Model Test - 06
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Take This test comprising 3 sections with a duration of 2 hours each
section.
Each section contains 50 questions. Observe the given weightage to
each question. 1/3 rd negative marking do exist for the wrong answers.
Maintaining the time limit of 2 hours for each section is of atmost im-
portance, while taking the test.
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How to answer ?
Happy learning
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Paper - I : Physics - 1 to 50
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, electrons may be given enough energy to overcome the forces holding them in place and become energizedto move
freely through the bulk of the photoconductor , leaving behind positively charged “holes” where they once were .
In the presence of an external electric field , the electrons and the holes move in opposite directions .
The creation of electron - hole pairs occurs only in the areas of the photoconductor exposed to light , in a layer
known as the charge generation layer that typically lies near the bottom . The holes will migrate to the surface under
the attractive force of the adsorbed surface ions , while the electrons flow to the ground plane . The process is
schematized in figure 1 .
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Absorbed ions
Photon 15 µm
Ground
plane
Charge generation
layer (0 .1 µm)
Ground
The migration of the holes and their interaction with the surface ions lead to a decrease in the magnitude of the
potential at the surface . The new value is known as the “ light voltage,” since only those areas exposed to light
experience this change in potential . The surface potential ( relative to the potential of the ground plane ) is plotted
Figure 2.
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Surface potential
Light of Light of
0 Time
Light of
Voltage
Dark Voltage
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Toner particles ( ink particles are released from an ink gunand electrodes are used to direct and accelerate the toner
particles onto the page . An electrical charge is imparted to the particles as they leave the gun . These charged toner
particles adhere to the photoconductor surface in a manner that reflects the contrast between the light and dark
voltages , and the toner is then transferred onto paper. Finally , the paper is heated to bake the toner onto the page
and the copy is complete.
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1. As can be seen from figure2 , thetransition from dark to light voltage is not abrupt , but exhibits a finite duration that
corresponds roughly to the time the hole takes to that move to the surface . This is characterized by the transit time
d2
which is approximated by the relation TL = where d is the thickness of the photoconductor, µ is thedrift
m | V0 |
(3 mark)
mobility of the charge and V0 is thedark voltage . Which of the following will decrease the transit time ?
a) increasing the thickness of the photocoductor
b) increasing the intensity of the light projected onto the photocoductor
c) increasing the wavelength of the light projected onto the photocoductor
d) increasing the number of gaseous ions adsorbed per unit area
1 q1q 2
2. Find the units of ε0 from Coulomb’s law . F = 4ππ
r 2 Where F is the force of electrostatic attraction
0 (3 mark)
q1 and q 2 are charges ,and r is the distance between the charged particles.
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a) C / ( Nm) b) Nm 2 /C 2 c) C 2 /( Nm 2 ) d) C / J
3. If the dark voltage is - 80V ,and if the photoconductor can be thought of as a 15 − µm thick dielectric with dielectric
(3 mark)
constant 3 ,what is the magnitude of the surface charge density due to the adsorbed ions ?
6. The diagram shows a cell E, connected to a pure resistor R and pure self induction L of negligible resistance. If at
time, t = 0, the switch S is closed, the self induced emf ‘e’ across the self inductor varies with time as shown by the
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graph : (3 mark)
E S
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R L
e e e e
a) b) c) d)
o t t t t
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7. Two masses m and M are connected by a massless inextensible string which is passing over a fixed pulley. At some
instant V1 and V2 are their velocities, shown in the figure. The ratio V1/V2 is —— (3 mark)
V1
m
V2
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8. n-identical spheres are placed on a smooth surface touching each other in a straight line. An another identical sphere
1
moving with velocity ‘u’ along the same straight line hits the sphere. If e = , is the coefficient of restitution
2 (6 mark)
between any 2 spheres, the velocity of nth sphere is ——
3
n −1
3
n www.aieeepage.com
1
n −1
9. The figure shows the net power (P) versus current intensity (I) in a circuit. The emf of the cell φ when the power
(3 mark)
consumed is maximum.
100 W
75–
50–
25–
5A
O
I 10 Amp
a) 40 V b) 30 V c) 20 V d) 10 V
10. When a particle is allowed to Slide down from the top (A) of a hill. It stops at X due to friction. The coefficient of
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friction is independent of velocity and direction of motion. The work performed by a tangential force to take the same
object back to the top of the hill is —— (3 mark)
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h
X
x
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11. The graph shows the motion of a ball rebounding from a horizontal surface being released from a point above the
(3 mark)
surface. The quantity represented on the y-axis is the ball’s
x
time
− Ke2
12. Suppose the potential energy between electron and proton at a distance ‘r’ is given by . Application of
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3r 3 (6 mark)
Bohr’s theory to hydrogen atom in this case shows that :
i) energy in nth orbit is proportional to n6
ii) energy is proportional to m–3 (m: mass of electron) Then :
a) both (i) and (ii) are correct b) only (i) is correct
c) only (ii) is correct d) none are correct
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13. If the ground state of hydrogen atom is chosed as zero potential energy level, the value of the total energy in the first
(3 mark)
excited state (in eV) is —
a) 10.2 b) 13.6 c) 3.4 d) 23.8
14. A thermodynamic process is such that VT = constant, the molar heat capacity of such a process is — (3 mark)
a) C = CV + 2 R b) C = CV − 2 R c) C = CV + R d) zero
15. The given diagram indicates the energy levels of a certain atom. When the system moves from 2E level to E level, a
4E
photon of wavelength λ is emitted. The wavelength of the photon emitted during its transition from level to E
3 (3 mark)
level is —
2E
4E/3
λ 3λ 4λ
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a) 3 b) 4 c) 3 d) 3λ
16. A tank is filled with water to a height 0.5m. It is placed on a stand of height 1.5m above the ground. At what height
‘h’ above the ground a small hole be made in the tank so that the water falls on the ground at the farthest distance
‘R’? (3 mark)
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m
0.5
h
m
1.5
K–R
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17. The V – T diagram of an ideal gas for the process A → B → C as shown. Select the correct alternative (3 mark)
A
C
o
T
PAGE
(3 mark)
is —
U
A B
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D C
o V
V0 2V0
19. One mole of an ideal gas whose pressure changes with volume on P = α V , where α is a constant, is expanded so
(6 mark)
that its volume increases twice. The heat capacity of the gas is —
R (r + 2) Rr+2 R r +2 R r +1
2 r −1 2 r − 1
a) 2(r + 1) b) 2 r − 2
c) d)
20. The thermal power of density U (energy/volume) is generated at a constant rate inside a uniform sphere of radius R
and thermal conductivity K. The distribution of temperature inside the sphere when the steady state temperature. T0
at the surface is — (3 mark)
PAGE
a) there will be two images above and below F
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b) there will be three images on same vertical time passing through F and towards night
F
c) there will be three images one at F and other two above and below the point F towards right
d) there will be three images one at F and other two above and below the point F towards left
22. In a double slit experiment, the distance between the slits is ‘d’. The screen is at a distance ‘D’ from slits. If a
bright fringe is formed opposite to a slit on the screen, the order of the fringe is : ( λ –wavelength of light) (3 mark)
d2 2λ D d 2d
a) b) c) d)
2λ D d 2 λD λD
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40
23. The figure shows a thin glass converging lens of focal length, f = cm. To the left of the lens is a square of area
3
100cm2. The base of the square is on the principal axis, and the right side of the square is 20cm from the lens. The area
(6 mark)
of the image is —
20cm
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amplitude at an antinode to the amplitude at a node is 1.5. The percentage of energy passes across the obstacle is
(3 mark)
——
a) 12% b) 24% c) 48% d) 96%
25. A source emitting a sound of frequency f is placed at a large distance from an observer. The source starts moving
towards the observer with a uniform acceleration ‘a’. If the speed of sound in the medium is V. Then the frequency
heard by the observer corresponding to the wave emitted just after the source starts is — (3 mark)
a)
Vf 2
b)
Vf 2 www.aieeepage.com
c)
2Vf 2
d)
2Vf 2
Vf − a Vf + a 2Vf − a 2Vf + a
N 4
26. A positively charged sphere of mass 5kg is attached by a spring of spring constant 10 . The sphere is tied with
m
a thread so that spring is in its natural length. Another idential, negatively charged sphere is fixed with floor,
1
vertically below the positively charged sphere as shown. If initial seperation between the spheres is r0 =
m , and
2
magnitude of charge on each sphere is q = 100 µθ , the maximum elongation of the spring when the thread is burnt
(3 mark)
is —
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r0
a) 15 cm b) 10 cm c) 25 cm d) 22 cm
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A solid non conducting hemisphere of radius R has a uniformly distributed positive charge of density ρ per unit
volume. A negatively charged particle having ‘q’ is transferred from centre of its base to infinity. Work performed in
(3 mark)
the process is —
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28. The potential energy U of a particle of mass 1 kg, moving in xy plane is given by U = 2x – y. If the particle is at rest
(3 mark)
at (2, 1), its acceleration at this position is given by —
a) 10 b) 2 10 c) a x = 1; a y = 3 d) ax = −3; ay = −1
29. A less is coated with a thin film of µ = 1.2 inorder reduce the reflection from its surface at λ = 5000 A 0 . Minimum
(3 mark)
thickness of the film which will minimize the intensity of the reflected light is —
a) 10–6 m b) 10–1 cm c) 10–5 cm d) 10–6 cm
30. Two thin symmetrical lenses of different nature have equal radii of curvature 20cm. The lenses are put close together
and immersed in water. The focal length of the system is 24 cm. Then the difference between refractive indices of the
two lenses will be — (3 mark)
2 1 4 5
a) b) c) d)
9 3 9 9
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1
31. At a certain point on a screen the path difference for the two interfering rays of same amplitude is th of a
8 (3 mark)
wavelength. The raio of the, intensity at this point to that at the centre of a bright fringe is —
a) 0.853 : 1 b) 0.693 : 1 c) 0.492 : 1 d) 0.341 : 1
32. Two sources A and B are sounding notes of frequency 680 Hz. A listener moves from A to B with a constant velocity
m m m m
a) 2.0 b) 2.5 c) 3.0 d) 3.5
s s s s
(3 mark)
33. In the circuit shown the cells have no internal resistances the potential difference VA–VB is —
+ +
+
– – –
10
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a) 1 V b) 15 V c) 5V d) V
17
JG JG
34. A charge particle q pases through a region having perpendicular uniform electric field E and magnietic field B
undeviated. Choose the current alternative — (3 mark)
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35. Charges Q1, Q2, Q3 and Q4 are given to the plates 1, 2, 3 and 4 respectively. The charge appear at the outer surface of
the first plate to — (3 mark)
1 2 3 4
Q1 + Q 2 + Q3 + Q 4 Q1 + Q 2 + Q3 + Q 4 Q1 – Q 2 – Q3 – Q4 Q1 – Q 2 – Q3 – Q 4
a) b) c) d)
2 4 2 4
36. A parallel plate capacitor is connected to a battery. The plates are pulled apart is in a uniform speed. If x is the
PAGE
seperation between the plates, then the φ rate of change of the electrostatic energy of the capacitor is proportional
(6 mark)
to :
1 1
a) x2 b) x c) d)
x2 x
37. For a cell, graph between potential difference (V) across the terminals of the cell and current (I) drawn from cell is
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shown. The emf and internal resistance of cell— (3 mark)
V (volt)
o
S
(amp)
i
a) 2V, 0.4Ω b) 2V, 0.5Ω c) > 2V, 0.4Ω d) < 2V, 0.4Ω
38. The gap between the plates of a parallel plate capacitor is filled with glass of resistivity ρ and dielectric constant K.
The capacitance of the capacitor equals C. If a voltage V is applied to it, then the leakage current of the capacitor at
that instant is —
(3 mark)
CV 2 CV 2CV CV
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a) b) c) d)
2 kρε 0 kρε 0 kρε 0 kρ ε 0
39. The annular disc of copper with inner and outer radii as a and b is rotating with a uniform angular speed ω is a region
wher a uniform magnetic field B along the axis of notation exists. Then the emf induced between the inner sides and
outer rim of the disc is —
(3 mark)
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a
1 1 1
a) zero b) Bω a 2 c) B ω (b 2 − a 2 ) d) B ω (b 2 − a 2 )
2 4 2
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40. A spring of mass ‘m’ lies on a smooth table. One end of it is clamped to the nearest wall and the other end is pulled
with velocity ‘V’ the kinetic energy of the spring is — (3 mark)
1 2 1 2 1 2 1 2
a) mv b) mv c) mv d) mv
2 3 6 9
41. A small sphere of superdense material has a mass half of the mass of the earth. It is situated at a height ‘h’ (much
smaller than the earth’s radius) from where it falls on the earth’s surface. Then its speed when its height from the
(3 mark)
h
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earth’s surface is reduced to is —
2
2 gh 3 gh
a) 2gh b) gh c) d)
3 2
42. Two particles of masses M1 and M2 are connected by a light spring of spring constant K as shown M2 is placed on
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rough table where as M1 is hanging vertically. M1 performs vertical oscillations with amplitude A. If M2 on table
always remains at rest then minimum value of coefficient of friction between M2 and table is — (3 mark)
M2
M1
M2 KA M1 KA M2 KA M1 KA
a) + b) + c) − d) −
M1 M 2 g M2 M2g M1 M 2 g M2 M2g
43. A particle moves with an initial velocity V0 and retardation α V , where V is its velocity at any time ‘t’. The particle
(3 mark)
will cover a total distance of —
V0 V0 V0 2V0
a) b) c) d)
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4α 2α α α
44. A block of mass ‘m’ is allowed to slide down a smooth inclined plane of angle θ as shown. The power developed
(3 mark)
by the force of gravity at the moment when the block reaches the bottom is —
u=0
m
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l
1 2 3 2 2 3 2 2 3
a) ⋅ m lg sin θ b) ⋅ m lg cos θ c) ⋅ m lg sin θ d) 2 ⋅ m 2 lg 3 sin 3 θ
3 3 3
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45. Three points are located at the vertices of an equilateral triangle whose sides equals ‘a’. They all start moving
simultaneously at time, t = 0 with velocity V = kt, where k is a positive constant. All the three points move such that
first always point heading continually for the second, the second for the third, and the third for the first, how soon
will the points converge? (3 mark)
a 2a a 4a
a) b) c) d)
K K 2K K
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Classical theories aren’t enought to explain why this distribution of thermal wavelengths should be Scientists turned
their attention to the blackbody, an ideal system whose surface is a perfect absorber and emitter of radiation. The
thermal emission spectra from stars can be approximated closely by the blackbody distribution.
Wien’s displacement law arose from experimental results : as the temperature of a blackbody increases, the wavelength
at which the maximum intensity of thermal radiation occurs decreases.
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λ T = 2.9 ×10 m.k
max
−3
Max Planck was able to determine the correct formula for the distribution of blackbody emission wavelengths bu
making two assumptions. First, the oscillating molecules of the blackbody that give off the thermal radiation can only
have particular, discrete frequencies. The fact that the allowed frequencies of the molecules were quantized means
that their energy has to satisfy E = nhf, where h is Planck’s constant, and n is a positive interger. Second, the emitted
quanta, called photons, have discrete energies that are proportional to their frequency. (Note : h = 4.15 x 10-15 eV-s).
46. As a result of the Big Bang, a cosmic background radiation exists in all of space, at a temperature of 3 K. What is the
(3 mark)
wavelength of this radiation?
a) 1.1 x 10-15 m b) 8.7 x 10-4 m c) 9.7 x 10-4m d) 1.0 x 103 m
47. Which of the following could be the termperature of a blackbody whose maximum emitted intensity is in the visible
(3 mark)
light spectrum?
a) 500 K b) 2000 K c) 5800 K d) 29000 K
48. How does the frequency of blackbody radiation at maximum intensity vary with the temperature of the emitting
body? (3 mark)
a) As the temperature of the object increases, the emitted frequency at maximum intensity increases
b) As the temperature of the object decreases, the emitted frequency at maximum intensity increases
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c) As the temperature of the object increases, the emitted frequency at maximum intensity is unchanged
d) As the temperature of the object increases, the emitted frequency at maximum intensity decreases.
49. A mass m, connected to a spring with force constank k, undergoes oscillation. If the energy of oscillation is
quantized, how big is the energy gap between consecutive energy states? (3 mark)
1 k k h m h k
a) b) h c) d)
50.
2π m m
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A 3-kg block of lead is heated from a temperature of 400 K to 410 K by adding 3840 J of heat energy. What is the
specific heat of lead? (3 mark)
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Paper - I I : Mathematics - 51 to 100
The locun of the middle points of a system of parallel chords of an ellipse is called a diameter and chords of are called
−b 2 x2 y2
=
a 2 m , (where m is slope of chord of ellipse 2 + 2 = 1 ) which is a st.
its double ordinates, the equation is y x
a b
1 −b 2
line thro’ (0, 0) having slope m1 such that mm = . Also if y = mx bisect all chords 11to y = m1 x , where
a2
−b 2
mm1 = . Such a pair of diameters which bisects all chords 11 to the other are called conjugate diameters.
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a2
51. If θ1 & θ2 be eccentric angles of the ends A & C of a pair of conjugate diameters, then θ1 , θ2 differ by (3 mark)
π 3π π
(a) (b) π (c) (d)
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3 2 2
x2 y2
52. In the above question (1) AO 2 + CO 2 = {Where O is centre of ellipse + = 1} (3 mark)
a2 b2
(a )
2
(a) a 2 + b 2 (b) 2
+ b2 (c) a2 − b2 (d) 1
π π π 3π 2π
(a) (b) (c) or (d)
2 3 4 4 3
Questions 54 - 95 are independent questions
54. The equation a ( x 4 + y 4 ) − 4bxy ( x 2 − y 2 ) + 6cx 2 y 2 = 0 represents two pairs of lines at right angles and the two
(6 mark)
pairs will coincide if
PAGE
(3 mark)
a) 1 b) 2 c) 3 d) 0
G G G
56. Radius of the circle r 2 + r .(2iˆ − 2 ˆj − 4kˆ ) − 19 = 0, r .(iˆ − 2 ˆj + 2kˆ ) + 8 = 0 (3 mark)
a) 5 b) 4 c) 3 d) 2
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57. The equation ax + by + c = 0 reprsents a plane perpendicular to the (3 mark)
sin x − cos x
58. The period of the function f ( x) = (3 mark)
sin x + cos x is
π
a) b) 2π c) π d) None of these
2
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3
59. The function f : ( −∞,1] → (0, e 5 ] defined by f ( x) = e x −3 x + 2 is (3 mark)
x2
60. If the normal of f(x) = 0 at x = 0 is given by 3x - y + 3 = 0 then xlim is equal to
→0 f ( x ) 2 − 5 f ( 4 x 2 ) + 4 f (7 x 2 ) (3 mark)
1 1 1
a) − b) c) d) 0
3 3 6
61. The following functions are differentiable on (-1, 2) (3 mark)
2x 2 x sin t x 1- t + t 2
∫x (log t ) 2 dt ∫0 ∫0
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a) b) dt c) dt d) None of these
t 1+ t + t2
62. Between any two real roots of the equation e x sin x = 1 the equation e x cos x = −1 has (3 mark)
a) atleast one root b) exactly one root c) atmost one root d) no root
63. The normal to the curve x =α (cosθ +θ sin θ ), y =α (sinθ −θ cosθ) at any θ is such that : (3 mark)
65. If e1 and e2 are the eccentricities of the conic sections 16 x 2 + 9 y 2 = 144 and 9 x 2 − 16 y 2 = 144 , then (3 mark)
a) e12 + e22 = 3 b) e12 + e22 > 3 c) e12 + e22 < 3 d) e12 + e22 = 1
66. A line meets the co-ordinate axes in A and B. A circle is circumscribed about the triangle OAB. If the distances from
(3 mark)
A and B of the tangent to the circle at the origin be m and n. Then the diameter of the circle is
a) m (m + n) b) m + n c) n (m + n) d) m2 - n2
67. In the figure OABC is a square of side 8 cm, then the equation of the smallest circle is (3 mark)
PAGE
Y
A B
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O A
X
a) ( x − 4) 2 + ( y − 4) 2 = 4 b) ( x − 4) 2 + ( y − 4) 2 = 8
c) ( x − 4) 2 + ( y − 4) 2 = 12 d) None of these
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cos A sin A cos (A + D)
68 In a quadrilateral ABCD. Let ∆ = cos B sin B cos (B + D) , then ∆ (3 mark)
π
is a root of equation x 2 − 9 x + 8 = 0, where 0 < α < , then the principle
2 4
α + sin 6 α +......to ∞ ]loge 2
69. If e[sin α +sin 2 (3 mark)
−1 2π
value of sin sin is
3
a) α b) 2α c) −α d) − 2α
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x 2 + 2 x2 + x x +1
70. Let ax7 + bx6 + cx5 + dx4 + ex3 + fx 2 + gx + h = x2 + x x + 1 x2 + 2 then (3 mark)
x2 + 2 x2 + x x + 1
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If in x, y, z the system of linear equations (sin 3θ ) x - y + z = 0, (cos 2θ ) x + 4y + 3z = 0; 2x + 7y + 7z = 0 has
(6 mark)
non-zero solution, then θ =
π π nπ
a) nπ b) 2 nπ ± c) mπ d)
6 3 2
72. If the integers λ and µ are chosen at random between 1 to 100 then the probability that a number of the form
(3 mark)
λ
7 + 7 µ is divisible by 5 is
1 1 1 1
a) b) c) d)
4 7 8 49
73. Amar, Akbar and Anthony repeatedly take turns tossing a die. Amar begins; Akbar always follows Amar Anthony
always follows Akbar; and Amar always follows Anthony. Find the probability that Anthony will be the first one to
toss a six. (The probability of obtaining a six on any toss is independent of the outcome of any other toss.) (3 mark)
1 2 5 25
a) b) c) D)
3 9 18 91
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a2 is equal to
74. If a sin2 x + b cos2 x = c, b sin2 y + a cos2 y = d and a tan x = b tan y, then (3 mark)
b2
(b − c ) ( d − b ) ( a − d ) (c − a ) ( d − a ) (c − a ) (b − c ) (b − d )
a) b) c) d)
(a - d) (c - a) (b - c) (d - b) (b - c) (d - b) (a - c) (a - d)
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75. If sin x = cos y, 6 sin y = tan z and 2 sin z = 3 cos x; u , v, w denote respectively sin 2 x, sin 2 y, sin 2 z
(3 mark)
1 1 3 1 3 1
a) (1, 0, 0) b) (0, 1, 0) c) ; ; d) ; ;
2 2 4 2 4 2
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76. The greatest and least values of sin −1 x ( ) + (cos x )
3 −1 3
are (3 mark)
π π π3 π3 7π 3 π 3
a) ,− b) ,− c) , d) None of these
2 2 8 8 8 32
77. If in triangle ABC, ∠C = 45o then exhaustive range of sin 2 A + sin 2 B is (3 mark)
1 1+ 2
,
a) [ 0, 1 ] b) ( 0, 1 ) c) 2 2
d) None of these
78. The line x + 2y = 4 is translated parallel to itself by 3 unit in the sense of increasing x and then rotated by 300 in the
anticlockwise direction about the point where the shifted line cuts the x-axis. The equation of the line in the new
position is (3 mark)
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a) y = tan (θ − 30 o ) (x - 4 - 3 5 ) b) y = tan (30 o − θ ) (x - 4 - 3 5 )
c) y = tan (θ + 30 o ) (x + 4 + 3 5 ) d) y = tan (θ − 30 o ) (x + 4 + 3 5 )
79. A point moves such that the square of its distance from a straight line is equal to the difference between the square
of its distance from the centre of a circle and the square of the radius of the circle. The locus of the point is (3 mark)
a) a straight line at right angle to the given line www.aieeepage.com
b) a circle concentric with the given circle
c) a parabola with its axis parallel to the given line
d) a parabola with its axis perpendicular to the given line
x2 y2
80. If CP and CD are semi-conjugate diameters of the ellipse + = 1 then CP 2 + CD 2 = (3 mark)
a2 b2
a) a + b b) a 2 + b2 c) a 2 − b2 d) a2 + b2
81. If the line y = mx + 2 cuts the parabola 2y = x2 at points ( x1 , y1 ) and ( x2 , y 2 ) ; where, x1 < x2 , then value of m
(3 mark)
x2
2
mx + 2 − x dx
for which ∫
2 is minimum is
x1
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2 1
x + x3 + x6
82. I =∫ 1
dx is equal to (6 mark)
1+ x 3
x
1 1
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2 2
3 3 6
x 3 3 6
x
a) x + 6 tan −1 + c b) x − 6 tan −1 + c
2 2
1
2
3 3 5
x
c) x + 6 tan −1 + c d) None of these
2
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x
1 2e 4e 6e
∫
(6 mark)
83. = + + + ......∞, then find f ( y ) log y xdy, y > 1
x 3! 5 ! 7 ! 0
2
[ f (e)]2 1 1 [ f (e 2 )]2
f
2 e
a) b) c) d) None of these
2 2
84. Let f ( x ) = x 2 , g (x) = cos x and α , β (α < β ) the roots of the equation 18x 2 − 9πx + π 2 = 0 . The area(3 mark)
bounded by the curve y = fog (x), the ordinates x = α , x = β and the x-axis is
1 1 π π
a) (π − 3) b) (π − 3) c) d)
6 12 12 6
PAGE
1 π
85. Let f ( x) = MIN tan x, cot x, ∀x ∈ 0, . The area bounded by y = f(x) and the x -axis is (3 mark)
3 2
4 π 2 π 4 π 2 π
a) In + b) In + c) In + d) In +
3 6 3 3 12 3 3 12 3 3 6 3
86.
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The tangent at a point P (x,. y) on a curve meets the axes at P1 and P2 such that P divides P1, P2 internally in the ratio
2 :1. The equation of the curve is (3 mark)
87.
G G G G
(G G ) (G G )
Unit vectors a , b and c are coplanar. A unit vector d is perpendicular to them. If a × b × c × d =
1ˆ 1 ˆ 1 ˆ
6
i − j + k,
3 3
G G G (3 mark)
and the angle between a and b is 300, then c is
1 ˆ 1 ˆ ˆ ˆ 1 1 ˆ
1) (i − 2 ˆj + kˆ) 2) (2i − j + k ) 3) (−2iˆ − 2 ˆj + kˆ) 4) (−i + 2 ˆj − 2kˆ)
3 3 3 3
Which of the given statement(s) match with the main statement.
a) 1, 4 b) 1, 2 c) 1, 3 d) None of these
G G G G
88. Consider a tetrahedron with faces F1 , F2 , F3 , F4 . Let V1 , V2 , V3 , V4 be the vectors whose magnitudes are
respectively equal to areas of F1, F2 , F3, F4 and whose directions are perpendicular to their faces in outward
(3 mark)
G G G G
direction. Then V1 + V2 + V3 + V4 equals
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a) 1 b) 4 c) 0 d) None of these
89. OA, OB, OC are the sides of a rectangular parallelopiped whose diagonal are OO’, AA’, BB’ and CC’. D is the centre
of the rectangel AC’O’B’ and D’ is the centre of the rectangle O’A’CB’. If the sides OA, OB, OC are in the ratio
1 : 2 : 3, the angle DOD’ is equal to (3 mark)
24 22 24 22
a) cos −1 b) cos −1 c) sin −1 d) sin −1
697 619 697 691
90.
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The least value of 2 log100 a-log a 0.0001, a > 1 (3 mark)
a) 2 b) 3 c) 4 d) None of these
2 3 1
91. If α is an imaginary fifth root of unity, then log 2 1 + α + α + α − = (3 mark)
α
a) 1 b) 0 c) 2 d) -1
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92. Which of the following statements is ture? (3 mark)
i) The amplitude of the product of the two complex numbers is equal to product of their amplitudes
ii) For any polynomial f(x) with real coefficients imaginary rosts always occur in conjugate pairs
iii) Order relation exists in complex numbers whereas it does not exist in real numbers.
iv) The values of ω used as a cube root of unity and as a fourth root of unity are different
Which of the given statement(s) match with the main statement.
a) i and ii only b) ii and iv only c) iii and iv only d) i, ii, and iv only
93. In the expansion of (1 + x)n ( 1+y)n (1+ z)n, the sum of the coefficients of the terms of degree r is (3 mark)
a) (C)
n
r
3 n
b) 3. Cr c) 3n
Cr d) n
C 3r
1 1 1 + 3 + 5 + .... + (2 y − 1) 20
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94. If log10 x + log10 x 2 + log10 x 4 + ......∞ = y and =
4 + 7 + 10 + ....(3 y + 1) 7 log10 x' then x =
(3 mark)
| x| 1
95. The solution set of the inequality 1 − ≥ is (3 mark)
1+ | x | 2
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a) x ∈ [−1,1] b) x ∈ (−1,1) c) x ∈ (0,1) d) none of these
y
P(r, θ)
r y
0
θ
x
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We know that cartesian equation line is
c K
⇒ − = a cos θ + b sin θ or = a cos θ + b sin θ
r r
which is equation of line in polar form where a, K, b are constants.
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Normal form of a straight line:
Let P be length of ⊥ r from pole upon a straight line, α the angle which this ⊥ r makes with initial line & (r, θ ) the
coordinates of any movable point on the line, then P = r cos(θ − α) represents equation of line in normal form.
P(r, θ)
P
α x
0
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96. The general equation of a line is 3x+4y=5. Then the polar form is (3 mark)
5
(a) 3sin θ + 4 cos θ = (b) 3cos θ + 4sin θ = 5
r
5 5
(c) 3cos θ + 4sin θ = (d) 3cos(π − θ) + 4 sin(π − θ) =
r r
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2 (3 mark)
97. The equation of line 11 to cos θ + sin θ = & passing thro´ (1, π / 2) is
r
1 1 2 2
(a) cos θ + sin θ = (b) cos θ − sin θ = (c) cos θ − sin θ = (d) − cos θ + sin θ =
r r r r
l
98. The equation of line to a cos θ + b sin θ = , passing thro´ pole is (3 mark)
r
l1 −1 b
(a) a sin θ − b cos θ = (b) θ = Tan (c) r = a cos θ (d) r = a sin θ
r a
π
99. If length of ⊥ r from origin to a straight line is 3 units & angle made by it ( ⊥ r) with initial line is then equation
4 (3 mark)
of the straight line is
2 π 3 2 3 2
(a) = cos θ + sin θ (b) r = 3cos θ − θ (c) = cos θ (d) = cos θ + sin θ
r 4 r r
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l
100. The coordinates of foot of ⊥ r drawn from origin upon the line = a cos θ + b sin θ are (3 mark)
r
−1 b
l b −1 b l b
(a) l , Tan (b) , Sin −1 l , cos a (d) , Tan −1
a a (c) a
2
a +b
2
2
a +b
2
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Paper - I I I : Chemistry - 101 to 150
A = εbc Equation
where ε is the molar absorptivity in liters per mole per centimeter, b is the length of the path through the solute in
centimeters, and c is the molar concentration. EDTA (ethylenediaminetetraacetic acid) is a nnabsorbing compound
that is often used in photometric titrations, since it forms complexes with many metallic ions, and each mole of EDTA
always reacts with one mole of metal, regardless of the charge on the cation. The ion Bi3+ reacts with EDTA to form
a nonabsorbing complex. However, the concentration of bismuth can be measured by adding to the solution a small
PAGE
amount of Cu2+, which does combine with EDTA to form an absorbing complex. the reactions are:
Cu 2 + + Y 4− CuY 2- (Reacton 2)
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The stability of each complex is indicated by a characteristic equilibrium constant K, where
[BiY − ]
K (BiY − ) = ≈ 1023 (Equation 2) and
[Bi3+ ] [Y 4- ]
[CuY 2− ]
K (CuY − ) = ≈ 1019 (Equation 3)
[Cu 2+ ] [Y 4- ]
Figure 1 shows the results of a titration of a bismuth and copper solution with EDTA. Because the K values of the
bismuth and copper complexes are sp ;arge. ot can be assumed that the two reactions, which occir consecutively,both
go to completion.
0.6
PAGE
1 2 3
mL Y 4- added
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Figure -1
4 5 6
101. How many mL of EDTA must be added befiore the bismuth endpoint is reached? (3 mark)
a) 2 . 5 mL b) 3 . 0 mL c) 4 . 0 mL d) 5 . 0 mL
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102. Why is Cu2+ a good chice to use to locate the Bi3+ endpoint? (3 mark)
a) Because the copper complex is less stable than the bismuth complex
b) Because the copper complex is more stable than the bismuth complex.
c) Because copper and bismuth produce a positive absorbance slope.
d) Because the copper complex produces an especially intense color.
103. If the EDTA solution is 0.1 M, approximately how many grams of Br3+ were present in the slution whose titration is
(3 mark)
shown in Figure 1?
a) 1.9 x 10-1 g b) 2 . 5 x 10-1 g c) 1.9 x 10-2 g d) 6. 2 x 10-2 g
104. Some metal-EDTA complexes can be titrated directly by themselves. Which of the following photometric titration
curves will be produced when the substance tirated and the titrant absorb light, but the product does not? (3 mark)
A
A A A
PAGE
a) b) c) d)
titrant added titrant added titrant added titrant added
105. What would be the effect of placing the solution in a container that was twice as long? (3 mark)
106. If E represents any real element, which of the following statements must be true concerning the element E as shown
(3 mark)
above?
a) The value of A is larger than Z.
b) The value of Z is larger than A.
c) If E is an ion, the value of Z is negative.
d) The value of Z cannot be larger than the value of A.
107. Which of the following is always true of the relationship between A and Z on any given element E ? (3 mark)
PAGE
108. Aspirin is the common name for acetylsalicylic acid. The structure is shown below, what three functional groups are
present in this molecule? (3 mark)
O CH3
O
O
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OH
a) ether, aromatic ring, carboxylic acid b) ester, phenul, carboxylic acid
c) alkene, aromatic ring, carboxylic acid d) alcohol, ether, carboxylic acid
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109. A sample of hydrazine sulphate (N2H6SO4) was dissolved in 100 ml. of water, 10 ml. of this solution was reacted with
excess of ferric chloride solution and warmed to complete the reaction. Ferrous ion formed was estimated and it
required 20 ml. of M/50 potassium permanganate solution. Estimate the amount of hydrazine sulphate in one litre of
(3 mark)
the solution.
Reaction : 4 Fe3+ + N 2 H 4 → N 2 + 4 Fe 2 + + 4 H −
MnO4− + 5FE 2 + 8H + → MN 2+ + 5FE 3+ + 4 H 2O .
a) .065 g b) .325 g c) 6.5 g d) 3.25 g
PAGE
2 6.0M 2.0M 4.5
3 2.0M 6.0M 1.5
Determine the rate expression for the reaction.
a) rate = k[X] [Y] b) rate = k[X]2 c) rate = k [X] d) rate = k [Y]
111. A researcher wishes to have two samples of oxygen gas with the same pressure, volume, and temperature, but with
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(3 mark)
different densitites. Is this possible?
a) Yes, because density is not given in the ideal gas law.
b) Yes, if different isotopes of oxygen are used.
c) No, because once pressure, volume, and temperature of an ideal gas are known, all other parameters are
determined.
d) No, because density is inversely proportional to volume.
112. A crystal sublimes according to the reaction (3 mark)
X 2 (s) R X 2 (g)
Which of the following expressions represents the temperature at which solid crystal is in equilibrium with gaseous
crystal? ( ∆ H =change in enthalpy, ∆ G =change in free energy, ∆ S =entropy change.)
∆H ∆G −∆H ∆G + ∆H ∆S
a) Tequib = b) Tequib = c) Tequib = d) Tequib = ∆ H
∆S ∆S ∆S
(3 mark)
113. What is the correct IUPAC name for the alkene shown below?
114.
a) 2-metylbutyl-2-butene
c) 3-ethyl-5-methyl-2-heptene
PAGE b) 2-methylbutyl-3-butene
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d) 3-ethyl-5-methyl-3-heptene
Acording to Bohr’s theory, the electronic energy of hydrogen atom in the nth Bohr’s orbit given by
−21.76 ×10−19
En = J . Calculate the longest wavelength of light that will be needed to remove an electron from
n2 (6 mark)
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α 2 VT (3 mark)
115. For solids and liquids : C p − Cv = ,
β
C p and Cv representing heat capacities at constant pressure (P) and volume (V), respectively. β is a constant
called the : (Note : T=temperature)
a) coefficient of thermal expansion b) virial coefficient
c) Benedict-Webb-Rubin constant d) isothermal compressibility factor
116. According to the collision model, what three conditions are required for a reaction to occur? (3 mark)
PAGE
statements is/are true? (3 mark)
T1
+
T2
Gº 0
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–
Temperature
T3
I. ∆ Gº at T1 is positive
∂ ∆ Gº
II. = 0 at T3
∆ T P
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20 atmospheres at 27ºC. If the cylinder can hold 2.82 litres of water, calculate the number of balloons that can be filled
(6 mark)
up.
a) 10 b) 8 c) 5 d) 4
120. Once an object falls into a black hole, scientists consider it to have left our universe. That means our universe is:
(3 mark)
a) Open b) Closed c) Isolated d) Entropic
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121. The apparatus below is used to measure the electrode potential of zinc. Indicate which of the statement(s) below is/
are true: (Note the following half reactions : Zn → Zn +2 + 2e ; 2 H + + 2e − → H 2 take place in this system)
(3 mark)
–
e
–
V
e
Salt bridge,
ns
Cathode+
KCl-agar
+I
o
–I
on
s
– Anode H2 o
1 atm
2+ +
Zn H
(1M) (1M) H2
Pt
Zn
I. The two halves of the cell are connected by the salt bridge. It permits a current to flow and the two solutions to
mix.
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II. The hydrogen electrode serves as a reference electrode.
III. The reactions occuring at the zinc electrode as current flows are : Zn → Zn +2 + 2e and 2 H + + 2e − → H 2 .
Which of the given statement(s) match with the main statement.
a) I only b) II only c) I and II only d) II and III only
(3 mark)
122. Direction : Refer to the structures below to answer the following question.
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O OH
Structure A Structure B
What is the relatioship between structure A and B?
a) geometric isomers b) stereoisomers c) tautomers d) There is no relationship
123. At a certain temperature equilibrium constant (Kc) is 16 for the reaction. (6 mark)
PAGE
done each cycle? Neglect losses due to friction. (3 mark)
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23