Process Technology : Lupotech-T

LDPE 1990 q LLDPE LDPE . LDPE .

CTR

LDPE , ,

90

, . . , single-line 2001 25 40 LDPE , . . LDPE . ( DSM .

Basell Polyolefins Aubette LDPE 32 . Petlin Malaysia 5000 ) . Petlin Sasol Petronas, DSM Stamicarbon Clean Tubular Reactor(CTR) . Lupotech-T . Basell . LLDPE , CTR LDPE LLDPE . Stamicarbon . , LDPE 10% , . LLDPE LDPE . CTR . 40 40 DSM

Basell

. 2004 40

LDPE

Stamicarbon , 20-55

LLDPE monomer LLDPE

LDPE LLDPE . Basell

comonomers , LDPE . .

. LDPE

acetate(EVA) . Basell

Lupotech-T 30% , .

. . 35

ethylene-vinyl

Lupotech-T Lupotech-T . Luposim . Basell , . Stamicarbon (conversion) 1.005 CTR reactor 40% 100%

(transition time) Luposim

10-30 . Luposism . , Basell Luposim

. . CTR . Stamicarbon , CTR . Stephan Damer

CTR pass LDPE 1

tubular 1.002-

. Stamicarbon

'DSM

active-grade slate

' 'non-bumping' spec (tubular) .

. CTR (residence time) onstream times . off-

. Stamicarbon , CTR (bumping)

Stamicarbon 'free license'

1995 60%

CTR , LDPE

. 40% autoclave copolymer , . . LDPE ,

EVA .

Sumitomo Chemical tubular ethylene-methyl methacrylate(EMMA) Sumitomo . , . , reactor u , LDPE LDPE . LLDPE LDPE LDPE . , EVA LLDPE tubular melt flow rate

Sumitomo

'non-bumping' Sumitomo autoclave copolymer

. LLDPE

. Basell .

10 ( 30

National Petrochemical Co(NPC) . LDPE ( 90 ) HDPE/LLDPE swing 125 ) . NPC Amir Kabir Petrochemical 2003 LDPE , Basell Lupotech . 2004 . NPC LDPE Olefins No 9 , . , LDPE

Stamicarbon

Marun Petrochemical CTR . 2005

, LDPE

LDPE (shrink-film) . LDPE , HDPE (stiffness) LDPE (changeability) , . . . LDPE

(laminating film), draw-down . Stamicarbon

LLDPE LLDPE

. Basell (extrusion coating) . LLDPE . PE , PE 65% .

LDPE , LLDPE LLDPE

metallocene LLDPE LLDPE LDPE Stamicarbon 2-4% . . . , 1980 . . . Basell , . LLDPE . Stamicarbon . Stamicarbon , 90

, 2 LLDPE LDPE

LLDPE LDPE metallocene LLDPE 1800 . 1-2% , LDPE . Basell LDPE

6% 12%, LLDPE .

, 5% 8%

LDPE

2002-2005

Process/Technology Beijing Yanshan Petrochemical Petkim Pequiven Amir Kabir Petrochemical+ Daqing General Petrochemical Works DSM Marun Petrochemical+ Shell/CNOOC BASF-YPC Co Pars Petrochemical+ China Turkey Venezuela Iran China Tubular (ExxonMobil) Tubular (CTR-DSM/Stamicarbon) Tubular (CTR-DSM/Stamicarbon) Tubular (Lupotech T-Basell Polyolefin) not decided 200,000 120,000 300,000 300,000 200,000 400,000 200,000 200,000 400,000* 300,000+ 2002 2003 2004 2004 2003 2004 2004 2005 2005 2005

Netherlands Tubular (CTR) Iran China China Iran Tubular (CTR-DSM/Stamicarbon) Tubular (Lupotech T) Tubular (Lupotech T-Basell Polyolefin) not decided

: Stamicarbon/Basell Polyolefins +subsidiary of National Petrochemical Co, Iran *two plants, each of 20 , 1990 LDPE 2010 , , LLDPE . Stamicarbon . . PE LDPE , LLDPE LDPE end-use . Stamicarbon . . LDPE LDPE LLDPE ,

2004-05

. Basell Basell . Basell 2000 Elenac, Montell, Targor , , Basell Novolene Basell

commodity polymer

Equistar . Basell HDPE Spheripol,

Targor Novolen gas-phase PP . PP ABB Lummus Global , Novolen Technology Holdings

. Basell

Lupotech G LDPE

Spheripol, Spherilene . Basell . DPE) Spherilene comoner hexene .

LLDPE HDPE (unimodal gas-phase), Lupotech T . . Basell . 2004

Spherilene(gas-phase ) LLDPE HDPE Hostalen, PP Basell Ziegler Natta metallocene Jam Petrochemical Hostalen, Jam Petrochemical 30 .

Werner Breuers , Spherilene q pipe-grade HDPE medium-density poylethylene(mSpherilene . Breuers , octene butene hexene . . , butene hexene 80% .

octene

octene LLDPE 36% : )

Spherilene licensees (

q Daelim Industrial Basell Daelim Industrial* OPP Petroquimica Ipiranga Petroquimica Haldia Petrochemicals Jam Petrochemical National Organic Chemicals Ltd 130,000 220,000 130,000 260,000 130,000 225,000 300,000 210,000 1994 1995 1996 1999 1999 2000 2004 on hold

: Basell Polyolefins *asset transferred to Hanwha Chemical Spherilene 1992 160 ) speciality polymer Hoechst . . . . Basell policy hostalen . 300 6 ( bimodal reactor .

Breuers . slurry gm/ )

, Basell , Hostalen unimodal bimodal HDPE . Hostalen ,

policy HDPE ,

Hostalen . Hostalen (0.94-0.96 .

(stiffness) . .

canister

. 30-40%

end

bimodal HDPE blow-moulded drum (wall thickness) .

HDPE Hostalen process licensees (

: 1000

) q( ) 195 110 100 110 75 50 200 190 40 340 330 60 200 60 160 140 320 300 300 1964, 1995* 1981 1975 1977 1967 1968 1972, 1997 1980 1980 1983, 1990, 1997 1986, 2000 1987 1992, 1996 1994 1999 2001 2003 2004 2004

Frankfurt-Hoechst, Germany Basell Polyolefins Koln-Knapsack, Germany Ingolstadt-Munchsmunster, Germany Basell Produccion Iberica SL Qenos (Kemcor) National Organic Chemical Industries Safripol Fina Oil and Chemicals Co Tarragona, Spain Altona, Australia Mumbai, India Sasolburg, South Africa Bayport, US

China National Technical Import Corp Liaoyang, China Ipiranga Petroquimica Thai Petrochemical Industry Polisur LG Petrochemical Arak Petrochemical+ Indian Petrochemicals Corp Ltd Amir Kabir Petrochemical+ Basell Polyolefins Jam Petrochemical+ Marun Petrochemical+ Trifuno, Brazil Rayong, Thailand Bahia Blanca, Argentina Yeochon, South Korea Arak, Iran Gandhar, India Bandar Imam, Iran Wesseling, Germany Bandar Assaluyeh, Iran Bandar Imam, Iran

) * plant retrofitted in 1995 with Hostalen + subsidiary of National Petrochemical Co, Iran : Basell Polyolefins Breuers , . Basell Basell HDPE Hostalen .

Jam Petrochemical Amir Kabir Petrochemical(NPC ) Bandar Imam . 10 . Marun Petrochemical . Basell Hostalen 2003 . Breuers metallocene . Dow Chemical Union Carbide polyolefin

Basell .

, .

metallocene ,

Breuers 100

, 2005 , . Breuers

metallocene LLDPE 12

300 2005 33 . Basell metallocene LLDPE

. 2000 . .

Breuers Breuers

, , 'free-licensing' polyolefins 70%

. . .

Basell . Breuers

, National Organic Chemical Industries Ltd . .

olefins/polyolefins

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(2001 ,

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