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Acids and Alkalis Page 1

Acid and alkalis : 1985

3. (b)
Three bottles of dilute acid are labelled as X, Y and Z. One of them contains nitric acid,
another sulphuric acid and the remaining one hydrochloric acid. The table below
summarises the results of two tests carried out on the three acids
Observation
Test
X Y Z
Heating with A colourless gas is A colourless Same observation as
marble chips rapidly liberated but the gas is rapidly Y.
reaction soon slows liberated.
down and then stops.
Heating with A colourless gas is Same Yellowish-brown fumes
zinc granules rapidly liberated, and a observation appear above the
colourless solution is as X reaction mixture, and a
obtained. colourless solution is
obtained.

(i) Identify X and Z.


In each case, explain the observation that leads to your identification.
(ii) (1) Name the colourless solution formed in the reaction between zinc and Y.
(2) What will be observed if dilute sodium hydroxide solution is slowly added to the
solution in (ii)(1), until the hydroxide is in excess ?
(iii) Write an equation for the reaction of dilute nitric acid with
(1) marble chips.
(2) zinc granules.
(9 marks)

Acid and alkalis : 1986

2. (b)
(i) Sodium hydrogencarbonate decomposes upon heating to give carbon dioxide. What
volume of carbon dioxide at room temperature and atmospheric pressure can be
obtained by decomposing 1.00 g of sodium hydrogencarbonate ?
(Relative atomic masses : H=1.00, C=12.0, O=16.0, Na = 23.0.
Molar volume of a gas at room temperature and atmospheric pressure 24.0 dm3)

(ii) Baking powder is a mixture containing sodium hydrogencarbonate and a solid acid,
HA.
(1) Why should baking powder be stored in a dry place ?
(2) Write an equation for the reaction between sodium hydrogencarbonate and the acid
HA.
(3) Suggest why sodium hydrogencarbonate is used in baking cakes.
(iii) Give ONE use of sodium hydrogencarbonate in first aid process
(9 marks)

5. (c)
0.27 g of magnesium ribbon was dropped into a conical flask containing 25.0 cm3 of 0.500
Acids and Alkalis Page 2

M sulphuric acid. After reaction, the excess acid was titrated against 0.203 M sodium
hydroxide solution, and 21.50 cm3 of the base were required for neutralization.
(Relative atomic mass of magnesium = 24.3)

(i) Write an equation for the reaction between magnesium and sulphuric acid.
(ii) Suggest a suitable indicator for this titration, and give the colour change at the end-
point.
(iii) From the titration data, calculate
(1) the number of moles of sodium hydroxide used to neutralize the excess acid.
(2) the number of moles of sulphuric acid which have reacted with the magnesium.
(3) the percentage purity of the magnesium ribbon.
(iv) According to the manufacturer, the purity of the magnesium ribbon was 99.6%, but the
purity determined in (iii) (3) was lower than this value.
(1) Suggest a possible reason for this difference.
(2) Suggest how the experimental procedure could be improved to obtain a purity
determination closer to 99.6%.
(10 marks)

Acid and alkalis : 1988

1. (b)
The chart below shows two routes by which atmospheric nitrogen is converted to
fertilizers that can be used by plants:

(i) What is the natural process that can


convert atmospheric nitrogen to
nitric acid in Route I ? Write
balanced equations to illustrate this
process.
(ii) (1) Name the industrial process for
the conversion of atmospheric
nitrogen to ammonia in Route
II, and write a balanced equation
for the conversion.
(2) Knowing that this process is exothermic, give TWO conditions that can
theoretically give a high yield of ammonia and explain your answer.
(iii) Assuming that the effectiveness of a fertilizer is directly proportional to its nitrogen
content per unit mass, determine by calculation whether ammonium nitrate [NH4NO3]
or urea [(NH2)2 CO] is the more effective fertilizer.
(Relative atomic masses : H=1, C=12, N=14, O=16)
(13 marks)

Acid and alkalis : 1989

2. (a)
Acids and Alkalis Page 3

Antacid tablets are used to relieve pains caused by excess acid in the stomach.
The label (in English and Chinese) on a brand of antacid, called “Consonant”, is shown in
the diagram below:

CONSONANT®
Antacid Tablets

Active ingredient : Calcium carbonate


Dosage : 1-2 tablets, 3 times a day
Chew before swallowing

The following experiment was performed by a student to find out the amount of calcium
carbonate in such a tablet :
Steps
(1) A tablet was weighed and ground to a powder, and then added to a conical flask
containing some distilled water.
(2) A few drops of methyl orange indicator were added to the flask. Standard
hydrochloric acid was then added from a burette in small portions, with swirling.
(3) On adding each portion of the acid, the solution in the flask first turned pink and
then yellow upon swirling. Effervescence was also observed.
(4) More acid was added until a permanent pink colour was just observed.

Experimental Results:
Mass of one tablet = 1.20 g
Volume of the hydrochloric acid used = 15.2 cm3

(i) Explain the meaning of the term “standard” in step (2).


(ii) In step (3), explain
(1) the colour changes in the solution.
(2) why effervescence was observed.
(iii) In step (4), explain why a permanent pink colour was observed.
(iv)Calculate the percentage by mass of calcium carbonate in one antacid tablet.
(Relative atomic masses : C = 12.0, O = 16.0,
Ca = 4.0.0)
(v) On the label, it was recommended that the tablets should be chewed before swallowing.
Suggest an explanation for this.
(vi)Antacid tablets containing calcium carbonate are seldom used nowadays. Instead,
magnesium hydroxide is usually used as the active ingredient. Based on the reactions
involved, suggest one reason why magnesium hydroxide is preferred to calcium
carbonate.
(13 marks)

Acid and alkalis : 1990

3. (b)
The formula of a weak alkanoic acid can be represented by
CnH2nCO2H (where n is an integer).
Acids and Alkalis Page 4

A sample of the alkanoic acid weighing 0.355 g was dissolved in about 20 cm3 of water in a
conical flask. The solution was then titrated against a 0.180 M sodium hydroxide solution.
A total of 22.40 cm3 of the alkali was required for complete neutralization.

(i) Explain the meaning of the term ‘weak acid’.


(ii) Describe how the end-point in this titration can be determined.
(iii) Calculate
(1) the number of moles of sodium hydroxide used for the titration.
(2) the relative molecular mass of the alkanoic acid.
(iv) (1) Deduce the molecular formula of the alkanoic acid.
(2) Draw TWO molecular structures for the alkanoic acid.
[Relative atomic masses : H=1.0, C=12.0, O=16.0]
(12 marks)

Acid and alkalis : 1991

2. (a)
A student wished to find out which of the two commercial brands of vinegar, A and B, was
the better buy, i.e. of lower price per gram of ethanoic acid (CH3COOH). The following
table listed some of the information about these two brands:

Price Volume of Concentration of


Brand
vinegar ethanoic acid
A $3.00 250 cm3 50 g dm3
B $6.00 500 cm3 UNKNOWN

The student carried out a titration experiment to determine the concentration of ethanoic
acid in Brand B as follows:
25.0 cm3 of the vinegar was first diluted to 250.0 cm3 with distilled water. 25.0 cm3
portions of the diluted solution were then titrated against 0.10 M sodium hydroxide
solution, using a suitable indicator, until the end-point was reached.
The following results were obtained.

Titration 1 2 3 4
Final reading 2 2 2 2
(cm3) 5.5 5.7 6.2 5.9
0 0 0 0
Initial reading 0 1 1 1
(cm3) .00 .00 .30 .10

(i) Describe, giving the names of the apparatus used, how 25.0 cm3 of the vinegar should
be diluted to 250.0 cm3.
(ii) Suggest a suitable indicator for this titration and state its colour change at the end-
point.
(iii) Based on the titration results, calculate a reasonable average for the volume of the
sodium hydroxide solution used.
(iv) Write the equation for this titration. (Ionic equations will not be accepted.)
(v) Calculate the molarity of ethanoic acid in Brand B.
(vi) Show by calculation which brand of vinegar is the better buy.
(Relative atomic masses: H=1.0; C=12.0; O=16.0)
(13 marks)
Acids and Alkalis Page 5

Acid and alkalis : 1992

1. (a)
A student tried to prepare a sample of a solid salt by reacting copper(II) oxide with
sulphuric acid in the laboratory as shown in the diagram below. The student wrote the
following procedure of the experiment in her notebook:

I. Excess copper(Il) oxide was added to 50.0 cm3 of 2.0


M sulphuric acid in a beaker.
II. The mixture was heated for 2 minutes, and was
stirred continuously during this time.
III. The remaining copper(II) oxide was filtered off.
IV. The filtrate was allowed to cool for one day.

(i) Referring to the above diagram, write down TWO aspects that are considered
UNSAFE in the laboratory.
(ii) (1) Name the salt the student tried to prepare.
(2) Calculate the theoretical mass of the salt that can be obtained.
(iii)Explain why the student heated the reaction mixture in step II.
(iv) The student followed exactly the procedure written in her notebook, but did not obtain
any SOLID salt after one day. Suggest an explanation.
(Relative atomic masses : H=1.0; O=16.0; S=32.0; Cu=63.5)
(8 marks)

2. (a)
Consider the following hazard warning labels :

Label A Label B Label C Label D

Choose TWO labels which should be displayed on a bottle of concentrated nitric acid.
Explain your choice. (3 marks)

2. (b)
What would be observed when concentrated nitric acid is added dropwise to
(i) a saturated solution of iron(II) sulphate?
(ii) zinc granules?
Explain the observations and write appropriate equations.
(6 marks)

2. (c)
Acids and Alkalis Page 6

1.0 g of calcium carbonate is added to 50.0 cm3 of 0.1 M nitric acid. At the end of the
reaction, 55.0 cm3 of a certain gas are collected at room temperature and pressure.
(i) Draw a diagram of the set-up suitable for this experiment.
(ii) Calculate the theoretical volume of the gas which would be liberated at room
temperature and pressure.
(iii)Explain any difference between the theoretical volume and the volume of the gas
collected.
(Relative atomic masses : C=12.0; O= 16.0; Ca=40.0;
Molar volume of gas at room temperature and pressure = 24.0 dm3)
(6 marks)

Acid and alkalis : 1993

1. (b)
Liquid wastes discharged from some factories are acidic and need to be neutralized before
discharging into the sea. A certain factory used slaked lime (calcium hydroxide) to
neutralize its liquid waste, which consisted of 0.5 M hydrochloric acid discharging at a rate
of 20 dm3 per minute.

(i) Why are the liquid wastes neutralized before discharging into the sea ?
(ii) Write an equation for the reaction between hydrochloric acid and slaked lime.
(iii) Calculate the mass of slaked lime required per minute to neutralize the acid present in
the liquid wastes.
(iv) Although slaked lime is cheaper, factories nowadays use sodium carbonate instead of
slaked lime to neutralize their acidic liquid wastes. Suggest a reason.
(Relative atomic masses : H=1.0; O=16.0; Ca=40.0)
(6 marks)

4. (b)
To determine the percentage by mass of calcium carbonate in egg shells, a student added
100 cm3 of 2 M hydrochloric acid to 0.3 g of egg shells in a container. After 30 minutes, all
the egg shells dissolved and 67 cm3 of carbon dioxide were collected at room temperature
and pressure.
(i) Write an equation for the reaction between calcium carbonate and hydrochloric acid.
(ii) Calculate the percentage by mass of calcium carbonate in the egg shells.
(Relative atomic masses : H=1.0; C=12.0; O=16.0; Ca=40.0;
Molar volume of gas at room temperature and pressure = 24.0 dm3)
(4 marks)

Acid and alkalis : 1994

5. (a)
A domestic drain cleaner named ‘RAINBOW’ contains concentrated sulphuric acid as the
active ingredient. A student carried out the following experiment to determine the
concentration of sulphuric acid in ‘RAINBOW’.

1.0 cm3 of ‘RAINBOW’ was diluted to 500 cm3 with distilled water. 25.0 cm3 of the diluted
solution were measured and transferred to a conical flask. The solution in the flask
required 18.2 cm3 of 0.10 M sodium hydroxide solution for complete
Acids and Alkalis Page 7

neutralization.
(i) Name the apparatus used to measure 25.0 cm3 of the diluted solution.
(ii) Calculate the molarity of sulphuric acid in ‘RAINBOW’.
(iii)Suggest ONE disadvantage of using ‘RAINBOW’ for cleaning drains.
(iv) State ONE safety precaution needed when using ‘RAINBOW’. Explain your answer.
(v) If ‘RAINBOW’ is poured into drains blocked with fat, the fat can be removed.
Assuming the formula of fat is
H
|
H—C—OCOR
|
H—C—OCOR (R represents an alkyl group),
|
H—C—OCOR
|
H
explain how ‘RAINBOW’ can remove the fat.
(8 marks)

Acid and alkalis : 1995

7. (a)
The label on a bottle of ‘Effervescent Calcium’ tablets is shown below.

(i) Effervescence occurs when a Effervescent Calcium


tablet of ‘Effervescent Each bottle contains 10 tablets.
Calcium’ is added to water.
Each tablet contains
Based on the information
Calcium carbonate 625 mg
given on the label, explain
Vitamin C 1000 mg
why effervescence occurs.
Citric acid 1350 mg
Write the ionic equation for
Dosage 1 tablet daily
the reaction that occurs.
Administration : Dissolve one tablet in a glass
(ii) Suppose that a student puts a
of water.
tablet of ‘Effervescent
Warning : (1) Keep out of reach of children.
Calcium’ into an excess
(2) Keep …………………..
amount of water and collects
the gas liberated.

(1) Assuming that the tablet completely dissolves, calculate the theoretical volume of
gas liberated.
(2) It is found that the volume of gas collected in the experiment is less than the
theoretical volume calculated in (1). Give ONE reason to explain the difference,
assuming that there is no leakage of gas in the experiment.
(iii)On the label, some words are missing in the second warning statement. Complete the
second warning statement, beginning with the word ‘Keep’. Explain your answer.
(Relative atomic masses C=12.0, O=16.0, Ca=40.0;
Molar volume of gas at room temperature and pressure = 24.0 dm3)
(9 marks)

Acid and alkalis : 1996

6. (b)
Acids and Alkalis Page 8

A , B, C and D are four unlabelled bottles, each


containing one of the following reagents:
2M ammonia solution, 2M ethanoic acid,
2M hydrochloric acid, 2M nitric acid
The following scheme is uscd to identify the
four reagents.

(i) What is the reagent in bottle A ? Explain


why this reagent turns red litmus paper
blue.
(ii) What is the reagent in bottle B ? Write a
chemical equation for the reaction between
this reagent and copper turnings, and a
chemical equation for the formation of the
brown fumes.
(iii) (1) Suggest a test to distinguish between
the reagents in bottles C and D.
(Smelling the reagents is NOT an
acceptable answer.)
(2) State the observable change in this test
and explain your answer.

(8 marks)

9. (a)
The diagram below shows a longitudinal section
of a fire extinguisher. When the extinguisher is
being used, solution X is allowed to mix with the
sodium hydrogencarbonate solution and a
reaction immediately occurs. A jet of aqueous
solution will then be forced out of the
extinguisher.

(i) Suggest what solution X may be.


(ii) (1) Write an ionic equation for the reaction between solution X and the sodium
hydrogencarbonate solution.
(2) Explain why a jet of aqueous solution is forced out of the extinguisher.
(3 marks)
Acid and alkalis : 1997

3.
(a) Suggest ONE method to determine the pH of an aqueous solution.
(b) Arrange the following substances in the order of increasing pH and explain your
answer.
1M ethanoic acid, 1M hydrochloric acid,
1M sulphuric acid
(c) Three solution samples, A, B and C, are being tested for the purpose of perming hair.
The table below lists the pH of these samples :
Sample pH
A 6.5
B 8.5
Acids and Alkalis Page 9

C 10.0
Which sample is most suitable for perming hair answer ? Explain your
(6 marks)

7. (a)
Malachite is a mineral containing copper(Il) carbonate and copper(II) hydroxide. It is
insoluble in water but reacts with dilute sulphuric acid. The procedure for preparing
copper(II) sulphate crystals from malachite is as follows.

Step 1 Pour 50 cm3 of 2M sulphuric acid in a beaker and then warm the acid.
Step 2 Add small portions of powdered malachite to the warm acid while constantly
stirring, until effervescence stops and some powdered malachite remains in
the beaker.
Step 3 Remove the remaining powdered malachite from the solution.
Step 4 Evaporate the solution slowly to obtain copper(II) sulphate crystals.

(i) Write a chemical equation for the reaction which causes the effervescence.
(ii) Why is it necessary to add powdered malachite until some of it remains in the beaker?
(iii)Draw a labelled diagram to show how the remaining powdered malachite can be
removed from the solution.
(iv) Calculate the theoretical mass of copper(II) sulphate crystals, CuSO4.5H20, that can be
obtaincd.
(Relative atomic masses : H=1.0, C=12.0, O=16.0, S=32.1, Cu=63.5)
(8 mark)

Acid and alkalis : 1998

3.
Consider the following substances:
Sodium benzoate, sodij chloride, sodium pypochlorite, Sodium hydrogencarbonate,
sodium hydroxide, Sodium sulphite and monsodium glutamate

(c) Which substance is commonly used as an active ingredient in oven cleaners? Briefly
explain its action.
(3 marks)
5.
Each of five unlabelled bottles contains one of the following chemicals:

2M hydrochloric acid 2M nitric acid


2M sodium chloride solution 2M sodium hydroxide solution
distilled water

Suggest how you would carry out tests to identify the contents of each bottle, using the
materials and apparatus listed below. Your answer should include the observation of each
test.
copper foil, solid copper(II) carbonate, 2M copper(II) chloride solution,
test tubes and a Bunsen burner

(You are NOT required to write chemical equations. Answers in the form of flow diagrams
will NOT be marked.)
Acids and Alkalis Page 10

(8 marks)

6. (a)
(i) A student prepared sodium nitrate solution by reacting 1M sodium hydroxide solution
with dilute nitric acid. The student carried out a titration to determine the amount of
dilute nitric acid required to react with a known volume of 1M sodium hydroxide
solution.
(1) Write the chemical equation for the reaction. (An ionic equation will NOT be
accepted for this question.)
(2) Draw a labelled diagram for the set-up of the titration.
(3) Phenolphthalein can be used to determine the end point of the titration. State the
colour change at the end point.
(4) Suggest how the student can prepare a sodium nitrate solution using the titration
results.
(5 marks)

Acid and alkalis : 1999

2.
For each of the following experiments, state ONE observable change and write a chemical
equation for the reaction involved.
(a) Dilute nitric acid is added to magnesium carbonate powder in a beaker.
(2 marks)

5.
The diagram below shows a bottle of chemical waste in a
school laboratory.
Describe and explain how you would remove kerosene
and iron(III) ions from the chemical waste. k e ro se n e
(You may use any apparatus and chemicals available in a a n a q u e o u s s o lu tio n o f
school laboratory.) iro n (III) c h lo rid e a n d
s o d iu m c h lo rid e
(8 marks)
7. (b)
A student carried out the following experiment to determine the concentration of ethanoic
acid in a brand of commercial vinegar.

’25.0 cm3 of the vinegar was placed in apparatus Y and was then diluted to 25.0 cm3
with distilled water. 25.0 cm3 of the diluted vinegar solution was withdrawn and titrated
against 0.10 M sodium hydroxide solution with phenolphthalein as indicator.’

(i) Write a half-equation for the reaction that occurs at the zinc case of the cell during
discharge.
(ii) State the function of following substances in a zinc-carbon cell.
(1) carbon rod
(2) manganese(IV) oxide
(iii) Suggest a chemical test to show the presence of ammonium ions in the moist paste of
ammonium chloride.
(iv) Explain whether you agree with the following statement.
Acids and Alkalis Page 11

‘Zinc-carbon cells cause more environmental problems than nickel-cadmium cells do.’
(v) Complete and balance the following half-equations for the reactions that occur at the
electrodes of a nickel-cadmium cell.
Cd + OH- → Cd(OH)2
NiO2 + H2O → Ni(OH)2 + OH-
(9 marks)

Acid and alkalis : 2000

7. (a)
The sour taste of citrus fruits is mainly due to citric acid which is a CH2CO2H

weak acid with the following structure:


HO C CO2H

(i) What is the meaning of the term ‘weak acid’? CH2CO2H


(ii) Given that citric acid is a tribasic acid, write a chemical equation for the complete
neutralization of nitric acid by sodium hydroxide solution.
(iii) In a titration experiment to determine the concentration of citric acid in orange juice,
25.0 cm3 of a sample of orange juice required 10.0 cm3 of 0.30 M sodium hydroxide
solution to reach the end-point, at which the citric acid had been completely
neutralized.
(1) Given that the relative molecular mass of citric acid is 192, calculate the
concentration of citric acid, in g dm-3, in the sample of orange juice.
(2) State ONE assumption in your calculation in (1).
(3) Given that the following materials and apparatus, briefly describe how a 0.30 M
sodium hydroxide solution can be prepared.
1.20 M sodium hydroxide solution
distilled water
25.0 cm3 pipette
50.0 cm3 volumetric flask, 100.0 cm3 volumetric flask and
250.0 cm3 volumetric flask (Only one of these flasks should be used.)
(10 marks)
4.
The mass of a sample of copper powder contaminated with copper(II) oxide is known.
Describe how you would conduct an experiment to derermine the percentage by mass of
copper powder in the sample. State the expected observation of the experiment.
(Hint: You may use an acid in the experiment.)
(9 marks)

8. (c)
State whether each of the following statements is true or false. Explain your answer in each
case.
(ii) When concentrated sulphuric acid is diluted, water should be added slowly to the acid.
(2 marks)
Acids and Alkalis Page 12