2 Name__________________________________

Part I 1. (20 points) Carbon dioxide (CO2 (g)) dissolves in water to produce carbonic acid H2CO3. CO2 + H 2O H 2 CO3 Aluminum carbonate, A12(CO3)3, can be used as an antacid (not the best choice however!). How many grams of aluminum carbonate can be formed from combination of 10.0 L of CO2(g) at STP with 500. mL of 0.543 M A1(OH)3 which react by the following unbalanced equation? Al (OH )3 + H 2CO3 Al2 (CO3 )3 + H2 O

3 Name__________________________________ 2. (15 points) Given the following: H fo (C2 H 2 (g)) = 227 kJ/mole H fo (CO2 (g)) = -393 kJ/mole H fo (H 2O(l )) = -286 kJ/mole H fo (C2 H 4 (g)) = 52.3 kJ/mole (a) Calculate the heat of combustion of C2 H 2 (g) . (b) How much heat in kJ would be evolved in combustion of 1.00 g C2 H 2 (g)?

4 Name__________________________________ Part II Place Answers on Cover Page

1.

A mixture of 1.00 g of HCl and enough water to give 1.00 x 102 mL of solution will have what molarity? (a) 0.274 M (b) 0.548 M (c) 0.0100 M (d) 0.0274 M (e) 0.0548 M

2.

A 10. mL solution of 1.0 M NaOH is required to react completely with how many mL of a 0.25 M solution of H2SO4? (a) 40. mL (b) 160 mL (c) 4.0 mL (d) 10. mL (e) 20. mL

3.

The net ionic equation for the neutralization of sulfuric acid with sodium hydroxide is:
2 (a) SO4 ( aq) + 2 Na + ( aq) Na2 SO4 ( aq) 2 (b) SO4 ( aq) + 2 Na + ( aq) Na2 SO4 ( s )

(c) H 2 SO4 (aq ) + 2OH (aq ) 2 H2 O (l ) + SO42 ( aq) (d) H + ( aq) + NaOH ( aq) H 2O (l ) + Na+ (aq ) (e) H + ( aq) + OH (aq) H 2O (l )

4.

o The H f for CO2(g) is -393 kJ/mole and H rxn for the reaction

2CO(g) + O 2 (g) 2CO2 (g) is -560 kJ. The H o for CO(g) is (in kJ/mole) f (a) +113 (b) -673 (c) -113 (d) -209 (e) -226

5 Name__________________________________ 5. For the reaction 2H 2 (g) + O2 (g) 2H2 O(g) which of the following is true? (a) (b) (c) (d) All reactants and products are in their standard state. o The H f for H2O(g) is -484 kJ/mole. The reaction is exothermic. o The H f for H2O() would be less negative. H = -484 kJ

o o (e) You would need H f (H2(g)) to calculate H f (O2(g)).

6.

Two identical flasks contain O2 and H2 gas, respectively, at the same temperature and pressure. In comparing the two flasks, which of the following is not a true statement. (a) The total mass of each gas is different. (b) The average speed of H2 molecules is greater than that of O2 molecules. (c) The average kinetic energy of H2 is greater than that of O2. (d) The number of molecules of H2 and O2 is the same. (e) The number of moles of H2 and O2 is the same.

7.

If the pressure in a helium-filled balloon is 4.4 atm when filled to 5.0 x 102 L, what volume is occupied by the helium-filled balloon when the pressure is reduced to 1.1 atm? (a) (b) (c) (d) (e) 2.0 x 102 L 2.5 x 102 L 2.2 x 102 L 2.0 x 103 L 3.0 x 102 L

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8.

What is the temperature (K) for 0.500 moles of an ideal gas at 2.00 atm in a 22.4 L container? (a) (b) (c) (d) (e) 0K 273 K 1.09 x 103 K 68.3 K 546 K

9.

How many different orbitals can have the principal quantum number n = 3? (a) 4 (b) 9 (c) 6 (d) 5 (e) 18

10.

Which of the following properties is associated with the value of the quantum number? (a) (b) (c) (d) (e) The number of electrons in an orbital. The size of an orbital. The orientation in space of an orbital. The energy of an orbital. The shape of an orbital.

11.

The number of 5d electrons in the electronic configuration of element 75 (Re) is: (a) 10 (b) 2 (c) 3 (d) 5 (e) 7

12.

Which of the following is not a permitted set of quantum numbers for an orbital in an atom? (a) (b) (c) (d) (e) n = 2, = 2, m = 1 n = 3, = 1, m = -1 n = 1, = 0, m = 0 n = 6, = 1, m = 0 n = 5, = 4, m = -4

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13.

Which of the following represents the electron configuration of an atom of tin (Sn)?

(a) (b) (c) (d) (e)

[Xe]5s24d105p3 [Kr]5s24d105p3 [Kr]4s23d104p3 1s22s22p63s23p64s23d104p65s24d95p3 [Kr]5s24d105p2

Some Potentially Useful Equations for General Chemistry Examinations

MM is molar mass PV = nRT P x MM ( g / mol ) = dRT PVi PV2 i = 2 Ti T2 U = q + w, H = q p for a constant pressure process q = m x C(per gram) x T

v = c

E = hv

h p

p = momentum = mass x velocity for matter

Heisenberg Uncertainty Principle: xp x

h 4 Energy levels for the hydrogen atom: 2.179 x 1018 J En = n2

H o = nH o (products) - mH o (reactants) f f