National Transportation Product Evaluation Program (NTPEP) test deck on Interstate 80 near Williamsport, Pennsylvania. Interstate 80 is a major east-west interstate with an average daily traffic rate (ADT) of 15,000. All three photos were taken after 10-months exposure, including a winter season of snowplowing. Figure 9 shows a UCAR Latex DT 250 transverse paint line on concrete. The line was applied at 15 mils thickness using an AASHTO, Type 2 glass bead. In contrast, the 15-mil paint lines in Figures 10 and 11 are based on 100% acrylic latex emulsions. Figure 10 depicts a first-generation, fast-dry emulsion and Figure 11 shows a premium fast-dry emulsion. The paint systems for all three figures were prepared using similar percent vehicle and pigment solids. Figure 9 UCAR Latex DT 250 Figure 10 100% Acrylic Paint Figure 11 Premium Acrylic Paint
Road Performance
continued
100% Acrylic
Premium Acrylic
High-performance traffic paints, such as those based on UCAR Latex DT 250, require that all equipment exposed to the paint, including tanks, lines, fittings and filters, be made of stainless steel or durable plastic to ensure trouble-free operation. Equipment parts made of steel, black iron, galvanized or brass of any kind must be replaced for ease of operation.
Application Equipment
Comparative Performance Properties of UCAR Latex DT 250 versus Two Leading Commercial Fast-Dry Traffic Latexes Fast-Dry White Traffic Paint DT 250 Commercial A Commercial B
Formulation Properties Stormer Viscosity, KU 24-hr 7-day, 60 C Density, lb/gal No-Tracking Time, min1 50% R.H./72 F Dry-Through Time, min1 90% R.H./72 F CIE Color x (B) y (B) Contrast Ratio Reflectance
1 = 15-mil wet film
Table II
7
The following starting point formulations are typical of fast-dry traffic paints used today. Table I on page 7 lists the laboratory properties of UCAR Latex DT 250 based on two leading commercial fast-dry acrylic binders.
Paint Fast-Dry Yellow Traffic Paint with Methanol Formulations Formulation Suggestion V-2211 and Properties Ingredients DT 250 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pounds . . . . . . . . . . . . Gallons UCAR Latex 460.0 . 52.87
continued DOWICIL1 75. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.5 . . . . . . . . . . . . . . 0.04 Drewplus L-493 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.0 . . . . . . . . . . . . . . 0.27 Colloid 226/35 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.7 . . . . . . . . . . . . . . 0.73 Natrosol 250 HBR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.3 . . . . . . . . . . . . . . 0.03 Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13.0 . . . . . . . . . . . . . . 1.56 1244 Sunglow Yellow. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.0 . . . . . . . . . . . . . . 2.58 Ti-Pure R-900 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20.0 . . . . . . . . . . . . . . 0.60 Mix for 3 minutes Omyacarb 5. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 765.0 . . . . . . . . . . . . . 34.00 Mix for 4 minutes Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30.0 . . . . . . . . . . . . . . 4.52 Texanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21.0 . . . . . . . . . . . . . . 2.66 Drewplus L-493 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.0 . . . . . . . . . . . . . . 0.40 Mix for 3 minutes _______ ________ Total . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1354.5 . . . . . . . . . . . 100.26 Physical Properties Pigment Volume Concentration (PVC), % . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54.4 Weight per Gallon, lb. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13.5 Total Solids, % by weight. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78.1 by volume . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63.4 VOC, g/L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85.8 Coalescent, % . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9.0
The physical property data listed are considered to be typical properties, not specifications. 1 Note: Dowicil 75 was omitted for general lab screening.
When considering the use of any UCAR Emulsion Systems product in a particular application, the Customer should review our latest Material Safety Data Sheets and ensure that the intended use can be accomplished safely. For MSDS and other product safety information, contact the UCAR Emulsion Systems Sales Office nearest you. Before handling any other products mentioned in the text, available product safety information should be obtained and necessary steps should be taken to ensure safety of use. No chemical should be used as or in a food, drug, medical device, or cosmetic, or in a product or process in which it may contact a food, drug, medical device, or cosmetic until the Customer has determined the suitability and legality of the use. Since government regulations and use conditions are subject to change, it is the Customers responsibility to determine that this information is appropriate and suitable under current, applicable laws and regulations. UCAR Emulsion Systems requests that the Customer read, understand, and comply with the information contained in this publication and the current applicable MSDS. The Customer should furnish the information in this publication to its employees, contractors, Customers, or any other users of the product(s), and request that they do the same.
Product Safety
Follow procedures typically recommended for polymer dispersions. Use corrosion-resistant storage tanks and piping. Air-operated diaphragm pumps are preferred. Avoid temperature extremes. Do not freeze; store above 40 F. For further information, refer to booklet UCAR Latexes Shipping, Storage, and Handling.
The Dow Chemical Company maintains an around-the-clock emergency service for its products. American Chemistry Council (CHEMTREC) and Transport Canada (CANUTEC) maintain aroundthe-clock emergency service for all chemical products.
Mainland U.S.A.: Dow Chemical Products: 800-DOW-CHEM (800-369-2436) or 979-238-2112 All Chemical Products: Phone CHEMTREC at 800-424-9300 Alaska, Hawaii, and Puerto Rico: Dow Chemical Products and All Other Chemical Products: Phone CHEMTREC at 800-424-9300 Canada: Dow Chemical Products: Phone 514-640-6400 (collect) All Chemical Products: Phone CANUTEC at 613-996-6666 (collect) Europe, Middle East, and Africa: Dow Chemical Products: Phone The Dow Chemical Company in Terneuzen, The Netherlands at 31-115-694982 All Chemical Products: Phone CHEMTREC in U.S.A. at 800-424-9300 Latin America, Asia/Pacific and any other location worldwide: Dow Chemical Products and All Other Chemical Products: Phone CHEMTREC in U.S.A. at 800-424-9300
Emergency Service
At sea, radio U.S. Coast Guard, who can directly contact The Dow Chemical Company at 800-DOW-CHEM or 979-238-2112 (North America only) or CHEMTREC in U.S.A. at 800-424-9300 DO NOT WAIT. Phone if in doubt. You will be referred to a specialist for advice.
11
ARGENTINA Dow Quimica Argentina J.D. Peron e Irigoyen S/N Pto. Gral. San Martin - San Lorenzo Provincia de Santa Fe 2202 Argentina Telephone: 54-4376-438629 BRAZIL Dow Quimica S.A. UCAR Emulsion Systems Rua Alexandre Dumas 1671 Sao Paulo 04717-903 Brasil Telephone: 55-11-5188-9000 (general) Fax: 55-11-5188-9090 CHINA Dow Chemical Pacific Limited 47/F, Sun Hung Kai Centre 30 Harbour Road, Hong Kong Telephone: (852) 2879 7333 Fax: (852) 2610 0416 Union Carbide (Guangdong Zhongshan) Company Limited A Dow Chemical Group Company 57 Xiaolan Highway Postcode 52845 Xiaolan, Zhongshan, Guangdong, China Telephone: (86) 760 2101 288 Fax: (86) 760 2100 823 Shanghai Petrochemical Union Carbide Emulsion Systems Company Limited Suit 1101, Shui On Plaza 333 Huai Hai Zhong Road Shanghai 200021, China Telephone: (8621) 6385 1608 / 6249 2738 Fax: (8621) 6384 8228
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SINGAPORE Dow Chemical Pacific (Singapore) Pte. Ltd. #18-01 The Heeren 260 Orchard Road Singapore 238855 Telephone: (65) 6835 3773 Fax: (65) 6834 0319 Dow Chemical Pacific (Singapore) Pte. Ltd. - Tech Centre 16 Science Park Drive #04-01/02 The Pasteur Singapore 118227 Telephone: (65) 6778 2630 Fax: (65) 6777 6249 SWITZERLAND Dow Europe GmbH 13, rue de Veyrot - P Box 3 .O. CH-1217 Meyrin 2 (GE) - Switzerland Telephone: 41227194111 Fax: 41227827686 THAILAND Dow Pacific (Thailand) Limited 15th Floor, White Group Tower 2 75 Soi Rubia, Sukhumvit 42 Road Prakanong, Klongtoey Bangkok 10110, Thailand Telephone: (66) 2 381 1038 Fax: (66) 2 391 7367 UNITED ARAB EMIRATES Dow UCAR Emulsion System FZE P Box 16943, Jebel Ali .O. Dubai, United Arab Emirates Telephone: 971-4-8074200 Fax: 971-4-8074300
NORTH AMERICA Customer Information Group (CIG) Telephone: 1-800-447-4369 Fax: 989-832-1465 www.dow.com
PHILIPPINES Dow Chemical Philippines, Inc. 23/F, 6750 Ayala Avenue 1226 City of Makati Telephone: (63) 2 819 1986 Fax: (63) 2 815 2180
NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customers use and for ensuring that Customers workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Seller assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
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