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COPOLYMERIZATION OF PROPYLENE OXIDE AND CARBON DIOXIDE AND HOMOPOLYMERIZATION OF PROPYLENE OXIDE
Type Patent Inventor GEOFFREY COATES Abstract Copolymers of propylene oxide and carbon dioxide and homopolymers of propylene oxide are made using two dimensional double metal cyanide complexes having the formula Co[M(CN)4] or hydrated or partially dehydrated form thereof. There is no propylene carbonate by product in the copolymerization. Assignee CORNELL RES FOUNDATION INC [ Application Number WO2007US18507 20070822 Priority Numbers : US20060839682P 20060824; US20070889236 20070810 URL http://worldwide.espacenet.com/publicationDetails/biblio? CC=WO&NR=2008024363&KC=&FT=E&locale=en_EP Extra WO2008024363 (A3) US2008051554 (A1) JP2010501668 (A) EP2057199 (A2) EP2057199 (A4) Date Added 4 2555 12:56:47 Modified 4 2555 12:57:54
Polyether carbonate polyols made via double metal cyanide (dmc) catalysis
Type Patent Abstract [0001]The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50C to about 190C and in the presence of from about 0.001 wt.% to about 0.2 wt.% of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt.% to about 40 wt.%, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties. Issue Date 2011 URL http://v3.espacenet.com/textdoc? DB=EPODOC& Date Added 4 2555 15:24:39 Modified 4 2555 15:24:39
Tags:
alkylene, carbonate, catalyst, catalysts, cyclic, ep2287226, glycol, non crystalline, polyether, polyol, propylene
Attachments
textdoc?DB=EPODOC&IDX=EP2287226&F=0
United States Patent: 4500704 - Carbon dioxide oxirane copolymers prepared using double metal cyanide complexes
Type Inventor Inventor Abstract Patent William J. Kruper, Jr. Daniel J. Swart The invention is a process for the preparation of a carbon dioxide oxirane copolymer wherein the process comprises contacting carbon dioxide with an oxirane in the presence of (1) an organic coordination compound and (2) a catalytic amount of a double metal cyanide complex under conditions such that an oxirane carbon dioxide copolymer is prepared. The Dow Chemical Company (Midland, MI) 4500704 February 19, 1985 United States Patent http://patft.uspto.gov/netacgi/nph-Parser? Sect1=PTO1&Sect2=HITOFF&
Accessed 4 2555 15:33:10 Date Added 4 2555 15:33:10 Modified 4 2555 15:33:10
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alkylene, atr ftir, carbonate, ep2115032, glycerin, im vergleich, isomere, oxides, polyether, polyols, propandiol
Attachments
textdoc?DB=EPODOC&IDX=EP2115032&F=0
PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS WITH DOUBLE METAL CYANIDE CATALYSTS AND IN THE PRESENCE OF METAL SALTS
Type Patent Inventor AUREL WOLF Abstract The present invention relates to a process for preparing polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO 2 ) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of metal salts. Assignee BAYER MATERIALSCIENCE AG [DE]; WOLF AUREL [DE]; GRASSER STEFAN [DE]; GUERTLER CHRISTOPH [DE]; HOFMANN JOERG [DE] + Application Number WO2011EP52337 20110217 Issue Date 2011 URL http://v3.espacenet.com/textdoc? DB=EPODOC& Date Added 4 2555 15:40:59 Modified 4 2555 15:43:17
Tags:
activation step, butanol, carboxylate, cobalt, cyanide, halogenide, metal salt, oxides, pct11101403, pctep11052337, polyol, tert butanol, wo11101403, woep2011052337
Attachments
textdoc?DB=EPODOC&IDX=WO2011101403&F=0
Assignee Patent Number Application Number Priority Numbers Issue Date Extra
Attachments
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United States Patent: 6762278 - Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds
Type Inventor Inventor Inventor Inventor Abstract Patent Werner Hinz Edward Michael Dexheimer Edward Bohres Georg Heinrich Grosch A method of forming a polyethercarbonate polyol using a multimetal cyanide compound is disclosed. The method includes providing a multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the weight of the multimetal cyanide compound and further including at least two of the following components: an organic complexing agent, water, a polyether, and a surface-active substance. Then an alcohol initiator is reacted with at least one alkylene oxide and carbon dioxide under a positive pressure in the presence of the multimetal cyanide compound, thereby forming the polyethercarbonate polyol. BASF Corporation (Mt. Olive, NJ) 6762278 July 13, 2004 United States Patent http://patft.uspto.gov/netacgi/nph-Parser? Sect1=PTO1&Sect2=HITOFF&
Accessed 5 2555 10:32:51 Date Added 5 2555 10:32:51 Modified 5 2555 10:32:51
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