I.

TITLE

: a. Neutralization Titration Titration between NaOH solution 0,1N with oxalic acid as standar solution b. Aplication of Neutralization Titration Determining percent content of H2SO4 in accu zuur

II. DATE

: 22th November 2011, start at : 07:30 am-11:30 am

III. PURPOSE : a. Making and determining standardization of base solution. b. Determining percent content of H2SO4 in Accu Zuur (Yuasa Merck). IV. THEORY :

V.

TOOLS AND MATERIALS a. Burette b. Conical Flask (Erlenmeyer) c. Measuring Cylinder d. Volumetric Flask e. Volumetric pipette f. Pro pipette g. Beaker Glass h. Pipette i. Funnel j. Analyst Balance k. Picnometer l. Spatula m. Filter paper n. Pipette o. Aquadest p. NaOH q. Accu Zuur r. Oxalic Acid s. Methyl Orange Indicator t. Phenolftalein Indicator

VI. PROCEDURE
Standarization of NaOH solution 0,1 N with oxalate acid as a standard solution

H2C2O4.2H2O 0, 6000 grams taking place in volumetric flask 100 mL dissolving by aquadest until limitation mark mixed well Oxalate acid as standard solution taking 10 mL of that solution using volumetric pipette (pour into Erlenmeyer 100 mL) pouring by aquadest 25 mL using graduated cylinder pouring by 3 drops of PP indicator Oxalate acid as standard solution titrate with NaOH solution until color of indicator is change done 3 times repetation writting down the scale of NaOH in the burrette in initial and final titration calculate the average concentration of NaOH 2NaOH + H2C2O4 Na2C2O4 + 2H2O

Determining Percentage of H2SO4 in Accu Zuur Accu Zuur Pouring 2 ml in piknometer with volumetric pipette Close the piknometer immediately Weight the piknometer Dissolving with aquades in volumetric flask 100 ml Keeping it well until become cold Weight the empty piknometer first Writing the mass

Accu Zuur solution Taking 10 ml into Erlenmeyer Adding several drops of methyl orange indicator

Accu Zuur solution + indicator Titrate with NaOH 0,1 N Repeating until 3 times Calculate the amount of H2SO4

Result

VII.DATA a. Titration of NaOH with Oxalic Acid

Burette Scale Before After 0 9,2 18,7 9,2 18,7 27,7 V NaOH (ml) 9,2 9,5 9

No 1 2 3

N NaOH (N) 0,1034 0,1002 0,1057 Naverage=0,1031 Reaction: H2C2O4.2H2O(aq) + NaOH(aq)Na2C2O4(aq) + 4H2O(l)

Titrator Miftahul Izzati Laili Ninik Nigusti Ayu S. Fitria Dwi Lestari

Note

Using Burette with accuracy 0,05 mL

b. Application of Acidy-Alkalimetry Titration

Burette Scale Before After 0 15 30,3 15 30,3 45,3 V NaOH (ml) 15 15,3 15

No 1 2 3

N NaOH (N) 0,1546 0,1577 0,1546

Titrator Fitria Dwi Lestari Miftahul Izzati Laili Ninik Nigusti Ayu S.

Note

Naverage=0,1556 Reaction: H2SO4(aq) + NaOH(aq) Na2SO4(aq) + 2H2O(l)

Using Burette with accuracy 0,05 mL

VIII. ANALYSIS

Standardization of NaOH using oxalic acid In the standardization of solution required a known concentration solution first. Solution of known concentration is called standard solution. In the standardization of NaOH solution required oxalic acid as standard solution. The first step is manufacture of standard solution of H2C2O4 , we get 0.6000 g of H2C2O4 and then diluted in 100 mL of aquadest in volumetric flask, this substance is soluble because of the polar. The reaction is: H2C2O4. 2H2O (s) + H2O (l) H2C2O4 (aq) After making standard solution, this solution is taken 10 mL using volumetric pipette because volumetric pipette has high standard accuracy and then it is poured in conical flask 100 mL and added with 25 mL of aquadest and 3 drops of PP indicator. This solution is filtrated using NaOH which have been put in burette until 0 scale. The purpose of addition indicator is to accelerate the reaction during titration to achieve the end point that is marked by changing of color from colorless to pink. The reaction that occur is : H2C2O4 (aq) + NaOH (aq) 2H2O (l) + Na2C2O4(aq) This titration is done 3 times and the volume of NaOH which is needed are 9.2 ml, 9.5 ml, and 9.0 ml. In this volume, titration is stopped because it had reached end point of titration, from this titration we can determine concentration of NaOH. From the calculation, we get the average value of normality is 0,1031 N. we get this value from : a. V NaOH x N NaOH 0,0092 L x N NaOH N NaOH b. V NaOH x N NaOH 0,0095 L x N NaOH N NaOH c. V NaOH x N NaOH 0,0090 L x N NaOH N NaOH = V C2H2O4.2H2O x N C2H2O4.2H2O = 0,01 L x 0,0952 N = 0,1034 N = V C2H2O4.2H2O x N C2H2O4.2H2O = 0,01 L x 0,0952 N = 0,1002 N = V C2H2O4.2H2O x N C2H2O4.2H2O = 0,01 L x 0,0952 N = 0,1057 N

N average = Reaction :

= 0,1031 N

C2H2O4.2H2O (aq) + NaOH (aq) Na2C2O4 (aq) + 4H2O (l)

Determining percent content of H2SO4 in accu zuur In this experiment, we have to determine the density of accu zuur first using piknometer. In the piknometer, already labeled the volume 25 ml. we need to know the mass of solution by weight the empty picnometer first and then weight the picnometer which had been filled with the accu zuur and calculate the mass. We can calculate the density directly from this formula :

The density that we got, can be use to calculate the percentage of H2SO4 in accu zuurafter this titration done well. We use Yuasa Accu Zuur that had been titrated with NaOH which the concentration is known from the first experiment and methyl orange as indicator. Our data experiment show the volume of NaOH that we get sequencely are 15 ml, 15.3 ml and 15 ml. And then we have to determine the concentration of NaOH with the calculation below : a. M eq H2SO4 = M eq NaOH N H2SO4 = 0,1546 = 0,1546 x 2 mmol = 0,3092 mmol mmol 0,3092 x = = = 15,1508 mg

in 100 ml solution x = 15,1508 mg x 100 = 1515,08 mg = 1,51508 gram

Percentage H2SO4 b. N H2SO4 = 0,1577

x 100% = 59,15 %

= 0,1577 x 2 = 0,3154 mmol mmol 0,3154 x = = = 15,5446 mg

in 100 ml solution x = 15,5446 mg x 100 = 1554,46 mg = 1,55446 gram = x 100% = 60,34 %

Percentage H2SO4 c. N H2SO4 = 0,1557

= 0,1557 x 2 mmol = 0,3114 mmol mmol 0,3114 x = = = 15,5286 mg

in 100 ml solution x = 15,5286 mg x 100 = 1552,86 mg = 1,55286 gram = x 100% = 59,57 %

Percentage H2SO4

% average

= 59,69 %

Thus, the percentage value of H2SO4 in accu zuur is 59,69 %

IX. DISCUSSION a. Standardization of NaOH using oxalic acid as standard solution when we did this experiment, we did not face any difficulties. We just have a little in determine the color changing of the analyte that the titrator can finish the titration. It is influence to the volume of NaOH that we need in this experiment for each repetation. So, we have to be more careful when read the burette scale and dont forget to drop the indicator a moment before do the titration. Because it will influence the analyte and can change the result of the data. b. Determining percent content of H2SO4 in accu zuur when we do this experiment, we did some mistakes. We drop yhe indicator before the titration. Finally we repeat the procedure by make the solution again. And then we drop the indicator just a moment before we do the titration. When we still doing the titration, we were careless when read the scale of the burette while we can not determine the color changing. Because of our knowledge about pH trayek is poor so we dont know the end of this titration.

X. CONCLUSION From the result of experiment can be concluding that: a. Standardization of NaOH using oxalic acid as standard solution from the first experiment, we can know the concentration of NaOH, we can standardize it using standard solution of oxalic acid using titration. Concentration of oxalic acid is 0,0552 N and the average of NaOH concentration is 0,1031 N b. Determining percent content of H2SO4 in accu zuur using titration we can determine the percentage of H2SO4 in accu zuur from experiment we can know that percentage of H2SO4 in Yuasa Accu Zuur is 59,69%. It is gotten from weight percentage analysis : % H2SO4 = x 100%

XI.

Answer of Question :

1.

Why in the manufacture of NaOH solution must use boiled water?

Answer: In the manufacture of NaOH solution must use boiled water because it is not pure in solution consisting of NaOH, but also contained Na2CO3 so that boiling water works to remove CO2 contained in Na2CO3.

2.

What is the difference between: a. Standard primer solution and standard secondary solution? b. Acidimetric and alkalimetri?

Answer: a. In analytical chemistry, a standard solution is a solution containing a precisely known concentration of an element or a substance i.e, a known weight of solute is dissolved to make a specific volume. It is prepared using a standard substance, such as a primary standard. Standard solutions are used to determine the concentrations of other substances, such as solutions in titrations. The difference between the primary standard solutions with secondary standard solution are standard primer solution is a solution of known concentration for certain and is used to determine the concentration of secondary standard solution, secondary standard solution is a solution whose concentration has been determined accurately through the standardization process.

b. Acidimetric i.e. involving base neutralization titration with acid of known concentration. Alkalimetri i.e. involving titration of neutralizing acid with a base of known concentration.

3.

Give reasons for the use of indicators in the titration of the above!

Answer:

The use of indicators in the titration is useful to know when to stop adding titrant because indicator will change color, and when there are changes color is called the equivalence point and end point of titration.

XII.

Refferences Poedjiastuti, Sri., dkk. 2009. Panduan Praktikum Kimia Analitik I Dasar-dasar Kimia Analitik. Surabaya: Jurusan Kimia FMIPA Unesa. Day, R. A. 1991. Quantitative Analysis Sixth Edition. New Jersey: Prentice Hall.

Attachments :
Standardization of NaOH using oxalic acid as standard solution

Attachments :
Determining percent content of H2SO4 in accu zuur

Accu Zuur after titration

The color changing of accu zuur before titration and after titration