TEST - 1 (Paper - I)
ANSWERS
CHEMISTRY
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. (B) (A) (A) (C) (D) (A) (B) (A, B, C, D) (A, B, C, D) (A, B, C, D) (A, B, C, D) (B) (B) (C) (A) (B) (4) (5) (8) (4) (5) (4) (2)
MATHEMATICS
24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. (D) (B) (D) (C) (C) (B) (C) (A, B, C, D) (A, B, C, D) (A, B, D) (A, C) (C) (A) (B) (B) (A) (1) (6) (4) (4) (1) (4) (9)
PHYSICS
47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. (A) (D) (C) (A) (A) (A) (C) (A, B, C, D) (A, B, C, D) (A, C) (A, B, C) (A) (D) (A) (C) (A) (3) (4) (6) (5) (3) (8) (5) 1/17
1
B(I)
RH (Z)2
1 2
2
1 3
2
5 RHZ 2 36
36
B(I)
5 RH Z 2
1
L(I)
RH (Z)2
4
1 12
1 22
3 RH Z2 4
L(I) = B(I)
36 5 RH Z
3 RH Z 2
= 59.3 107
88
Z2 = 2.
59.3
10
109678
15
9.0
Answer (A)
v C 1 275
v= v=
C 275
nh 2 mr
v=
2 m
n h 0.529 h 2 m 0.529 10
8
10
n2 Z
n= n=
n=2
1 1 = RHZ2 2 2 1 (n + 2)
1 1 = 109678 2 2 1 4 15 = 109768 = 1.02 105 cm1 16
2/17
Test - 1 (Paper - I) (Answers & Hints) 3. Answer (A) h = h0 + KE KE = h ho (Slope)KE/ = h h = h0 + eVS eVS = h h0 VS =
h h0 e e
S/
(Slope)V
h e
h h e e
(Slope)KE/ (Slope)VS /
4.
Answer (C) m = (2
2 m 1
1)
...(iii)
m 1 2
2m 2 4
...(iv)
(iii) & (iv) are correct. 5. Answer (D) 2Mg(s) + O2(g) 2 mol 2 24 g 1 mol 1 32 g 2MgO(g) 2 mol 2 40 g
48 g Mg required 32 g O2
30 g Mg required
32 30 = 20 g O2 48
All India Aakash Test Series for IIT-JEE - 2013 6. Answer (A) SO2(g) + t=0 Final 10 (10 x)
1 O (g) 2 2
15
Catalyst
SO3(g) 0
15
x 2
x=8 nSO = 8
3 2
nSO = 2
nSO3 nSO2 8 2 4 16
7.
2 x 3
2 x 3
13.6 22
3.4 eV
10.2 eV
3.4 ( 13.6)
1 1 1 = RH Z 2 2 2 nf ni
= 109678 102 Z2
1 1
2
1 22
Z2 = 4
Z
1 nf
2
2, He
1 ni
2
1 1
2
1 2
2
3 4
4/17
Test - 1 (Paper - I) (Answers & Hints) 9. Answer (A, B, C, D) Fact. 10. Answer (A, B, C, D)
Lime stone
(CaCO3 ) Oxalic acid
CaC2O4
KMnO 4
Decolorizes
Meq. of CaCO3 = Meq. of CaC2O4 = Meq of KMnO4 Meq. of CaCO3 = Meq. of CaO in lime stone Meq. of CaO = Meq. of KMnO4
W 1000 = 45 0.2 56/2
2 2 55.55
0.034
1 x2
RH
1 12
He
1
He
4RH , RH
1 4
He
RH
Li 2
1 9 RH
4 9
He
4x 9
5/17
All India Aakash Test Series for IIT-JEE - 2013 13. Answer (B) 6=
(ni nf )(ni nf + 1) 2 ni = 4 nf = 1
1 RH 22 1 1
2
1 42
1 RH 15 = 4
4 15 RH
14. Answer (C) Fact. 15. Answer (A) Fact. 16. Answer (B) Mass of carbon in dot = 2 106 g 12 g C 6.023 1023 atoms 2 106 g C
6.023 1023 2 10 12
= 1.0038 1017 17. Answer (4) Spin multiplicity 2 s + 1 p6 For 3 clockwise ( s ) = Spin multiplicity = 2 18. Answer (5) 19. Answer (8) The next electron will enter into 6d subshell whose (n + l) equal to 8. n=6 l = 2 (for d-subshell) n+l=8 20. Answer (4) dxy, dyz, dxz, dx 2 y 2, contain 2 nodal plane. 6/17
1 1 1 3 + + = 2 2 2 2
3 +1= 4 2
Test - 1 (Paper - I) (Answers & Hints) 21. Answer (5) C3H8(g) + 5O2(g) 1 vol. 1L 5 vol. 5L 3CO2(g) + 4H2O(g) 3 vol. 3L 4 vol. 4L
1 L of propane gas required 5 L volume of O2 gas. 22. Answer (4) Average titre value =
23. Answer (2) Ni2+ 1s2 2s2 2p6 3s2 3p6 4s0 3d8
PART - II (MATHEMATICS)
24. Answer (D)
( (
) )
2 6 tan
y x = 2 tan2 2 2
x y tan cot = 3 2 2
(a
2 1
2 2 + a2 + a3
) (b
2 1
2 2 + b2 + b3 ( a1b1 + a2 b2 + a3 b3 )
2
) z ) (
2
+ 2 + 2 2
2 + 2 + 2 2 + 2 + 2
2
Let
(1 k ) tan4 (1 + k ) tan2 + 1 k =
0
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All India Aakash Test Series for IIT-JEE - 2013 As tan2 is real (1 + k)2 4(1 k)2 0
1 k 3 3
But lets exclude those values of k for which both the roots are negative, as tan2 can't take negative values.
1+ k <0 1 k
k +1 >0 k 1
, k ( , 1] (1 )
1 Hence, the range is , 1 3
27. Answer (C) We have, x + a = a (2cos 2cos2 + 1)
x = 2cos2 2cos a
...(A)
Similarly,
y = 2sin (1 cos ) a
...(B)
2 sin (1 cos )
2cos (1 cos )
x y
cot =
x or cos = y
x x + y2
2
2x 2x 2 2 + 1 x+a=a 2 2 x + y2 x +y
(x2 + y2 + 2ax)2 = 4a2(x2 + y2) 28. Answer (C) If x2 + 4y2 = 4 then let x = 2cos and y = sin f(x, y) = x2 + y2 xy = 4cos2 + sin2 2sin cos = 2(1 + cos2) +
1 (1 cos 2) sin 2 2
3 5 cos2 sin2 + 2 2
5 + 13 2
Test - 1 (Paper - I) (Answers & Hints) 29. Answer (B) Adding we get x(cosy + siny)3 = 27 And subtracting we get x(cosy siny)3 = 1 (cosy + siny)3 = 27 (cosy siny)3 cosy + siny = 3 (cosy siny) tany =
1 2
cos ( B + C ) 1 p sin B C = 1 + p ( )
cos ( B C ) =
1 +p 2 ( p 1)
3 4
1 < cos ( B C ) 1 2
1 2 < p+1 2 ( p 1)
p +1 p 1
0 < 1+
p < 0 or p > 1
p + 1 2 ( p 1)
Also,
2 ( p 1)
p < 0 or p Hence, p
2 1
p 2 +12 0 p 1
2 +1
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All India Aakash Test Series for IIT-JEE - 2013 Alternate Solution tanA + tanB + tanC = tanA tanB tanC 1 + tanB + tanC = p 1+
p + tan B p = 0 tan B
tan2B (p 1) tanB + p = 0 Now this quadratic must have real roots (p 1)2 4p 0 p
2 +1
f ( x + T ) = x + T + a [ x + T + b]
f(x) = f(x + T) x + a [x + b] = x + T + a [x + T + b] [x + T + b] [x + b] = T x + T + b {x + T + b} (x + b) + {x + b} = T {x + b} = {x + b + T} x + b + I = x + b + T ; where I is an integer. T = z ; so any integer is the period of the function. 32. Answer (A, B, C, D)
( 2 + sin x )
; nI 2
Test - 1 (Paper - I) (Answers & Hints) 33. Answer (A, B, D) If f(x + y) = f(x) + 2y3 + kxy x, y R Put x = 0 f(y) = f(0) + 2y3 Put y = 1 f(1) = f(0) + 2 f(0) = 0 f(y) = 2y3 f(x) = 2x3 Put x = y = 1 f(2) = f(1) + 2 + k 8=2+2+k k = 4
1 1 3 f ( x + y ) .f =4=k = 2 (x + y ) . 2 3 x+y (x + y )
f(3) f(2) = 38 34. Answer (A, C)
We have, 2sin x + 6
2 sin x + 6
2 sin2 x + 2 3 sin x cos x + 1
=4
3 sin x + cos x
=4
2 sin x + 6
x= 5 or 3 3
2 sin x + 6
=4
35. Answer (C) The given equation is (1+ a) cosx.cos(2x b) = (1 + a cos2x) cos(x b) ( cos x.cos ( 2x b ) cos ( x b ) ) = a ( cos2x.cos ( x b) cos x cos ( 2x b ) ) cos(3x b) + cos(x b) 2 cos(x b) = a(cos(3x b) + cos(x + b) cos(3x b) cos(x b)) 2sin(2x b)sinx = 2a sinx sinb sinx(sin(2x b) a sinb) = 0 sinx = 0 or sin(2x b) = a sin b S1 = n; S2 =
1 n n + b + ( 1) sin1 ( a sin b ) , n Z 2
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All India Aakash Test Series for IIT-JEE - 2013 36. Answer (A) S2 is non-empty if |a sinb| 1 37. Answer (B) If a = 0
1 5 2cos x + = m + 2 4
To have solution 0 m+
5 25 4 4
Now when m = 5 cosx = 1 x = 2m But which is not possible. 40. Answer (1) cos(1 2) cos(3 4) + cos(1 + 2) cos(3 + 4) = 0 cos1cos2cos3cos4 + sin1sin2sin3sin4 = 0 tan1tan2 tan3 tan4 = 1 tan1tan2 tan3 tan4 = 1 41. Answer (6) The graph of y = 4sin2x and y = tan1tanx
2 Since y = 4 sin x x = = 2 4
y = tan
( tan x ) x =
4
=1
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(0, 2) (0, 4 )
5 3cos2 = 7sin 6sin2 7sin + 2 = 0 (3 sin 2) (2sin 1) = 0, which have four solutions in [0, 2]. 43. Answer (4) |3k + 1| 5 5 3k + 1 5 2k
4 3
Hence four integral values of k satisfy. 44. Answer (1) Since, 0 {x} < 1 cos1 < cos{x} 1
1 1 1 cos { x} < cos 1
1 2
1 <2 cos1
1 1 cos { x} < 2
1 Hence, cos x = 1 { }
13/17
All India Aakash Test Series for IIT-JEE - 2013 45. Answer (4) (sinx + 3cosx) (sinx + cosx) = sin2x + 3 cos2x + 4 sinx cosx = 1 + 1 + cos2x + 2sin2x Maximum value = 2 + 5 = k [k] = 4 46. Answer (9) Consider, f(x) = (cosecx + sinx)2 + (secx + cosx)2 = 4 + (sin2x + cosec2x) + (sec2x + cos2x) Now, sin2x + cosec2x 2 and sec2x + cos2x 2 But the equality holding for different values of x Hence, sin2x + cosec2x + sec2x + cos2x > 4 Hence, f(x) > 8
(f ( x )) = 9
at x =
| v | dt
Integrating
v 0t 1
s=
t , if t 2b t b
2
v0b 1
1 2
, if t > b
48. Answer (D) Area under area versus displacement curve is ads = v
v f2 v i2 2 Area under a-s curve is
f dv .ds = vdv ds vi
So area =
1 1 (5 + 15 ) 10 5 10 2 2
14/17
5 2 v2 so f 2 2
= 75
v f2 = 75 2 + 50
sin =
5 , , ... 3 3
for to be minimum. =
3
1 3 2
2 3 Centripetal acceleration = v
2 2 3 4 m/s2 3
rA = u1 cos
t i
(u1 sin 1 )t
gt 2 j 2
u1 sin
1 2 gt 2
AB = rB rA = ( u2 cos 2 u1 cos 1 ) t i + ( u2 sin 2 u1 sin 1 ) tj = pti + qtj AC = rC rA = ( u3 cos 3 u1 cos 1 ) ti + ( u3 sin 3 u1 sin 1 ) tj = rti + stj
Area =
1 AB AC 2
i j qt st k 0 = ( pr qs ) t 2 k 0
AB AC =
pt rt
v = r
Here, = 5
AB AB
and r = AB
B P v
Now AB = 8i 2 j + 3k 2i + j + k
) (
)
r A
= 6i 3 j + 2k
= 5. 6i 3 j + 2k 62 + 32 + 22
5 6i 7
3j
2k
5 6i 3 j + 2k 5i + j k 2i j k So v = 7
=
) (
5 6i 3 j + 2k 3i 2k 7 15 2i 7 6j 3k
) (
L = 2 g
1 = 1.40 s 2 10
Time measured must have percent error of some order. Let t be total time then percent error in time = t = 500 s Number of oscillations =
500 = 350 1.4
1 1 0 0 = 0 .2 t
16/17
vdv = pdx vn
1 n v dv = 0 x0
v0
Pdx
0
2 v0 n + px0 = 2 n ( )
2 v0 n x0 = p 2 n
Also a =
dv = pv n dt
dv = pdt vn
0 t
v n dv
v0 0
pdt
v0 n + 1 = pt 0 1 n
1 v0 n 1 t0 = 1 n p
x0 t0
1 n p
1 v0 n
v 0 (1 n )
(2 n )
v0 5
1 n v0 = v0 2 n 5
5 5n = 2 n 4n = 3
n=
3 4
17/17
All India Aakash Test Series for IIT-JEE - 2013 54. Answer (A, B, C, D)
j r = 5 cos2t + 2sin2t k
y = 5 cos 2t cos2t =
y 5
z 2
y 2 z2 + =1 25 4
v=
dr dt
= 10 sin2t + 4cos 2t k j
dv dt
j 20 cos2t
(8 sin 2t ) k
4r
Velocity v and r are perpendicular at points A, B, C and D. Time to complete one cycle is
2 second 2
second 4
18/17
( ) 100 =
v A, B = v A v B
= 8 4i j
8 +4
8 2 2
4 Distance between the particles will continuosly increase and they will be at minimum separation at t = 0.
Minimum separation = 57. Answer (A, B, C)
2400 500 cos37 2400 500 4 5
2 2 + 22 = 8 = 2 2
To find the height when the bullet hits the balloon we consider motion along y. y = (500 sin37) 6
1 2
10
62
= 500
3 6 5 36 5
= 1800 180 = 1620 m If t is the waiting time then after (t + 6) second the balloon must be at same height as that of gun. (1620) = (t + 6) 10 + 1000 10t + 60 + 1000 = 1620 10t = 560 t = 56 seconds 58. Answer (A) vx = 4y ; vy = u0
dx = ay dt dy = u0 dt
19/17
dy dy / dt u0 = = dx dx / dt 4 y
4ydy = u dx
0
4y 2 = u0 x 2
2y2 = u0x 59. Answer (D) 60. Answer (A) Solution of Q59 & Q60
dv x dy =4 = 4v y = 4u0 x-component acceleration ax = dt dt
t - axis at an n-axis a = ax
dv y dt
=0
ax i
ay j = 4u0 i
Now
cos =
1 dy 1+ dx
2
1 u 1+ 0 4y
2
4y
( 4y )
2 + u0
sin =
dy / dx 1 dy / dx
2
u0 / 4 y 1 u0 4y
2
(16y
16u0 y
u0
2 2 + u0
2 16 y 2 + u0
2 4u0
Normal acceleration = an = a sin = 61. Answer (C) Let vR = speed of river flow vB = velocity of boat in still water.
d Time in shortest path = v sin = 3t 0 B d Shortest time = v = t 0 B
2 16 y 2 + u0
20/17
Test - 1 (Paper - I) (Answers & Hints) d = 0.5 km here, t0 = 15 minutes also vR vB cos = 0 for shortest path Thus sin =
1 3
or vR = vB cos
2 2 1 2 = 4 2 km 3 h 1 3 4
d 1 2 2d = 1 = = t0 9 3t 0
x=
d (v R cosec v B cot ) vB
dx =0 d
for x to be minimum
3t 0 =
vRd
2 2 vB vR vB
d vB = t 0
vR =
3 d 3 km/h = 2 2t 2
a . b = 2.2 cos60 = 2
If the angle between a and a + b be then
21/17
a. a + b = a a + b cos
or a + a. b = 2 a + b cos or 4 + 2 = 2 a + b cos
2
cos =
3 a+ b
2
Now a + b = a + b
= a + b
+ 2a. b
= 4 + 4 + 2 . 2 = 12
a+b =2 3
cos =
3 2 3
3 2
20 2 sin + 10 10 20 2
10
100
300
20 2 cos 10
at =
dv = 6t dt
at t = 1 s at = 6 m/s2 22/17
atotal =
2 ac + at2 = 62 + 62 = 6 2 m/s2
r2 =
0.552 + 0.432 + 0.052 + 0.362 + 0.082 + 0.052 + 0.00 2 + 0.032 + 0.052 + 0.062 10
0.6354 = 0.06354 10
r = 0.2520 = 0.25 So
r = 0.5 and
r 10 = 5
y 3 x
y 3/2 = 2 k 3 / 2 0
4 k .3 3 = 3
B Rest
Now 6 = 4t
1 1 t2 2
12 = 8t t2 t2 8t + 12 = 0
84 = 2, 6 second 2 2 Distance moved by B in 2 to 6 s is t = 8 64 48 =
1 1 2 2 4 6 + 2 2 ( 6 ) 4 2 + 2 2 ( 2)
(24 + 36) (8 + 4) = 60 12 = 48 = 6 8 Hence, = 8 23/17
All India Aakash Test Series for IIT-JEE - 2013 69. Answer (5) Here, range = 2h tan =
u2 sin ( 2 ) g u sin2 2g
2 sin 2 sin2
2
(h = 0.5 m)
u h
and h =
2gh sin2
= 2gh(1 + 4cot2)
1 2 = gh tan + 2 2
Putting values u2 = 10 u = 5 m/s
11 2 6 + 2 = 25 2
24/17