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# MSE 230

## HW10 (due 04/08, 04/09)

Spring 2010

This assignment covers polymers and composites over two weeks. It is due in recitation the week after the exam, so that you do not have a homework assignment due the week of the exam. 1. In order to get an idea of the size and number of macromolecules that constitute polymers: (a) Calculate the length of individual polyethylene molecules having molecular weight of 10,000, 100,000 and 1,000,000 g/mol if the molecules were straightened as in Fig. 14.5(b) so the carbon atoms all lie in a plane (i.e., straight end-to-end length not including the zigzagging). The carbon-carbon bond length is 0.155 nm and the tetrahedral bond angle is 109. (b) Polyethylene has a density of ~1 g/cm3. Calculate the number of molecules in 1 cm3 of polyethylene having the three molecular weights in part (a). 2. The table shows the molecular weight data measured for a particular polytertrafluoroethylene (Teflon). (a) Plot histograms for the molecular weight distribution on a number basis (Number fraction of molecules) and on a weight basis (Weight fraction of molecules). (b) Calculate the number-average molecular weight and the weight-average molecular weight. (c) If the price of the polymer were proportional to its molecular weight, which of these averages would be better to use if you were the buyer versus the seller. Explain. 3. Sketch the repeat unit structure and explain briefly the rank order of the melting temperatures of the following thermoplastics in terms of intermolecular bonding energy.
Molecular Weight Range (g/mol) 10,000 20,000 20,000 30,000 30,000 40,000 40,000 50,000 50,000 60,000 60,000 70,000 70,000 80,000 80,000 90,000 xi 0.03 0.09 0.15 0.25 0.22 0.14 0.08 0.04 wi 0.01 0.04 0.11 0.23 0.24 0.18 0.12 0.07

## TM (C) 137 175 212 327

4. (a) Why does the elastic modulus value for individual polymers (Table 15.1) vary so much compared to those for individual metals and ceramics? (b) What is the structural origin of the 3 to 5 times higher elastic modulus in HDPE compared to LDPE? (c) Briefly explain how and why the yield strength of a semi-crystalline polymer depends on each of the following: (i) molecular weight, (ii) degree of crystallinity, (iii) deformation by drawing. 5. Bungee cords are sized to the jumper to stretch to a strain of about 3 (300%). Lower strains would create g-forces on the jumper that are too high (decelerate too fast) and higher strains would reduce the safety factor (fracture stress/stress in the cord at the max strain). For an elastomer exhibiting the stress-strain behavior shown in Fig. 15.1C: (a) Calculate the diameter of cord for a strain of 3 with a 75-kg jumper; approximate E as linear up to = 3. (b) Estimate the safety factor for this case. Physics: By equating the gravitational potential energy of the jumper at a height equal to the maximum length of the cord (mgLf) and the strain energy stored in the stretched cord 2mg ( + 1) (E2A0L0/2), the design equation for the cord size is, A0 = . E 2