CHEMISTRY
Paper 2 4 5 4 1 2 1. Tuliskan nama dan angka giliran anda pada ruang yang disediakan. Kertas soalan ini adalah dalam dwibahasa. Soalan dalam bahasa Inggeris mendahului soalan yang sepadan dalam bahasa Melayu. Calon dikehendaki membaca maklumat di halaman belakang buku soalan ini. A Section Two hours and thirty minutes
DO NOT OPEN THIS QUESTION BOOKLET UNTIL BEING TOLD TO DO SO For Examiners Use Question 1 2. 2 3 4 5 6 4. B C Total 1 2 3 4 Full Mark 9 9 10 10 11 11 20 20 20 20 100 Mark Obtained
3.
SULIT
For Examiners Use
2 Section A
Bahagian A
4541/2
[60 marks]
[60 markah]
Table 1 shows the proton number and nucleon number for atoms P, Q, R and S. The letters used do not represent the actual symbols of the atoms.
Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom P, Q, R dan S. Huruf yang digunakan tidak mewakili simbol sebenar atom-atom tersebut.
Atom P Q R S
Proton number
Nombor proton
Nucleon number
Nombor nukleon
6 6 11 12 Table 1
Jadual 1
12 14 24 24
1(a) 1
(a)
[1 mark]
[1 markah]
(b)
1(b) 2
(i) (ii)
P : .. R: ... [2 marks]
[2 markah]
(c)
1(c) 1
X .
[1 mark]
[1 markah]
SULIT
4541/2
For Examiners Use
(d)
(i)
[1 mark]
[1 markah]
(ii)
[1 mark]
[1 markah]
(e)
(i)
[1 mark]
[1 markah]
(ii)
[1 mark]
[1 markah]
(iii)
[1 mark]
[1 markah]
Total A1 9
SULIT
4541/2
Table 2 shows the pH values of solutions V, W, X, Y and Z with a concentration of 0.1 mol dm-3.
Jadual 2 menunjukkan nilai-nilai pH bagi larutan-larutan V, W, X, Y dan Z yang mempunyai kepekatan 0.1 mol dm-3.
Solution
Larutan
V 1
W 4
X 7 Table 2
Jadual 2
Y 10
Z 13
pH value
Nilai pH
(a)
(i)
2(a) 2
neutral:
neutral : .............................................................................................
(ii)
alkaline:
beralkali: ............................................................................................
[2 marks]
[2 markah]
(b)
(i)
2(b)
: .
(ii)
2
: ... [2 marks]
[2 markah]
2(c)(i) 1
(c)
(i)
[1 mark]
[1 markah]
(ii)
2(c)(ii) 1
[1 mark]
[1 markah]
SULIT
4541/2
For Examiners Use
(d)
(i)
[1 mark]
[1 markah]
2(d)(i) 1
(ii)
Distilled water is added to 20.0 cm3 of solution Z to make 100.0 cm3 of solution. Calculate the new concentration of solution Z.
Air suling telah dicampurkan kepada 20.0 cm3 larutan Z untuk dijadikan 100.0 cm3 larutan. Hitung kepekatan yang baru bagi larutan Z.
2(d)(ii)
[2 marks]
[2 markah] 2
Total A2 9
SULIT
For Examiners Use
4541/2
Table 3 shows the apparatus set-up, description and observation for experiment I and II.
Jadual 3 menunjukkan susunan radas, penerangan dan pemerhatian bagi eksperimen I dan II.
Experiment
Eksperimen
I
Carbon Karbon Molten lead(II) bromide Leburan plumbum(II) Heat Panaskan bromida
II
Carbon Karbon Sodium sulphate solution Larutan natrium sulfat
Apparatus set-up
Susunan Radas
Description
Huraian
Observation
Pemerhatian
Gas bubbles are released at the Grey solid is formed at the cathode anode and cathode
Pepejal kelabu terenap di katod Gelembung-gelembung gas dibebaskan di anod dan katod
Table 3
Jadual 3
(a)
3(a) 2
(i)
: .....
(ii)
: .... [2 marks]
[2 markah]
(b)
3(b)(i) 1
Based on experiment I:
Berdasarkan eksperimen I :
(i)
[1 mark]
[1 markah]
SULIT
4541/2
(ii)
[2 marks]
[2 markah]
3(b)(ii) 2
(iii)
[1 mark]
[1 markah]
3(b)(iii) 1
(c)
(i)
[1 mark]
[1 markah]
(ii)
anode:
anod
:
3(c)(ii)
katod
(iii)
Name another solution that will give the same products of electrolysis as in experiment II.
Nama satu larutan lain yang akan memberikan hasil elektrolisis yang sama seperti di eksperimen II. 3(c)(iii)
[1 mark]
[1 markah]
Total A3
10
SULIT
For Examiners Use
4541/2
Diagram 4 shows the apparatus set-up of an experiment to investigate the redox reaction between acidified potassium manganate(VII) solution and iron(II) sulphate solution.
Rajah 4 menunjukkan susunan radas eksperimen bagi menyiasat tindak balas redoks antara larutan kalium manganat(VII) berasid dan larutan ferum(II) sulfat. Carbon A Karbon A Acidified potassium manganate(VII) solution Larutan kalium manganat(VII) berasid
Diagram 4
Rajah 4
(a)
4(a) 1
4(b) 1
(b)
[1 mark]
[1 markah]
(c)
4(c)
[2 marks]
2 [2 markah]
SULIT
4541/2
For Examiners Use
(d)
[1 mark]
[1 markah]
(e)
(i)
[1 mark]
[1 markah]
4(e)(i) 1
(ii)
[1 mark]
[1 markah]
4(e)(ii) 1
(iii)
[1 mark]
[1 markah]
(iv)
[2 marks]
[2 markah] 4(e)(iv) 2
Total A4 10
SULIT
For Examiners Use
10
4541/2
Diagram 5.1 shows the apparatus set up for the reaction between 40.0 cm3 of 0.1 mol dm-3 hydrochloric acid and excess small calcium carbonate chips.
Rajah 5.1 menunjukkan susunan radas untuk tindak balas diantara 40.0 cm3 asid hidroklorik 0.1 mol dm-3 dan ketulan kecil kalsium karbonat berlebihan.
Hydrochloric acid Asid hidroklorik Water Air Calcium carbonate Kalsium karbonat
Diagram 5.1
Rajah 5.1
The volume of gas produced is measured at 30 second intervals. Table 5.2 shows the results obtained.
Isipadu gas yang terhasil telah disukat pada sela masa 30 saat. Jadual 5.2 menunjukkan keputusan yang diperolehi.
Time (s)
Masa (s)
30
60
90
120
150
180
210
240
270
0.00 13.00 22.00 28.50 34.00 39.00 42.50 45.00 45.00 45.00 Table 5.2
Jadual 5.2
(a)
5(a) 2
... [2 marks]
[2 markah]
(b)
SULIT
4541/2
For Examiners Use
5(b) 3
[3 marks]
[3 markah]
SULIT
For Examiners Use
4541/2
5(c)
[2 marks]
2 [2 markah]
(d)
5(d) 1
On the graph that you have drawn in 5(b) sketch a curve that you would get if the experiment is repeated using excess large calcium carbonate chips.
Pada graf yang sama di 5(b) lakarkan lengkung yang diperolehi apabila eksperimen diulangi menggunakan ketulan besar kalsium karbonat berlebihan.
[1 mark]
[1 markah]
(e)
Based on collision theory, explain how the size of calcium carbonate affects the rate of reaction.
Berdasarkan teori perlanggaran, nyatakan bagaimana saiz kalsium karbonat mempengaruhi kadar tindak balas.
... [3 marks ]
[3 markah ]
Total A5 11
SULIT 6
13
4541/2
Compound J
Sebatian J
Compound M
Sebatian M
C4H9OH
Hot Porcelain chips
Serpihan porselin
C3H7COOH
Compound K
Sebatian K
Hidrogen,nikel, 180oC
Compound L
Sebatian L
Diagram 6
Rajah 6
(a)
(i)
[1 mark]
[1 markah]
6(a)(i) 1
(ii)
Compound J has four isomers. Draw the structural formula of one isomer of J.
Sebatian J mempunyai empat isomer. Lukiskan formula struktur bagi satu isomer J.
6(a)(ii)
[1 mark]
[1 markah] 1
(b)
Draw an apparatus set-up that can be used in the laboratory to carry out the conversion of compound J to compound K.
Lukiskan susunan radas yang boleh digunakan di dalam makmal bagi penukaran sebatian J kepada sebatian K.
6(b)
[2 marks]
[2 markah]
SULIT (c)
14
4541/2
The empirical formula of compound L is C2H5. Determine its molecular formula given that the relative molecular mass is 58.
Sebatian L mempunyai formula empirik C2H5. Tentukan formula molekul, jika jisim molekul relatifnya ialah 58.
6(c) 3
[3 marks]
[3 markah]
(d)
Compound K is an unsaturated hydrocarbon while compound L is a saturated hydrocarbon. Describe a chemical test to differentiate compound K and L.
Sebatian K adalah hidrokarbon tak tepu manakala sebatian L hidrokarbon tepu. Huraikan ujian kimia bagi membezakan sebatian K dan L.
... ...
6(d) 3
.. .. [3 marks]
[3 markah]
(e)
6(e) 1 Total A6 11
Name the reagent Y which is used to convert compound J, C4H9OH to compound M, C3H7COOH.
Namakan reagen Y yang digunakan untuk menukarkan sebatian J, C4H9OH kepada sebatian M, C3H7COOH.
[1 mark]
[1 markah]
SULIT
15 Section B
[Bahagian B]
4541/2
[20 marks]
[20 markah]
(a)
Diagram 7.1
Rajah 7.1
(i)
[6 marks]
[6 markah]
(ii)
State the position of element X in the Periodic Table. Explain your answer.
Nyatakan kedudukan unsur X dalam Jadual Berkala unsur. Terangkan jawapan anda.
[4 marks]
[4 markah]
SULIT
16
4541/2
(b)
Diagram 7.2. shows the standard representation for three elements, P, Q and R.
Rajah 7.2 menunjukkan perwakilan piawai bagi tiga unsur, P, Q dan R.
39 19
16 8
12 6
Diagram 7.2
Rajah 7.2
Elements P, Q and R react to form two compounds that have different type of bonds. Using the information in Diagram 7.2, suggest and explain how the two compounds can be formed.
Unsur P, Q dan R bertindak balas membentuk dua sebatian yang mempunyai jenis ikatan yang berbeza. Menggunakan maklumat dalam Rajah 7.2, cadangkan dan terangkan bagaimana dua sebatian tersebut terbentuk.
[10 marks]
[10 markah]
SULIT
17
4541/2
(a)
The major component of glass is silica while in ceramic is silicate. Compare and contrast the properties of glass and ceramic.
Komponen utama kaca ialah silika manakala dalam seramik adalah silikat. Banding dan bezakan ciri-ciri kaca dan seramik.
[4 marks]
[4 markah]
(b)
Modern medicine is used to treat various diseases and symptoms. Table 8.1 shows the medicine used to treat various diseases and symptoms.
Perubatan moden digunakan untuk merawat pelbagai simptom dan penyakit. Jadual 8.1 menunjukkan pelbagai ubatan yang digunakan untuk merawat simptom dan penyakit.
Medicine
Ubatan
B Tuberculosis, Pneumonia
Tuberkulosis, Radang paruparu
Table 8.1
Jadual 8.1
[6 marks]
[6 markah]
18
4541/2
A student carried out an experiment to investigate the effectiveness of soap and detergent in hard water. Soap and detergent is added separately to hard water in Experiment I and Experiment II. Table 8.2 shows the apparatus set-up and observation for the experiment.
Seorang pelajar menjalankan satu eksperimen untuk mengkaji keberkesanan sabun dan detergen dalam air liat. Sabun dan detergen ditambah secara berasingan ke dalam air liat pada Eksperimen I dan Eksperimen II. Jadual 8.2 menunjukkan susunan radas dan pemerhatian bagi eksperimen ini.
Experiment I
Glass rod
Rod kaca
Experiment II
Glass rod
Rod kaca
Initial
Permulaan Detergent + hard water
Detergen +air liat
After stirring
Selepas dikacau
Table 8.2
Jadual 8.2
Based on Table 8.2, compare the effect of soap and detergent on hard water. Which is a better cleaning agent? Explain.
Berdasarkan Jadual 8.2, bandingkan kesan sabun dan detergen ke atas air liat. Agen pembersihan yang manakah lebih baik? Terangkan jawapan anda.
[4 marks]
[4 markah]
(ii)
A mechanic found that his cloth has oily stain. He washed them with detergent. Describe briefly the cleansing mechanism of detergent during washing.
Seorang mekanik mendapati bajunya mempunyai kotoran berminyak. Dia membasuh pakaian itu menggunakan detergen. Huraikan secara ringkas tindakan pembersihan detergen ketika mencuci pakaian itu.
[6 marks]
[6 markah]
SULIT
19
4541/2
Section C
Bahagian C
[20 marks]
[20 markah]
(a)
Diagram 9.1 shows the preparation of lead(II) sulphate from lead(II) oxide.
Rajah 9.1 menunjukkan penyediaan plumbum(II) sulfat daripada plumbum(II) oksida.
Lead(II) sulphate
Plumbum(II) sulfat
Diagram 9.1
Rajah 9.1
(i)
Explain why lead(II) sulphate cannot be prepared directly from lead(II) oxide.
Terangkan mengapa plumbum(II) sulfat tidak boleh disediakan secara terus daripada plumbum(II) oksida.
[2 marks]
[2 markah]
(ii)
Based on Diagram 9.1, describe Step I and Step II used in the preparation of lead(II) sulphate. In your answer, include observation and equations involved.
Berdasarkan Rajah 9.1, huraikan Langkah I dan Langkah II yang digunakan dalam penyediaan plumbum(II) sulfat. Dalam jawapan anda, sertakan pemerhatian dan persamaan-persamaan terlibat.
[8 marks]
[8 markah]
SULIT
20
4541/2
(b)
Diagram 9.2 shows the steps involved to confirm the presence of anion and cation in solid lead(II) carbonate.
Rajah 9.2 menunjukkan langkah-langkah terlibat untuk mengesahkan kehadiran anion dan kation dalam plumbum(II) karbonat.
Lead(II) carbonate
Plumbum(II) karbonat
Reagents:
Bahan:
Aqueous sodium hydroxide, aqueous ammonia, nitric acid, sulphuric acid, lime water
Larutan natrium hidroksida, larutan ammonia, asid nitrik, asid sulfurik, air kapur
Apparatus:
Radas:
Pb2+ ions
Using all reagents provided, describe the methods used to confirm the presence of ions and observation involved.
Menggunakan reagen yang dibekalkan, huraikan kaedah yang digunakan untuk mengesahkan kehadiran ion-ion dan pemerhatian yang terlibat. [10 marks] [10 markah]
SULIT 10 (a)
21
4541/2
210 kJ heat is released when 1 mole of copper is displaced by zinc from copper(II) sulphate solution.
210 kJ haba dibebaskan apabila 1 mol kuprum disesarkan oleh zink daripada larutan kuprum(II) sulfat
Excess zinc powder is added to 50 cm3 of 1.0 mol dm-3 copper(II) sulphate solution and stirred. Calculate the change of temperature in this experiment. [Specific heat capacity of solution, c = 4.2 J g-1 oC-1; Density of solution = 1g cm-3]
Serbuk zink berlebihan ditambah kepada 50 cm3 larutan kuprum(II) sulfat 1.0 mol dm-3 dan dikacau. Hitungkan perubahan suhu dalam eksperimen ini. [Muatan haba tentu bagi larutan, c = 4.2 J g-1 oC-1 Ketumpatan larutan = 1g cm-3 ]
[4 marks]
[4 markah]
(b)
(i)
The bond energies of H H bond is 436 kJ mol-1 , Cl Cl bond is 243 kJ mol-1 and H Cl bond is 432 kJ mol-1. State whether the reaction to form the acidic gas is exothermic or endothermic. Explain your answer. Tenaga ikatan H H ialah 436 kJ mol-1 , ikatan Cl Cl adalah 243 kJ mol-1 dan ikatan H Cl adalah 432 kJ mol-1. Nyatakan samada tindak
balas penghasilan gas berasid tersebut adalah eksotermik atau endotermik. Terangkan jawapan anda.
[4 marks]
[4 markah]
(ii)
[2 marks]
[2 markah]
(c)
Plan an experiment to determine the heat of displacement for the reaction between zinc and copper(II) sulphate solution. Your description must include the following: Procedure of the experiment The method to calculate the heat of displacement.
Rancang satu eksperimen untuk menentukan haba penyesaran bagi tindak balas zink dengan larutan kuprum(II) sulfat. Huraian anda mesti mengandungi maklumat berikut: Prosedur eksperimen Langkah untuk menghitung haba penyesaran.
[10 marks]
[10 markah]
SULIT
For Examiners Use
22
4541/2
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
23
4541/2
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
For Examiners Use
24
4541/2
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
25
4541/2
For Examiners Use
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
For Examiners Use
26
4541/2
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
27
4541/2
For Examiners Use
SPACE FOR YOUR ANSWERS / RUANG JAWAPAN .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... .... 4541/2 Copyright Reserved MARA
[See next page CONFIDENTIAL
SULIT
28
4541/2
1.
This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C.
2.
Answer all questions in Section A. Write your answers for Section A in the spaces provided in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang disediakan dalam kertas soalan.
3.
Answer one question from Section B and one question from Section C. Write your answers for Section B and Section C on the lined pages at the end of the question paper. Answer questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer.
Jawap satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di bahagian akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda.
4. 5. 6. 7.
If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.
8.
The time suggested to complete Section A is 90 minutes, Section B is 30 minutes and Section C is 30 minutes
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit dan Bahagian C ialah 30 minit.
9. 10.