1. 1.1
1.2
1.3
1.4
2. 2.1 2.2
COMPOSITION / CHEMICAL ANALYSIS / INFORMATION ON INGREDIENTS COMPOSITION CHEMICAL ANALYSIS Natural, coated (with stearic acid) calcium carbonate (CaCO3: CAS-No. 471-34-1) CaCO3 99,0 % SiO2 0,05 % MgO 0,15 % Fe2O3 0,01 % -----
2.3 2.4 3.
Based on the available data on natural calcium carbonate and the additives mentioned under 2.1, the substance represents neither a hazard to man nor a hazard to the environment.
PAGE 1 / 5 4. FIRST AID MEASURES EYE CONTACT SKIN CONTACT: INHALATION: Move person to fresh air. In case of indisposition, seek medical advice. INGESTION: Symptomatic treatment. In case of indisposition, seek medical advice. 5. FIRE-FIGHTING MEASURES Non-flammable substance, therefore not applicable.
Rinse with plenty of water. In case of irritation, seek medical advice. Wash with water
6.
ACCIDENTAL RELEASE MEASURES In case of spillage, collect and dump in licensed landfill site. Avoid contact with acids.
7. 7.1
HANDLING AND STORAGE HANDLING The usual precautions for the handling with chemicals should be observed.
7.2
8. 8.2.1.1
EXPOSURE CONTROL / PERSONAL PROTECTION RESPIRATORY PROTECTION ACGIH TLV: OEL (8 hrs): Total fine dust: OEL (respirable crystalline silica): HAND PROTECTION Wear dust gloves 10 mg/m total dust (USA) 4 mg/m respirable dust (UK) 6 mg/m (Germany) 0.05 mg/m3 (Italy) 0.40 mg/m3 (Ireland)
8.2.1.2
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9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES GENERAL INFORMATION FORM COLOUR ODOUR METHOD powder white odourless
9.2
IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION pH-VALUE MELTING POINT BOILING POINT FLASH POINT FLAMMABILITY AUTOFLAMMABILITY EXPLOSIVE PROPERTIES VAPOUR PRESSURE DENSITY SOLUBILITY a) WATER-SOLUBILITY b) FAT-SOLUBILITY PARTITION COEFFICIENT n-OCTANOL/H2O FURTHER DATA a) THERMAL DECOMPOSITION 8.5 - 9.5 (100 g/l / 20 C) DIN-ISO 787/9 1340 C (102 bar) not applicable not applicable non-flammable no self-ignition not explosive negligible 2.7 (20 C) 0.014 g/l (20 C) 0.018 g/l (75 C) not determined < 1 (estimation) > 825 C DIN-ISO 787/10 DIN-ISO 787/8
none recommended Avoid contact with acids Can react with acids under the formation of carbon dioxide (CO2) that can displace oxygen (danger of suffocation). none
10.4
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11.
TOXICOLOGICAL INFORMATION
Due to the fact that solid calcium carbonate is a natural mineral of the surface of the earth and that dissolved calcium carbonate is a natural and indispensable component of natural waters, chronic toxic effects as well as sensitizing effects of the substance can practically be excluded. 12. ECOLOGICAL INFORMATION
In its solid state, calcium carbonate is a natural mineral of the earth. In its dissolved state, the substance is a natural and indispensable component of natural waters. Therefore, unfavourable effects to the environment may be excluded. Calcium carbonate cannot biodegrade. Restrictions may be indicated that concentrated suspensions of calcium carbonate in natural waters may have an unfavourable effect on water organisms (disturbance of the microflora and -fauna in the sediment and subsequent detriment to the existence of higher water organisms). LC50 Fish 96 h > 10'000 mg/l LC50 Daphnia 49 h > 1000 mg/l LC50 Algae 72 h > 200 mg/l 13. DISPOSAL CONSIDERATION
Disposal in a licensed landfill site is possible. For disposal recommendation consult manufacturer. 14. TRANSPORT INFORMATION -------------
GGVSee/IMDG CODE GGVE/GGVS UN No. RID/ADR ICAO/IATA-DGR ADNR 15. REGULATORY INFORMATION
R-phrases: S-phrases:
none none
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16.
classified as a non-toxic product under BAGT No. 617 300 EINECS listed under No. 207-439-9 TSCA Inventory listed under CAS No. 471-34-1 Limestone is exempt from the PDSL (naturally occurring substance). ACOIN edition 92 listed under CAS-No. 1317-65-3 MITI registered under 1-122-122 - 1317-65-3 - 1317-65-3
The information contained in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. The information provided herein is based on technical data that IONIAN KALK S.A. believes to be reliable, however IONIAN KALK S.A. makes no representation or warranty as to the completeness or accuracy thereof and IONIAN KALK S.A. assumes no liability resulting from its use or for any claims, losses, or damages of any third party. Recipients receiving this information must exercise their own judgement as to the appropriateness of its use, and it is the user's responsibility to assess the material's suitability (including safety) for a particular purpose prior to such use.
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