Problem Set for 3rd Long Exam due: 09 October 2009 Some topics are not discussed (yet).

Do read on them. On Molecular Orbitals 1. What is the molecular orbital configuration of Ne2? (1pt) 2. What is the bond order of F2+? (1pt) 3. Between O2 and O22+, which is diamagnetic? (1pt) On Condensed Phases: Solids and Liquids 1. Unit cells are the repeating structures of what particular solids? (1pt) 2. Among the types of solids according to bond between particles, which is expected to only conduct electricity when dissolved in water? (1pt) 3. Increase or decrease: What happens to the energy gap as one goes from insulating to conducting solids? (1pt) 4. Increase or decrease: As the strength of intermolecular forces of attraction increases, what happens to viscosity and surface tension properties of substances? (1pt) 5. Increase or decrease: As the molecular weight increases, what happens to the boiling point of non polar linear substances? (1pt) 6. NaF or KF: Which will exhibit a higher melting property? (1pt) On Heat Transfer & Phase Diagrams Consider the phase diagram shown for #s 1-3, 1. The substance is in what state (solid, liquid or gas) 1.15 atm at room temperature and sea-level pressure? (1pt) tmatmP 2. What phase change happens at 30C and 1atm? 1 atm (1pt) tmatm 0.9 atm 3. What are the critical temperature and critical tmatmP pressure values for the substance? (1pt) o 4. Calculate the mass (in g) of H2O at 50.0 C converted to steam at 120oC if 1000.0 kJ of 13C 30C 39C tmatm energy is absorbed. The molar heat of vaporization tmatm tmatm Temperature of water is 40.7 kJ/mol and the molar heat capacities of liquid water and steam are 75.3 J/mol-oC and 36.4 J/mol-oC, respectively. (2pts) 5. What is the normal atmospheric pressure of a certain high-altitude place if the water boils at 94oC in that area? The molar heat of vaporization of water is 40.7 kJ/mol. (2pts) On Gases 1. Three 5-L flasks, fixed with pressure gauges and small valves, each contain 4g of gas at 273 K. Flask A contains H2, flask B contains He and flask C contains CH4. Rank flask contents in terms of a. pressure *answer: A > B > C b. diffusion rate after the valve is opened (1pt) c. total kinetic energy of the molecules (1pt) d. density (1pt) * answer is provided for (a) to set an example. use >, =, and < signs only. 2. For each of the following, which shows the greater deviation from ideal behavior at the same set of conditions? a. argon or xenon (1pt) b. water vapor or neon (1pt) c. mercury vapor or CH4 (1pt)
Pressure

3. A sample of a liquid hydrocarbon known to consist of molecules with five carbon atoms is vaporized in a 0.204-L flask by immersion in a water bath at 1010C. The barometric pressure is 767 torr, and the remaining gas condenses to 0.482 g of liquid. What is the molecular formula of the hydrocarbon? (3pts) 4. Hemoglobin is the protein that transports O2 through the blood from the lungs to the rest of the body. In doing so, each molecule of hemoglobin combines with four molecules of O2. If 1.00 g of hemoglobin combines with 1.53 mL of O2 at 37.00C and 743 torr, what is the molar mass of hemoglobin? (3pts) Hm + 4O2(g) Hm(O2)4 On Solutions 1. A mixture which contains 0.550 g camphor and 0.045 g of an organic solute freezes1t 157.0 deg C. The solute contains 93.46% of C and 6.54% of H by weight. What is the molecular formula of the compound? Given: Kf of camphor = 37.7 deg C/molal, and Tf of camphor = 178.4 deg C. (3pts) 2. A solution of an unknown non-volatile non-electrolyte was prepared by dissolving 0.250 g of the substance in 40.0 g of CCl4. The boiling point of the resultant solution was 0.357 deg C higher than that of the pure solvent. Calculate the molar mass of the solute. (Kb for CCl4 = 5.02 deg C/molal) (3pts) 3. The osmotic pressure of 0.010 M solution of CaCl2 and urea at 250C are 0.605 and 0.245 atm, respectively. Calculate the vant Hoff factor for CaCl2. (3pts) On Acids & Bases 1. Given the following reactions, arrange the acids [HCOOH, H2S, HBrO, (COOH)2, C6H5OH] in order of increasing acid strength. (5pts) no reaction NaBrO + C6H5OH 2 NaBrO + H2S 2 HBrO + Na2S 2 C6H5OH + Na2S H2S + 2 C6H5ONa H2S + HCOONa no reaction 2 HCOOH + (COONa)2 2 HCOONa + (COOH)2 2. With the concept of conjugate acid/base pair, arrange the conjugate bases of the above acids in order of increasing basic property. (5pts) 3. A solution was tested to be of pH = 4.38. If 15.0 mL of 0.100 M of KOH was added to 25.0 mL of H2SO4 to prepare the given solution, what is the concentration of the acid used? (3pts)

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chem16:gee_lian