An addition polymer is a polymer formed by a polymerisation reaction. This is where a double or triple bond breaks and the reagent adds onto the molecule. Polyethylene is formed from a addition polymerisation reaction of ethylene. 1.2.5 Outline the steps in the production of polyethylene as an example of a commercially and industrially important polymer
Requires temperature of 300C and atmospheric pressure Fewer side chains, therefore long chains are nearly linear and pack close on cooling Property Flexibility LDPE More flexible Used for sandwich bags, cling wrap and motor vehicle covers Irregular packing- less strong More amorphous ie. Non-crystalline regions Low, so lighter HDPE Rigid Used for freezer bags Strong due to regular packing Suitable for water pipes Less transparent (more crystalline) higher
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Produces short molecular chains which can have many short branches (2-4C)
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Chain growth polymerisation is started by adding an initiator to the monomer. Most commonly, initiators (eg. Dibutyl peroxide) decompose in light and form free radicals. The feedstocks are provided by ethylene.
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Chemistry Stage 6
1.2.7 Describe the uses of the polymers made from the above monomers in terms of their properties
Styrene
Polystyrene
1.3.1 Gather and present information from first-hand or secondary sources to write equations to represent all chemical reactions encountered in the HSC course
1.3.2 identify data, plan and perform a first-hand investigation to compare the reactivities of appropriate alkenes with the corresponding alkanes in bromine water The reactivity of cyclohexane and cyclohexene can be compared directly using bromine water. They are appropriate because they are both liquids at room temperature and pressure.
1.3.3 analyse information from secondary sources such as computer simulations, molecular model kits or multimedia resources to model the polymerisation process Polymerisation can be modeled using chemical modeling kits. The double bond in the ethylene is broken, and allows for the monomer units to bond together.
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Cyclohexene (C6H10) When added to bromine water, the brown colour of the bromine solution is quickly decolourised. It is an addition reaction. The reactivity of its double bond allows for this quick reaction. Br + H2O l HOBr + Br- + H+ C6H10 (l) + Br2 (soln) ---> C6H10Br2 (soln)
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Cyclohexane (C6H12) When added to bromine water, the brown colour of Br2 remains, but slowly fades due to presence of UV light. It is a substitution reaction.
(soln)
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+ HBr (aq)
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Use Electrical conduit indoors Underground water pipers Transparent sheets and pipes Disposable cups
Chemistry Stage 6
A condensation polymer is the polymer formed from a condensation polymerisation reaction eg. nylon-66, proteins from amino acids 2.2.3 describe the reaction involved when a condensation polymer is formed The monomers will bond together and small molecule (usually water) is lost. eg. organic acid + alkanol --> ester + water
Cellulose is produced from glucose monomer units (produced during photosynthesis) with a flat, rigid and straight structure. It is insoluble in water. CH2OH groups on alternate sides of adjoining glucose units
hyxdroxy groups form H-bonding which in turn results in long, strong cellulose fibres each glucose unit is inverted; tipped "upside down"
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2.2.5 identify that cellulose contains the basic carbon-chain structures needed to build petrochemicals and discuss its potential as a raw material Cellulose structure has three carbon-chain and four carbon-chains present with glucose monomer units and attached hydrogen and hydroxy groups. These basic carbon-chain structures can be changed to be a raw material for production of petrochemicals. Cellulose is biomass and could be used as a fossil fuel. However, work and research must continue before cellulose can be economically viable and efficient to be able to be used as a raw material in today's society.
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Cellulose is an example of a condensation polymer formed from glucose monomer units and the elimination of a water molecule. 50% of most dry plant material consists of cellulose. HO - C6H10O4 - OH HO - C6H10O4 - OH HO -
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2.2.4 describe the structure of cellulose and identify it as an example of a condensation polymer found as a major component of biomass
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Chemistry Stage 6
Monomer is lactic acid Alcaligenes eutrophus can be fed starch, and produced the lactic acid monomers produced by the bacterial digestion of starch waste The bacteria then converts the lactic acid to the PLA polymer PLA is strong, flexible and biodegradable
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Potential use of PLA includes: medical implants, agricultural mulch films, disposable plastics.
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Chemistry Stage 6
Hydrating ethylene by adding water results in the production of ethanol as shown by the equation below: CH2=CH2 + H2O (g)
lCH3-CH2-OH (g)
This is done by passing ethylene and steam over a solid phosphoric acid catalyst. As this is a reversible exothermic reaction, large amounts of water and high pressure will favour the production of ethanol. A working temperature of 300C is needed for this reaction. 3.2.3 describe and account for the many uses of ethanol as a solvent for polar and non-polar substances Ethanol is used as a solvent for many polar and non-polar substances such as:
Glucose and sucrose Carboxylic acids Amino acids Water Food colourings Cosmetics
This is because ethanol is a very polar molecule: the C-O and O-H bonds. Hydrogen bonding also allows ethanol and water to be miscible, along with various other substances. As a result, ethanol can be used widely as a solvent due to bond polarity and hydrogen bonding. 3.2.4 outline the use of ethanol as a fuel and explain why it can be called a renewable resource Ethanol can be used as a fuel because it can readily combust: C2H5OH (l) + 3O2 (g) ---> 2CO2 (g) +3H2O (g) It has been used as a petrol extender in the past. Brazil in the '70s and '80s attempted using ethanol as its major fuel for cars, but the experiment proved too expensive and was abandoned.
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Ethanol can be called a renewable resource because it is made from carbon dioxide, water and sunlight and when burnt produces carbon dioxide and water which can be reconverted to ethanol.
Suitable grain or fruit mashed with water Presence of yeast Air is excluded Temperature of approx 37C
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3.2.2 describe the addition of water to ethylene resulting in the production of ethanol and identify the need for a catalyst in this process and the catalyst used
Chemistry Stage 6
DH = mCDt
Molar heat of combustion can also be defined as minus the enthalpy change for the combustion reaction.
3.3.1 process information from secondary sources such as molecular model kits, digital technologies or computer simulations to model - the addition of water to ethylene - the dehydration of ethanol As before, the reactions were modelled using molecular model kits. Additions of water to ethylene: this caused ethylene to react to form ethanol Dehydration of ethanol: produces ethylene
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The ending -ane/-ene is replaced with -anol eg. ethane and ethanol
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Stem MethEthButPropPentHexHeptOct-
Ethanol; while being promoted as a renewable resource, requires large amounts of energy such as fossil fuels for fertilisers and the distillation process. Ethanol currently has a potential as a liquid fuel when oil runs out, though current technologies have still yet to be developed. More research will have to be conducted to be able to use ethanol as a viable alternative for a fuel. Advantages Disadvantages Current engines can use ethanol up Large areas of agricultural land to 10 to 20% without modifications needed to produce ethanol Renewable resource Subsequent problems eg. Soil erosion, deforestation, disposal of Could reduce greenhouse gas fermentation liquors. emissions ie. Carbon dioxide released in combustion is equal to Less energy released in amount used in synthesis combustion
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Number of carbon atoms 1 2 3 4 5 6 7 8
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3.2.8 assess the potential of ethanol as an alternative fuel and discuss the advantages and disadvantages of its use
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The molar heat of combustion of a compound is the heat liberated when one mole of the compound undergoes complete combustion with oxygen at atmospheric pressure; with the products being carbon dioxide gas and liquid water.
Chemistry Stage 6
substitute for lead additives which are used to boost octane performance adding oxygen to petrol which lowers carbon monoxide emissions
However, it is currently uneconomical to use ethanol as a car fuel, as it is extremely expensive to produce it; especially in the distillation processes.
3.3.4 solve problems, plan and perform a first-hand investigation to carry out the fermentation of glucose and monitor mass changes Yeast and glucose were placed together into water inside a conical flask. The conical flask was sealed with Parafilm and the side had a rubber tube leading into a limewater solution. Before it was allowed to ferment, the entire flask was weighed, and it was also weighed afterwards. The limewater turned milky, indicating that carbon dioxide gas was indeed released during the fermentation. The mass changes were calculated using the data obtained by using the balance.
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Measure mass of spirit burner before lighting Burn fuel until water has changed by 10 degrees Measure mass of spirit after Use ethanol, 1- propanol, methanol
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3.3.6 identify data sources, choose resources and perform a first-hand investigation to determine and compare heats of combustion of at least three liquid alkanols per gram and per mole
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3.3.5 present information from secondary sources by writing a balanced equation for the fermentation of glucose to ethanol
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Chemistry Stage 6
4.2.3 account for changes in the oxidation state of species in terms of their loss or gain of electrons
A gain of electrons is reduction; while a loss is oxidation. In oxidation, the oxidation state of the ion increases and decreases in reduction. 4.2.4 describe and explain galvanic cells in terms of oxidation/reduction reactions
4.2.5 outline the construction of galvanic cells and trace the direction of electron flow
4.2.6 define the terms anode, cathode, electrode and electrolyte to describe galvanic cells Anode- produces free electrons from oxidation Cathode- accepts free electrons due to reduction reaction. Electrode- either anode or cathode, they are connected to an external circuit. Electrolyte- a substance which in solution or molten state conducts electricity. Mnemonic to remember: REDOX: RED(reduction) CAT(cathode) --- AN(anode) OX(oxidation)
4.3.1 perform a first-hand investigation to identify the conditions under which a galvanic cell is produced A galvanic cell is produced when metal plates are placed in their metal solutions, and a salt bridge connecting the two electrolyte solutions. An external circuit must be present so that electrons can flow around. emf generated depends on the nature of the half-cells and the concentration of the electrolytes and the temperature.
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Galvanic cells consist of two-half cells with electrolyte solutions connected by a salt bridge (usually KNO3). Electrons flow through the electrodes into the external circuit, while the salt bridge allows for the migration of ions to maintain electrical neutrality in both electrolyte solutions. The salt bridge must not form any precipitates with ions traveling through it. Electrons flow from the anode to the cathode.
Redox (reduction-oxidation) reactions involve transferring electrons, and resulting in electricity. Galvanic cells are constructed so that one half-cell oxidation produces free electrons, while the reduction half-cell requires electrons. When they are connected, electrons will flow from one half-cell to the other and produce electricity.
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The oxidation state of monatomic ions is the charge on the ion. A change in the oxidation state represents a loss or gain of electrons eg. Fe2+ ---> Fe3+ + e-
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K Na Li Ba Ca Mg Al Zn Fe Sn Pb Cu Ag Pt Au
Chemistry Stage 6
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4.3.4 solve problems and analyse information to calculate the potential requirement of named electrochemical processes using tables of standard potentials and half-equations The emf generated can be calculated by:
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Environmental impact
First largely commercialised battery cell Made portable objects such as torches and clocks possible and feasible Effect on environment is extremely small. The Mn3+ is oxidised to insoluble manganese(IV) oxide and as a result it is immobilised. Small amounts of zinc, NH4 salts and carbon are harmless. Not rechargeable, causing increased landfill
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taking the more positive reduction potential (further down the table); this is the reduction reaction changing the less positive reduction potential (higher up) adding the two values together
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Reduction reaction: Ag2O + H2O + 2e- --> 2Ag + 2OHVery small Considerable amounts of electricity can be produced Constant voltage is produced (1.6V) Long lifespan Easy to store and use Much more expensive to produce than dry cells Can be easily lost due to small size Allows for miniature electrical appliances (watches, hand-held calculators, hearing aids) Non-toxic (so possible inside the body) Not rechargeable, causing increased landfill Small amounts of zinc and silver are harmless to the environment.
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Chemistry Stage 6
Nucleon number too large: The nucleon number is reduced by alpha decay Excess protons: Positrons are released when protons decay
Excess neutrons: Beta radiation is produced when neutrons decay. One extra proton is formed during decay. Alpha Helium nucleus 4 He
2
Composition
2. If its ratio of neutrons to protons lies outside the zone of stability 5.2.2 describe how transuranic elements are produced
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5.2.4 identify instruments and processes that can be used to detect radiation The Geiger-Miller counter can be used to detect radiation by the radiation entering through the end window of the tube and hitting a gas molecule (usually argon). This ionises the argon by knocking an electron off. The high voltage accelerates the electron and ionises more argon molecules and so a cascade of electrons reach the end electrode. This electrical pulse can be amplified and measured. The scintillation counter uses the fact that certain substances when emitting radiation, also emit a flash of light which can be collected and amplified in a photomultiplier. The electrical signal then operates an electronic counter.
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Commercial radioisotopes are produced by placing fuel elements into the reactor core for about one week. The uranium decays to molybdenum-99. During its time in the technetium-99m generator, the Molybdenum-99 continually decays to technetium-99m. When the generator reaches its final destination, the technetium-99m can be extracted without removing it from the heavily shielded container. This is achieved by flowing normal saline solution through the alumina.
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Transuranic (elements with larger mass than uranium) were originally produced by bombarding nuclei with neutrons. As technology developed, transuranic elements were produced by bombarding large nuclei with positive particles of a high velocity such as helium and carbon.
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Beta Electron 0 e
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The conditions under which becomes unstable depends primarily on the ratio of neutrons to protons and the combined number of nuclear particles (nucleons).
Chemistry Stage 6
5.3.2 use available evidence to analyse benefits and problems associated with the use of radioactive isotopes in identified industries and medicine
Low energy emission level is just enough for gamma cameras to detect, yet cause very little damage to the patient
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Low energy emissions mean that safety is enhanced, leading to minimal safety precautions Long half-life means source does not need to be replaced frequently
Problems:
Use of such a radioisotope/detector system requires precision and often requires computer controlled feedback systems; which can be expensive to maintain Radioactive waste must be disposed of using safety procedures; despite its low energy emission levels and long half-life.
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Problems:
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Different forms of technetium-99m means that it will travel to different organs in the body, thus allowing for specific diagnostics
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Short half-life of 6 hours means that radioisotope decays very quickly and causes very little damage to the patient
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23 additional elements with atomic numbers up to 118 have been produced. The first transuranic element was produced in the 1940s within the containment of a nuclear reactor. This element was Neptunium. The most recent production of a transuranic element is element 118 at Russias Joint Institute for Nuclear Research in Dubna.
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5.3.1 process information from secondary sources to describe recent discoveries of elements
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