Definite volume Definite volume Influence the chemical properties of the substance
boiling point
melting point
vapor pressure
density
viscosity
surface tension
solubility
1
Condenses Phases: Water The Intermolecular Forces
Stronger Interactions
3 Major Types:
Ice floats on water. (Life on earth, as we know it, would not be
Dispersion Forces (London Forces)
possible if this were not true.)
Dipole-Dipole Interactions
Density of liquid water = 1.00 g/mL
H-Bonding
Density of ice = 0.917 g/mL
2
(Review from Ch 10) Adding Dipole Moments
Cl Cl (Review from Ch 10)
C C
Cl H
Cl H Cl
Cl
CCl4 CH2Cl 2
µ = 0.0 D µ = 2.0 D
14
Hydrogen Bonds
Dipole-Dipole Interaction Hydrogen bonds is a name given to a very strong dipole-dipole force.
Do not confuse with a covalent bond.
Interaction between opposite partial There is an interaction between a
charges in molecules with a permanent
dipole moment. hydrogen covalently bonded to a strongly electronegative atom (Z
= O, N or F) and
Must have polar molecules
(Remember Ch. 10) A nonbonding electron pair on another strongly electronegative
atom (O, N or F)
Strength of interaction determined by the
size of the dipole. As electrons are pulled away from H by an electronegative atom, what is
left is an unshielded proton that will strongly attract neighboring
electrons
Hydrogen bonds between molecules are drawn using either a dotted line
The negative end of one or a more often a dashed line (see next slide)
molecule interacts with
the positive end of an
adjacent molecule.
Hydrogen bond
Covalent bond
3
London Dispersion Forces
London Dispersion Forces • Weakest of forces.
• Between atoms/molecules that
have no permanent dipole.
Weakest type of interaction. • One instantaneous dipole can
Results from spontaneous, induce another instantaneous
instantaneous charge dipole in an adjacent molecule
separation. (or atom).
All molecules exhibit this type • The forces between
of interaction. instantaneous dipoles are called
Temporary.
London dispersion forces.
• Also known as Induced Dipoles
Strength of interaction increases
• ALL molecules have them
with increasing number of
electrons. • Temporary
• Size depends on
• the number of electrons
• More e– = stronger force.
• shapes of molecules
Example: Which of the following chemicals would have the higher boiling point?
Strengths of Intermolecular Forces Cl2 and I2
Example: Which of the following chemicals would have the higher boiling point? Example: Which of the following chemicals would have the higher boiling point?
CH3 OCH 3 and CH 3 CH2OH NaCl and CH 4
4
The Liquid State The Liquid State
If energy is further removed from a liquid, the The classes of crystalline solids.
molecules (or atoms) will be immobilized by
intermolecular interactions and a solid will form.
Crystalline Solids
Crystalline
Exhibits long-range order. Ionic Solids Molecular Solids Atomic Solids
Pattern: crystal lattice.
Components Components Components
are ions. are molecules. are atoms.
Amorphous
Very little order, but still hard and has a definite
shape.
5
The Solid State: Crystalline Solids The Solid State
The Solid State: Molecular Solids The Solid State: Atomic Solids
+ + +
+ + + + + +
e- e- e-
e- e- e- e- e-
+ + +
+ + + + + +
e- e- e- e- e- e- e- e-
+ + + + + + + + +
Malleable & Ductile - because metal ions can slide past each Interstitial alloys have small atoms
other in crystal. occupying some of the holes in the
Melting Points - relatively high due to strong attractions crystal lattice of the host metal.
between metal ions and electrons. Steel
+ + +
+ + + + + +
e- e- e-
e- e- e- e- e-
+ + +
+ + + + + +
e- e- e- e- e- e- e- e-
+ + + + + + + + +
6
Phase Changes
Phase Changes
Endothermic
(energy is absorbed by material)
A cooling curve for the conversion of gaseous water to ice.
Sublimination
Melting Vaporization
Freezing Condensation
Deposition
Exothermic
(energy is released by the material)
Energy Requirements for State Changes Energy Requirements for State Changes
Solution:
Solution:
7
Tips on Calculations
Note that the same substance will have a different value for specific heat Example 1
for each of its states/phases.
How much energy is required to heat 4.2 grams of water from 12°C
Specific heats are usually (but not always) in J/g (not moles).
to 100°C and convert it to steam at that temperature?
Heats of fusion or vaporization are usually in kJ/mole.
Make sure everything has the correct units.
Calculations:
Energy of melting/freezing = ΔHfusion x mol of substance
Energy of vaporization/condensation = ΔHvap x mol of substance Water @ 12 oC Water @ 100 oC Steam @ 100 oC
Energy of temp change of solid = m x specific heat solid x ΔT
Example 2
What is the final temperature when 50 g of ice is added to 12 fl oz
of 25 oC liquid water? {There are 128 fl oz in 1 gallon and 3785 mL
in 1 gallon. Assume the density of water is constant at 1.00 g/mL
and that the specific heat of water is 4.184 J/(goC).}