Key Idea The ratio of elements in a compound depends on the number of valence electrons. Where are the elements on the periodic table? What do you expect will happen?
Chem 1A, UC Berkeley, Fall 2011 Chem 1A, UC Berkeley, Fall 2011
Stoichiometries of Compounds
Balance the equation.
gases
Bonding Patterns
What patterns do you see in the bonding of C, H, O, and N?
H H C H H H C H H H C H H C H H C H O C O H N H C H H C H
Chem 1A, UC Berkeley, Fall 2011
N H
O H
H H C H H
H H C H H
H
Notice that one electron comes from each atom to make an electron pair bond.
Chem 1A, UC Berkeley, Fall 2011
What patterns do you notice? Use the shell models to explain why properties are periodic.
Chem 1A, UC Berkeley, Fall 2011
Covalent Bonding
1 H Li Na
2 He Be Mg
B Al
C Si
N P
O S
F Cl
Ne Ar
H
For these molecules, each atom contributes one electron to form the covalent bond.
Chem 1A, UC Berkeley, Fall 2011
Slide 10
O2
N2
Resonance Structures
More than one Lewis structure satisfies the octet rule.
SO2
H2 + N2
H3O+
OH!
Measurements indicate both bonds are the same Bond order refers to the number of bonds. The bond between each S and O is
Chem 1A, UC Berkeley, Fall 2011 Chem 1A, UC Berkeley, Fall 2011
Formal Charge
Bonded atoms do not contribute electrons equally.
O!S=O
Formal charge?
S and O each give 2 electrons to the double bond. S gives 2 electrons to the single bond. O gives none.
Draw the Lewis structure of CO.
Chem 1A, UC Berkeley, Fall 2011
..
..
..
..
.. .. ..
overall charge =
H!O=C!O!H
.. .. ..
Wrap-up points:
The valence electrons are involved in bonding between atoms. Atoms have noble gas envy. They bond to get 8 valence electrons. Covalent bond: Atoms share electrons. A formal charge results if each atom in a bonded pair does not contribute equally to the bond.