E B D A C
4.Markovnikov addition of HBr to CH3CH formation of a primary carbocation. initial attack by Br . initial attack by Br. isomerization of CH3CH2CH2Br. formation of a secondary carbocation.
CH2 involves:
5.Consider the dicarbonyl compound A drawn below. Which of the following compounds can be an enol tautomer of A?
c only a only a and c b only a and b 6.Determine the product(s) in the reaction below.
B D C A E
A B D C 9.Which of the following alcohols is most likely to yield a carbocation that is susceptible to rearrangements?
D C E B A
B A C
E A C B D
16.For which of the following alkenes is E-Z isomerism possible? A. CH3CH2CH=CHCH2CH3 B. CH3CH2CH=CHBr C. (CH3)2C=CHCH3 D. H2C=CHCH2CH(CH3)2 A and C B and D A, B, C, and D A, B, C A and B 17. Which of the following alkenes will react fastest with water in the presence of a small amount of H2SO4?
NBS [1]Br2, [2] H2O 9-BBN [1] BH3, [2] H2O2/OH Br2/CCl4 19.What is the relationship between the keto and enol forms of acetone, CH3COCH3? Conformational isomers Same compounds Diastereoisomers Resonance structures Constitutional isomers