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CHEMISTRY TEST ELECTROCHEMISTRY I and II

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Std: XII Sub:Chemistry

Marks : 100 Time : 2.30 Hrs

Choose and write the best answer: 1.An example for semiconductors is a) benzene b) glass c) cobalt oxide

(17 x 1 =17)

d) none

2. Ostwalds dilution law is applicable in the case of the solution of ............... a) CH3COOH b) NaCl c) NaOH d) H2SO4 3. Which of the following shows abnormal colligative properties a) sugar b)urea c) NaCl d) all the above

4.For strong electrolytes,the degree of dissociation() is equal to a) 0.1 b) 0 c)1.0 d) infinite

5. The laws of electrolysis were enunciated first by ............... a) Dalton b) Faraday c) Kekule d) Avogadro 6. Equivalent conductance is equal to molar conductance for electrolytes like a) AlCl3 b) K2SO4 c) NaCl d) all the above

7. Using Debye Huckel Onsagar equation, the plot of C versus C for strong electrolytes gives intercept equal to a) A+ B b) 1- c) d)

8.The quantity of electricity needed to deposit 1 gm equivalent of Al3+ is a) 1F b) 2F c) 3F d) 0.5F

9. When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid a) increases b) decreases c) does not change d) becomes zero 10.Which of the following is not a buffer solution a) CH3COOH+ CH3COONa b) NH4OH+NH4Cl c) H2SO4 +Na2SO4 11.For a buffer solution having equimolar amounts of acid and salt a) pH= pKa d) pKa = 0 b)pH = pOH c) pH = 1 d) none

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12.The pH of buffer containing equimolar amounts of acetic acid and sodium acetate is a) 1.0 d) 0 b) 14.0 c) 4.77

13.The pH range of phenolpthalien indicator is a) 6.8-8.4 b) 3.1-4.4 c) 4.4 6.2 d) 8.3 10

14. The suitable indicator for the titration of CH3COOH Vs NaOH is a) methyl orange d)none b) phenolpthalien c) phenol red

15. The pH of 0.001 M HCl solution a) 3 b) 1 c)2 d) 4

16. The process in which chemical change occurs on passing electricity is termed as ............... a) neutralisation b) hydrolysis c) electrolysis d) ionisation 17. The specific conductance of a 0.01 M solution of KCl is 0.0014 ohm-1 cm-1 at 25oC. Its equivalent conductance is ............... ohm1 cm2 eq1 a) 14 b) 140 c) 1.4 d) 0.14 Answer in one or two sentences (any 11) ) 1. Define Faraday. equivalent. 3. What are insulators. Give examples. 0.02M Ba(OH)2. (11 x 3 = 33

2. Define electrochemical 4. Calculate the pH of

5. What is common ion effect. Give examples. 6. What is a buffer solution ? Write its types with ex. 7. What are pH indicators ? Give ex. 8. What is ionic product of water?write its value. 9. Define specific and equivalent conductance. How are they related ? 10. A conductance cell has platinum electrodes, each with 5 cm2 area and separated by 0.5 cm distance. What is the cell constant? 11. What is the electrochemical equivalent of a substance when 150 gm of it is deposited by 10 ampere of current passed for 1 sec ? 12. State Faradays first and second laws.

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( 10 x

Answer in brief (Any 10).Qn.no.13 is compulsory 5 = 50 ) 1.Write the evidences of Arrhenius theory. 3. Write notes on Ostwalds theory of indicators. 5.Write notes on Quinonoid theory of indicators. law. 7.Derive the relation between emf and free energy. determined? 9. Explain the construction and working of SHE. with example. 11.Write the IUPAC conventions for writing cell diagram. 12.Derive Nernst equation.

2. Derive Henderson equation. 4. Explain Ostwalds dilution law. 6. State and explain Kohlrauschs 8.How emf of a half cell 10. Explain buffer action

13.(a) The Ka of propionic acid is 1.34 x10-5. What is the pHof a solution containing 0.1 M propionic and 0.001 M sodium proportionate ? (b) Calculate the E.M.F. of the zinc - silver cell at 25oC when [Zn2+] = 0.10 M and [Ag+]=10 M. (Eo cell at 25oC = 1.56 volt] (or) (a) 0.5 F of electric current was passed though 5 molar solutions of AgNO3,CuSO4 and AlCl3 connected in series. Find out the concentration of each of the electrolyte after the electrolysis ? (b) Determine the standard emf of the cell and standard free energy change of the cell reaction. Zn, Zn2+ || Ni2+, Ni. The standard reduction potentials of Zn2+, Zn and Ni2+, Ni half cells are 0.76 V and 0.25 V respectively.

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