THESAURUS OF ULTRAVIOLET (UV) SPECTROSCOPY

Compound Identification Assignment Nila Huda (1408100045) Kelas A

Ultraviolet (UV) spectroscopy is one of the most common spectroscopic techniques by UV light absorption that cause an electronic transition. Ultraviolet (UV) Light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV Absorption Spectrum is the pattern of absorption (a plot of ultraviolet absorption intensity as function of wavelenght). Absorption Intensities are rarely described quantitatively energy that was absorpted at the wavelenght. Absorption Band is a peak in UV spectrum represents absorption of energy. Selection Rule is a quantum mechanical rule that describes the types of quantum mechanical transitions that are permitted. Forbidden Transition is one important selection rule states that transitions that involve a change in the spin quantum number of an electronic during the transition are not allowed to take place. HOMO (Higest Occupied Molecular Orbital) is the highest molecular orbital that is uccupied by electron.

Thesaurus of Ultraviolet Spectroscopy Nila Huda - 1408100045

LUMO (Lowest Unoccupied Molecular Orbital) is the lowest molecular orbital that is not uccupied by electron. Lambert-Beer Law is the linear relationship between absorbance and concentration of an absorber of electromagnetic radiation. Molar Absorptivity is a measurement of how strongly a chemical species absorbs light at a given wavelength. It is an intrinsic property of the species. Monochromator (diffraction grating) is an optical device that separates and transmits a mechanically selectable narrow band of wavelengths of light or other radiation chosen from a wider range of wavelengths available at the input. Detector is generally a photomultiplier tube that recovers information of interest contained in a modulated wave. Chromophore is a functional group capable of having characteristic electronic transitions. Auxochrome is a substituent which does not itself act as a chromophore but whose presence bring about a shift of the absorbtion band toward the longer wavelength. Bathochromic Shift (red shift) is a band absorption shift to longer wavelength or lower energy due to increasing stability as result of the presence of an auxochrome or also by decreasing polarity of solvent. Hypsochromic Shift (blue shift) is a band absorption shift to shorter wavelength or higher energy due to decreasing stability as result of the removal of conjugation and also by increasing the polarity of the solvent .

Thesaurus of Ultraviolet Spectroscopy Nila Huda - 1408100045

Hyperchromic Effect is the effect that can increase intensity of absorption band because of increasing concentration of the sample measured. Hypochromic Effect is the effect that can decrease intensity of absorption band because of decreasing concentration of the sample measured. Hyperconjugation is the interaction result from overlap of the C-H bonding orbital with the system. Woodward-Fieser Rules are several sets of empirically derived rules which attempt to predict the wavelength of the absorption maximum ( max) in an ultraviolet spectrum of a given compound. Homoannular Diene is a cyclic diene where the central bond is a part of the ring system and has cisoid (s-cis) orientation both double bonds are in the same ring. Heteroannular Diene is a cyclic diene where the central bond is a part of the ring system and has transoid (strans) orientation both double bonds are not in the same ring. Exocyclic Double Bond is a double bond that lies outside of a given ring.

Thesaurus of Ultraviolet Spectroscopy Nila Huda - 1408100045