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JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR TRIAL JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR STPM 2009 JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARAN JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR NEGERI TERENGGANU JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR CHEMISTRY JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR PAPER 1 JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR One hour and forty-five minutes JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR

962/1

Instructions to candidates :

DO NOT OPEN THIS BOOKLET UNTIL YOU ARE TOLD TO DO SO.

There are fifty questions in this paper. For each question, four suggested answers are given. Choose one correct answer and indicate it on the multiple-choice answer sheet provided. Read the instructions on the multiple-choice answer sheet very carefully. Answer all questions.Marks will not be deducted for wrong answers.The total score for this paper is the number of correctly answered questions.

This question paper consists of 14 printed pages.

STPM 962/1 OTI 2 2009

2
Section A

SULIT*(CONFIDENTIAL*)

Four suggested answers labelled A, B, C and D are given for each question. Choose one correct answer.

The mass spectrum of iron shows peaks at mass number of 54, 56, 57, and 58. This shows that A B C D The atoms of iron have different numbers of neutron The sample of iron is radioactive The sample of iron is not pure The atoms of iron have different numbers of proton

Which of the following gases is most likely to exhibit ideal behavior? A B NH3 C4H10 C D CO2 H2

P/atm

217

5.1

-57

374

T/OC

The phase diagram for carbon dioxide is shown above. Which of the following statements is not true? A B C D The melting point of carbon dioxide increases with an increase in pressure. Solid carbon dioxide is denser than liquid carbon dioxide. Solid, liquid and gaseous carbon dioxide cannot exist in equilibrium at 1.0 atm. Carbon dioxide can be solidified at 1.0 atm by greatly reducing the temperature.

The electronic configuration of the outermost shell of an element is 3s2 3p1. What is the proton number for this element? A 3 B 11 C 13 D 15

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STPM 962/1 OTI 2 2009 5

SULIT*(CONFIDENTIAL*)

Which of the following has the biggest radius? A F B Cl C Na+ D Al3+

The information below describes an element, T. Melting point is 44OC Produces acidic oxides Monatomic in solid

Element T could be A B Fluorine Sodium C D Magnesium Phosphorus

The graph shows a property when going across period three. What could the property be?
Property

Proton number

A B C D

Atomic size Ionization energy Electric conductivity Boiling point

Which of the following molecules will not form a hydrogen bond with another similar molecule? A B C D C6H5OH CH3NH2 CH3CHO NH3

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STPM 962/1 OTI 2 2009 9 Valence band

SULIT*(CONFIDENTIAL*)

Conductor band

The diagram shows the conductor and the valence bands. Which of the following elements can be represented by the diagram shown? A B Carbon Magnesium C D Neon Oxygen

10

The shape of a molecule depends on the following factors, except A B C D The number of lone-pair electrons The number of bond-pair electrons The number of attractions between the electron orbitals The number of atoms bonded to the central atom

11

A chemist sketched a graph as shown below.

Rate of reaction

Reactant

Products Time

Which of the following reactions can be represented byb the graph above? A B Esterification Nitration C D Sulphonation Neutralization

12

Which of the following is true about the half life of a first order reaction? A B C D The half life is longer for a catalyzed reaction. The half life is shorter when pressure increase. After the fourth half life, the percentage of the remaining element is 6.25% of the original quantity. The half life is influenced by the concentration of the reactant.

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STPM 962/1 OTI 2 2009 13

SULIT*(CONFIDENTIAL*)

The dissociation of dinitrogen tetroxide into nitrogen dioxide is represented by the equation below.

N2O4 (g)

2NO2 (g)

Ho = + 57.2 kJmol-1

If the temperature of an equilibrium mixture of the gases is increased at constant pressure , the volume of the mixture will A B C D Increase, but only because of a shift of equilibrium towards the right Increase, both because of a shift of equilibrium towards the right and also because of thermal expansion. Stay the same, because any thermal expansion could be exactly counteract any thermal expansion Decrease, because a shift of equilibrium towards the left would more than counteract any thermal expansion.

14

Public swimming pools are often chlorinated to kill bacteria. As an alternative to chlorination silver ions can be used in a concentration of not more than 10-6 moldm-3 and not less than 10-7 moldm-3 of silver ions. Which of the following compounds would, in saturated solution, provided the necessary concentration of silver ion? compound A B C D AgBr AgCl AgIO3 Ag2SO4 solubility product 5 x 10-13 mol2dm-6 2 x 10-10 mol2dm-6 2 x 10-8 mol2dm-6 2 x 10-5 mol3dm-9

15

Distillation of a mixture of bromobenzene (C6H5Br) and steam at a pressure of 101kPa and a temperature of 95oC gave a distillate containing 100g water. The vapour pressure of water at 95oC is 85 kPa. What is the percentage by mass of bromobenzene in the distillate? (RMM C6H5Br = 156.5 ; H2O = 18.0) A B C D 50% 62% 76% 100%

16

Some data relating to magnesium and its compounds are as follows? standard electrode potential of magnesium = -2.38V melting point of magnesium oxide = 2850o C melting point of magnesium chloride = 714o C What is the most suitable method for extracting magnesium metal from its ores? A B C D Electrolysis of aqueous magnesium chloride Electrolysis of molten magnesium chloride Electrolysis of molten magnesium oxide Reduction of magnesium oxide with carbon [Lihat sebelah(Turn over SULIT*(CONFIDENTIAL*)

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STPM 962/1 OTI 2 2009 17

SULIT*(CONFIDENTIAL*)

A current of 8A is passed through molten aluminium oxide using inert electrodes. What will be the approximate volume of gas liberated, measured at s.t.p ? A B C D 2.8 dm3 5.6 dm3 8.4 dm3 11.2 dm3

18

Which one of the following equation correctly defines the enthalpy change of formation of carbon monoxide? A B C D C(s) C(s) C(g) C(s) + O2(g) + O (g) + O2(g) + CO2(g) CO(g) CO(g) CO(g) 2CO(g)

19

The enthalpy changes of formation of gaseous ethane and gaseous ethane are 52 kJmol-1 and 85 kJmol-1 respectively at 298K. What is the enthalpy change of reaction at 298K for the following process? C2H4(g) A B C D + H2(g) C2H6(g)

-137 kJmol-1 -33 kJmol-1 +33 kJmol-1 137 kJmol-1

20

Four isomers of C6H12 are shown below.

CH C H C

CH

CH3 C

C2H5

C2H5 H C C CH3

H C2H5

CH3 CH3

C2H5

C H

C CH3

CH3

Which of the following pairs consists of a pair of cis-trans isomers? A B 1 and 2 1 and 3 C D 1 and 4 2 and 4 [Lihat sebelah(Turn over SULIT*(CONFIDENTIAL*)

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STPM 962/1 OTI 2 2009 21

SULIT*(CONFIDENTIAL*)

Which one of the following is a correct statement about the two alkenes CH3CH2CH=CH2 and CH3CH=CHCH3? A B C D Neither exhibits cis-trans (geometrical) isomerism. Neither may be polymerized Neither reacts with bromine to give 1,4-dibromobutane Neither reacts with hydrogen to form butane.

22

Which one of the following reagents could best be used to distinguish between hex-1-ene and methylbenzene? A B C D Ag(NH3)2+ in H2O Br2 in CCl4 I2 in NaOH 2,4-dinitrophenylhydrazine in CH3OH

23

Compound G has the molecular formula C8H9C1. When compound G is heated with acidified potassium manganate(VII), a compound with the molecular formula C8H6O4 is formed. Compound G is most probably A C

24

Complete the following reaction equation.

`Ethanoyl chloride

2-hydroxybenzoic acid

C D

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STPM 962/1 OTI 2 2009 25

SULIT*(CONFIDENTIAL*)

Aldehyde and ketone are produced through catalytic oxidation of alkenes. One example of the reaction scheme is shown below where ethanal is produced from the oxidation of ethene.

Based on the scheme above, the product formed from catalytic oxidation of but-2-ene is A B C D CH3CH2CHO CH3CH2CH2CHO CH3COCH2CH3 CH2COCH3

26.

A reaction between compound P, CH3COCH2CO2CH2CH3 and phenyihydrazine is the first step in synthesizing Antipyrine, a type of medicine used to control fever. The reaction scheme is as follows.

What could Q be? A B

C D

27.

Why is ethanoic acid a stronger acid in liquid ammonia than in water? A B C D Ammonia is a stronger base than water. The molecules of ethanoic acid form a hydrogen bond with water. Ethanoic acid dissolves better in liquid ammonia than water. Ethanoic acid has a higher enthalpy of hydration.

28

Ethanol is more soluble in water when compared to ethyl ethanoate. Why is this?

A B C D

Ethanol is a polar molecule whereas ethyl ethanoate is not polar. Ethanol is not polar whereas ethyl ethanoate is polar. Hydrogen bonds are formed between the ethanol and water molecules. Hydrogen bonds are formed between ethyl ethanoate molecules. [Lihat sebelah(Turn over SULIT*(CONFIDENTIAL*)

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STPM 962/1 OTI 2 2009 29

SULIT*(CONFIDENTIAL*)

Which of the following compounds produces a white precipitate with ammonia? A C

30.

Reagent R is most probably A B C D Ammonia nitrate Ethanamide Alcoholic ammonia Methylamine

31

In an experiment, diluted hydrochloric acid was added to 2-aminopropanoic acid until the pH of the solution is 2. What is the shape of 2-aminopropanoic acid molecule that exists at this pH? A B C D

32

The scheme shows

A B C D

cationic polymerisation anionic polymerisation coordination polymerisation condensation polymerization

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STPM 962/1 OTI 2 2009 33

10

SULIT*(CONFIDENTIAL*)

Which of the following forms an ionic hydride? A B C D Sodium Silicon Sulphur Chlorine

34

Aqueous aluminium chlorine has a pH less than 7 because A B C D the charge density of the aluminium ion is high. the aluminium ion undergoes hydrolysis aluminium chloride undergoes partial dissociation in water. aluminium chloride is a covalent compound.

35

A tetrachloride of Group 14, XCl4 has the following properties. (i) (ii) (iii) It is easily hydrolysed. Unstable to heat. Decomposes at room temperature according to the equation XCl4 X could be A B C D germanium carbon silicon lead XCl2 + Cl2

36

Which of the following best explain the decreasing thermal stability of the chlorides and oxides in the oxidation state of +4 of the Group 14 elements (carbon to lead ) in the Periodic Table when descending the group? A B C D The bond energy increases. The first and second ionization energy decreases. The standard electrode potential decreases. Presence of the inert pair effect of the s orbital electrons.

37

Which of the following is correct regarding dinitrogen tetroxide, N2O4? A B C D It is polar. It has a V shape It is produced from NO2. It contains one unpaired electron.

38

Which of the following is true with regards to the ammonia molecule? A B C D It is non-polar molecule. It has a trigonal planar shape The H N H bond angle is 107o. It contains two lone pairs of electrons. [Lihat sebelah(Turn over SULIT*(CONFIDENTIAL*)

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STPM 962/1 OTI 2 2009 39

11

SULIT*(CONFIDENTIAL*)

The scheme below shows the reactions between potassium iodide with hot concentrated sulphuric acid, and with aqueous siver nitrate, as well as the solubility of the precipitate Y in concentrated aqueous ammonia. Conc. H2SO4 heat Vapour X

KI(s)

AgNO3 (aq)

Precipitate Y

Conc. NH3

Product

Which of the following is correct with regards to the colour of vapour X, colour of the precipitate Y, and the solubility of Y, in concentrated ammonia? Colour of X A B C D Brown Purple Purple Purple Colour of Y White Yellow White Yellow Solubility of Y, in conc. NH3 Soluble Soluble Insoluble Insoluble

40

Which of the following statements helps to explain why nickel can act as a catalyst in the hydrogenation of ethene at 200 oC according to the equation : H2C = CH2 (g) + H2 (g) A B C D CH3CH3 (g)

Nickel can exhibits variable oxidation states. Nickel has d orbitals that can form temporary bonds. Nickel can form stable intermediate with the reactants. Nickel is neutral in the hydrogenation process of H2C = CH2 .

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STPM 962/1 OTI 2 2009

12
Section B

SULIT*(CONFIDENTIAL*)

For questions 41 through 50, one or more of the three numbered statements 1 to 3 may be correct. Decide whether each of the statements is or is not correct. The responses A to D should be selected on the basis of the following.

1 only is correct.

1 and 2 only are correct.

2 and 3 only are correct.

1, 2 and 3 only are correct.

41

Which of the following depends on the number of solute particles in a given mass of solvent? 1 2 3 Elevation of boiling point of solvent Depression of freezing point of solvent Vapor pressure of solute

42

Hydroxyapatite, Ca5(PO4)3OH is the main constituent of tooth enamel . In the presence of saliva, the following equilibria exist. Ca5(PO4)3OH (s) HPO42- (aq) 5Ca2+ (aq) + 3PO43- (aq) + OH- aq) H+ (aq) + PO43- (aq)

Which of the following statements help to explain why tooth enamel is dissolved more readily when saliva is acidic? 1 2 3 The hydroxide ions are neutralised by the acid The phosphate ion PO42- (aq) accepts H+ (aq) Calcium ions react with acids

43

The dissociation constants, Ka, for three acids are given below: Ka (moldm-3) 4.90 x 10-5 8.32 x 10-5 1.15 x 10-3

Acid phenylethanoic acid 3-hydroxybenzoic acid 2-chlorobutanoic acid

Which of the following statement is/are correct about the acid? 1 2 3 Ka for 2,2-dichlorobutanoic acid is greater than Ka for 2-chlorobutanoic acid [H+] in 1.00 moldm-3 phenylethanoic acid solution is 4.90 x 10-5 3-hydroxybenzoic acid is the strongest acid

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STPM 962/1 OTI 2 2009 44

13

SULIT*(CONFIDENTIAL*)

Under which of the following conditions would the Partition Law not hold? 1 2 3 When the solutions are concentrated When the solute dissociate or associate in the solvents When the temperature changes

45

Which pairs of compounds can react to produce a compound with the following structural formula?

2 3

46

Which of the following compounds can be used to prepare diazonium salt when reacted with nitric acid(III)?

3 47 Which of the following statements explain the increasing thermal stability of the carbonates of the Group 2 elements (beryllium to barium) when descending the group?

1 2 3

When the solutions are concentrated When the solute dissociate or associate in the solvents When the temperature changes

48

Which of the following aqueous cations would give a precipitate when excess ammonia is added to it? 1 Al3+ 2 Zn2+ 3 Cu2+ [Lihat sebelah(Turn over SULIT*(CONFIDENTIAL*)

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STPM 962/1 OTI 2 2009

14

SULIT*(CONFIDENTIAL*)

49

In the diaphragm cell for the manufacture of chlorine by elavtrolysis of brine. The function of the diaphragm

1 2 3

is to separate the anode compartment from the cathode compartment. is to prevent the reaction between chlorine and sodium hydroxide produced. Is to act as catalyst to speed up the electrolysis process.

50

A complex salt with the formula of [Ni(NH3)x(H2O)y]Cl2 has the composition by mass of nickel, 13.98%; and hydrogen, 3.79%. Which of the following statements are true with regards to the complex salt?

1 2 3

The ratio of x to y in the formula of the salt is 2:1. The name of the complex salt is diaquatetraamminenickel(II) chloride. The cis isimer of the complex is optically active.

END OF QUESTION PAPER

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