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COPOLYMERIZATION OF PROPYLENE OXIDE AND CARBON DIOXIDE AND HOMOPOLYMERIZATION OF PROPYLENE OXIDE
Type Patent Inventor GEOFFREY COATES Abstract Copolymers of propylene oxide and carbon dioxide and homopolymers of propylene oxide are made using two dimensional double metal cyanide complexes having the formula Co[M(CN)4] or hydrated or partially dehydrated form thereof. There is no propylene carbonate by product in the copolymerization. Assignee CORNELL RES FOUNDATION INC [ Application Number WO2007US18507 20070822 Priority Numbers : US20060839682P 20060824; US20070889236 20070810 URL http://worldwide.espacenet.com/publicationDetails/biblio? CC=WO&NR=2008024363&KC=&FT=E&locale=en_EP Extra WO2008024363 (A3) US2008051554 (A1) JP2010501668 (A) EP2057199 (A2) EP2057199 (A4) Date Added 4 2555 12:56:47 Modified 4 2555 12:57:54

Polyether carbonate polyols made via double metal cyanide (dmc) catalysis
Type Patent Abstract [0001]The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50C to about 190C and in the presence of from about 0.001 wt.% to about 0.2 wt.% of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt.% to about 40 wt.%, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties. Issue Date 2011 URL http://v3.espacenet.com/textdoc? DB=EPODOC& Date Added 4 2555 15:24:39 Modified 4 2555 15:24:39

Tags:
alkylene, carbonate, catalyst, catalysts, cyclic, ep2287226, glycol, non crystalline, polyether, polyol, propylene

Attachments
textdoc?DB=EPODOC&IDX=EP2287226&F=0

United States Patent: 4500704 - Carbon dioxide oxirane copolymers prepared using double metal cyanide complexes
Type Inventor Inventor Abstract Patent William J. Kruper, Jr. Daniel J. Swart The invention is a process for the preparation of a carbon dioxide oxirane copolymer wherein the process comprises contacting carbon dioxide with an oxirane in the presence of (1) an organic coordination compound and (2) a catalytic amount of a double metal cyanide complex under conditions such that an oxirane carbon dioxide copolymer is prepared. The Dow Chemical Company (Midland, MI) 4500704 February 19, 1985 United States Patent http://patft.uspto.gov/netacgi/nph-Parser? Sect1=PTO1&Sect2=HITOFF&

Assignee Patent Number Issue Date Short Title URL

Accessed 4 2555 15:33:10 Date Added 4 2555 15:33:10 Modified 4 2555 15:33:10

PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS


Type Patent Inventor DARIJO MIJOLOVIC Abstract The invention relates to a process for preparing polyether carbonate polyols by addition of alkylene oxides and carbon dioxide onto H-functional starter substances using DMC catalysts, wherein one or more starter substances are initially placed in the reactor and one or more starter substances are metered continuously into the reactor during the reaction. Assignee BASF SE Application Number EP20080708045 20080121 Issue Date 2009 URL http://v3.espacenet.com/textdoc? DB=EPODOC& Date Added 4 2555 15:37:26 Modified 4 2555 15:39:37

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Zotero Report

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alkylene, atr ftir, carbonate, ep2115032, glycerin, im vergleich, isomere, oxides, polyether, polyols, propandiol

Attachments
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PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS WITH DOUBLE METAL CYANIDE CATALYSTS AND IN THE PRESENCE OF METAL SALTS
Type Patent Inventor AUREL WOLF Abstract The present invention relates to a process for preparing polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO 2 ) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of metal salts. Assignee BAYER MATERIALSCIENCE AG [DE]; WOLF AUREL [DE]; GRASSER STEFAN [DE]; GUERTLER CHRISTOPH [DE]; HOFMANN JOERG [DE] + Application Number WO2011EP52337 20110217 Issue Date 2011 URL http://v3.espacenet.com/textdoc? DB=EPODOC& Date Added 4 2555 15:40:59 Modified 4 2555 15:43:17

Tags:
activation step, butanol, carboxylate, cobalt, cyanide, halogenide, metal salt, oxides, pct11101403, pctep11052337, polyol, tert butanol, wo11101403, woep2011052337

Attachments
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Method for Producing Aliphatic Polycarbonates


Type Inventor Inventor Inventor Inventor Abstract Patent Aktiengesellschaft Basf Johannes Heinemann Gerrit Luinstra Edward Bohres The invention relates to a method for producing high-molecular aliphatic polycarbonates having the following properties: the average molecular weight Mw ranges from 30,000 to 1,000,000, and the content of cyclic carbonates and polyethers equals, in total, a maximum of 5 wt. %. Said polycarbonates are produced by polymerizing carbon dioxide with at least one epoxide while using at least one catalyst selected from the group consisting of zinc carboxylates and multi-metal cyanide compounds. The invention is characterized in that the catalyst is introduced in anhydrous form, and the catalyst is firstly brought into contact with at least a partial quantity of the carbon dioxide before the epoxide is added. Ipc1-7 WO03029325 (A1) DE20011047712 20010927 WO03029240 (A1) DE10147712 (A1) HEINEMANN JOHANNES [DE]; LUINSTRA GERRIT [DE]; BOHRES EDWARD [DE] + (HEINEMANN, JOHANNES, ; LUINSTRA, GERRIT, ; BOHRES, EDWARD) CIB: C07D317/36; C08G64/02; C08G64/18; C08G64/34; (IPC1-7): C08G64/02; C08G64/18; C08G64/34 ECLA: C07D317/36; C08G64/02B; C08G64/18B; C08G64/34

Assignee Patent Number Application Number Priority Numbers Issue Date Extra

Date Added 4 2555 16:48:35 Modified 4 2555 16:48:35

Attachments
Espacenet patent record

A METHOD OF FORMING A POLYETHERCARBONATE POLYOL USING A CO2-PHILIC COMPOUND OR SUBSTITUENT


Type Patent Inventor WERNER HINZ Abstract A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the multimetal cyanide compound in a reactor. The method further pro- vides a CO2-philic compound or a CO2-philic substituent. The CO2-philic compound and substituent enhance incorporation of the CO2 into the polyethercarbonate polyol and reduce formation of cyclic alkylene carbonates, such as cyclic propylene carbonate, which are undesirable byproducts. Patent Number EP1866359 (A1) 2007-12-19 Application Number EP20060708815 20060327 Priority Numbers WO2006EP61067 20060327; US20050092107 20050329 URL http://worldwide.espacenet.com/publicationDetails/biblio? CC=EP&NR=1866359&KC=&FT=E&locale=en_EP Extra EP1866359 (B1) WO2006103213 (A1) US2006224010 (A1) US7671228 (B2) PT1866359 (E) Date Added 5 2555 10:31:17 Modified 5 2555 10:32:18

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United States Patent: 6762278 - Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds
Type Inventor Inventor Inventor Inventor Abstract Patent Werner Hinz Edward Michael Dexheimer Edward Bohres Georg Heinrich Grosch A method of forming a polyethercarbonate polyol using a multimetal cyanide compound is disclosed. The method includes providing a multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the weight of the multimetal cyanide compound and further including at least two of the following components: an organic complexing agent, water, a polyether, and a surface-active substance. Then an alcohol initiator is reacted with at least one alkylene oxide and carbon dioxide under a positive pressure in the presence of the multimetal cyanide compound, thereby forming the polyethercarbonate polyol. BASF Corporation (Mt. Olive, NJ) 6762278 July 13, 2004 United States Patent http://patft.uspto.gov/netacgi/nph-Parser? Sect1=PTO1&Sect2=HITOFF&

Assignee Patent Number Issue Date Short Title URL

Accessed 5 2555 10:32:51 Date Added 5 2555 10:32:51 Modified 5 2555 10:32:51

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