(Heat) Engines and the (Heat) Engines and the Laws of Thermodynamics Laws of Thermodynamics
Heat Engine: A device that converts heat into Heat Engine: A device that converts heat into mechanical energy mechanical energy Example: Automobile (Car) Engine Example: Automobile (Car) Engine Movie Clip: Animation Car Engine Movie Clip: Animation Car Engine
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
+ +
dynamics=motion dynamics=motion
Thermodynamics=studyofheatandmotion Thermodynamics=studyofheatandmotion
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
FirstLawofThermodynamics FirstLawofThermodynamics
Heataddedtoagas=Q: Heataddedtoagas=Q: Dowork=W Dowork=W (i.e.movesomething) (i.e.movesomething) OR OR (+) (+) Increasetheinternal Increasetheinternal energy(temperature) energy(temperature) ofthegas=U ofthegas=U
Q=W+U Q=W+U
(Remember:=changein=finalinitial,soU=UfUi)) (Remember:=changein=finalinitial,soU=UfUi
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
Detour:Pressure Detour:Pressure
Area
Force
= Pressure
Pressure =
Force F P= Area A
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
Units for Pressure: Units for Pressure: SI unit is the Pascal [Pa] SI unit is the Pascal [Pa]
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics
W = P V = P V f V i
1 1 2 2 Remember: W = K = m v f m v i 2 2
Heat Engines and the Heat Engines and the Laws of Thermodynamics Laws of Thermodynamics Example: Pressure inside a Car Engine Piston Let's calculate the work done on a car going from 0 mph to 60 mph (~27 m/s) Assume a car mass of 850 kg
SecondLawofThermodynamics SecondLawofThermodynamics
Withoutexternalaction,HeatflowsfromHotto Withoutexternalaction,HeatflowsfromHotto Cold. Cold. Whichismoredisorganized(disorderly): Whichismoredisorganized(disorderly): asolid,aliquid,oragas? asolid,aliquid,oragas?
animation animation
Mostorganized Mostorganized Solids Solids Liquids Liquids Gases Gases Leastorganized Leastorganized
SecondLawofThermodynamics SecondLawofThermodynamics
Whichishotter:asolid,aliquid,oragas? Whichishotter:asolid,aliquid,oragas?
LowestTemperature LowestTemperature Solids Solids Liquids Liquids Gases Gases HighestTemperature HighestTemperature Mostorganized Mostorganized Solids Solids Liquids Liquids Gases Gases Leastorganized Leastorganized
SecondLawofThermodynamics
Withoutexternalaction,Coldthingsbecomehot Withoutexternalaction,Coldthingsbecomehot
Hotsystemsaremoredisorderlythancoldsystems. Hotsystemsaremoredisorderlythancoldsystems. =>Withoutexternalaction,orderedthingstend =>Withoutexternalaction,orderedthingstend towarddisorder towarddisorder Entropy=amountofdisorderinasystem Entropy=amountofdisorderinasystem =>Withoutexternalaction,entropyincreases. =>Withoutexternalaction,entropyincreases.
SecondLawofThermodynamics
Consideramachinethatconvertsheattowork: Consideramachinethatconvertsheattowork:
HEAT
Work
Totakealltheheatandconvertittousefulworkwould Totakealltheheatandconvertittousefulworkwould meantakingacompletelydisordersystemandchange meantakingacompletelydisordersystemandchange ittoanorderedsystem. ittoanorderedsystem. ========>VIOLATES2nddLAW<========= ========>VIOLATES2n LAW<========= =>Itisimpossibleforheattobecompletelyconverted =>Itisimpossibleforheattobecompletelyconverted intousefulwork. intousefulwork.
HeatEngines HeatEngines
HEAT
Work
wasteheat wasteheat
=>Someheatmustbeexpelledfromtheengine =>Someheatmustbeexpelledfromtheengine
HeatEngines HeatEngines TH i
Work
wasteheat wasteheat
TLow
Animated Engines Animated Engines
T Hi efficiency=1 T Low
T Hi efficiency=1 T Low
TLow
TLow 0=>efficiencyincreases
TLow =0=>infiniteefficiency!!!
=>ThirdlawofThermodynamics: =>ThirdlawofThermodynamics: YoucantgettoT=0K YoucantgettoT=0K
TH i
TLow
Work
PVGraphs PVGraphs
F P
W = Fd
d
W =P V
V