choi (sc34934) H13 - Kinetics 2 mccord (51175) This print-out should have 13 questions.

ns. Multiple-choice questions may continue on the next column or page nd all choices before answering. 001 10.0 points If k = 2.7 106 M1 s1 for the reaction AB which of the following is the correct rate law? 1. rate = k [A]0 2. rate = k [A]2 [B]1 3. rate = k [A]1 4. rate = k [A]2 correct 5. rate = k [A]0 [B]1 Explanation: 002 10.0 points A reaction is second order in A and zero order in B. Doubling the initial concentration of A and halving the initial concentration of B at constant temperature causes the initial rate to 1. decrease by a factor of 2. 2. increase by a factor of 4. correct 3. decrease by a factor of 4. 4. remain unchanged. 5. increase by a factor of 2. Explanation: 003 (part 1 of 2) 10.0 points Warning: the rate constant given is for the OVERALL reaction. Youll need to adjust it to be the rate constant for C2 F4 . dr mccord The rate constant for the following equation is 0.0478 M1 s1 . We start with 0.26 mol C2 F4 in a 5.00-liter container, with no C4 F8 initially present. 2 C 2 F4 C 4 F8

What will be the concentration of C2 F4 after 3.00 hours? Correct answer: 0.000951 M. Explanation: k = 0.0478 M1 s1 t = 3.00 hours 0.26 mol [C2 F4 ]ini = = 0.052 M 5.00 L Use the second order integrated rate law 1 1 = akt [A] [A]0 1 1 = +akt [A] [A]0 1 1 = [A] 0.052 M + (2) (0.0478 M1 s1 ) (10800 s) [A] = 0.000951 M

004 (part 2 of 2) 10.0 points What will be the concentration of C4 F8 after 3.00 hours? Note that this is the PRODUCT of the reaction. Correct answer: 0.0255 M. Explanation: The concentration of C4 F8 is equal to HALF the amount of C2 F4 that was LOST in the reaction. Since 0.000951 M C2 F4 remains, 0.052 M 0.000951 M is what reacted. 1 Take of that and get the answer of 0.0255 M. 2 005 10.0 points For a rst-order reaction, after 2.00 min, 20% of the reactants remain. Calculate the rate constant for the reaction. 1. 74.6 s1

choi (sc34934) H13 - Kinetics 2 mccord (51175) 2. 0.00186 s1 3. 0.013412 s1 correct 1. 10.0 grams 4. 0.00582 s
1 1

is 0.0693 min1 . How many grams of A would be left after 1 hour if the reaction started with 80 grams of A at time = 0?

5. 0.000808 s

2. Cannot be determined from the given information 3. 1.25 grams correct 4. 40.0 grams 5. 5.0 grams Explanation: t = 1 hour = 60 min a=1 Thus [A0 ] ln [A] k = 0.0693 min1

Explanation: Since Mr = M0 ek t , where Mr is the mass of reactants remaining, M0 is the initial mass of reactants, k is the rate constant, and t is the time elapsed in seconds, we have Mr = ek t M0 Mr k t = ln M0 Mr 1 k = ln t M0 1 20% = ln 2 min 100% 1 1 ln = 120 s 5 1 = 0.013412 s 006 10.0 points A reaction has k = 8.39 M1 s1 . How long does it take for the reactant concentration to drop from 0.0840 M to 0.0220 M? 1. 4.00 s correct 2. 8.39 s 3. 2.00 s 4. 1.42 s 5. 5.42 s Explanation: 007 10.0 points The rst-order rate constant for the conversion AB

= akt

ln [A0 ] ln[A] = a k t ln [A0 ] a k t = ln[A] ln[A] = ln(80 g) (1) 0.0693 min1 (60 min) = 0.224 A = e0.224 = 1.25 grams 008 10.0 points Warning: The rate constant given is for the OVERALL reaction. Youll need to adjust it accordingly to be correct for NO2 . dr mccord For the reaction 2 NO2 2 NO + O2 Rate = 1.4 1010 /M s [NO2 ]2 at 25.0 C. If 2.3 mol of NO2 are initially present in a sealed 1.00 liter vessel at 25 C, what is the concentration of NO2 after 176 years? Correct answer: 0.502622 M. Explanation: a=2 t = 176 years k = 1.4 1010 M1 s1 nNO2 = 2.3 mol

choi (sc34934) H13 - Kinetics 2 mccord (51175) The rate law indicates a second order reaction. Since the relationship of interest involve [NO2 ] and time, use the integrated rate law: 1 1 = akt [NO2 ]t [NO2 ]0 1 1 = akt + [NO2 ]t [NO2 ]0 = 2 1.4 1010 M1 s1 365 d 24 h 176 y y d 1L 3600 s + h 2.3 mol 1 = 1.98957 M [NO2 ]t = 0.502622 M 009 10.0 points A non-steroidal anti-inammatory drug is metabolized with a rst-order rate constant of 3.25 day1 . What is the half-life for the metabolism reaction? 1. 2.25 day 2. 0.308 day 3. 1.63 day 4. 0.213 day correct Explanation: 010 10.0 points A compound decomposes with a half-life of 8.0 s and the half-life is independent of the concentration. How long does it take for the concentration to decrease to one-ninth of its initial value? 1. 64 s 2. 3.6 s 3. 25 s correct 4. 72 s 5. 32 s Explanation: 011 10.0 points Consider the following data for the reaction A products .

Trial 1 2 3 The reaction

Initial [A] Half-life M s 0.2 0.5 0.1 24 60 12

1. has an order that cannot be determined from the data given. 2. is zero order. correct 3. is second order. 4. No choice is correct. 5. is rst order. Explanation: Concentration is directly proportional to half-life, so it is zero order. 012 10.0 points Consider the rst order reaction A products where 25% of A disappears in 24 seconds. What is the half life of this reaction? 1. t1/2 = 25 s 2. t1/2 = 36 s 3. t1/2 = 12 s 4. t1/2 = 48 s

choi (sc34934) H13 - Kinetics 2 mccord (51175) 5. t1/2 = 40 s 6. t1/2 = 58 s correct Explanation: a=1 [A]0 = 100 ln [A]0 [A]t = akt k= [A]0 1 ln at [A]t 1 100 = ln 24 s 75 = 1.199 102 s1 t = 24 s [A]t = 75 [N2 O5 ]t = e5.18037 = 0.00562593 M = ln 0.517 mol 10.00 L ln 2 (1) (16 min) 5.00 min = 5.18037

t1/2 =

ln 2 = 58 s k

013 10.0 points The rst order reaction N2 O5 (g) N2 O4 (g) + 1 O2 (g) 2

has a half-life of 5.00 minutes at a certain temperature. If an experiment is started with 0.517 moles of N2 O5 in a 10.00 liter container, what molar concentration will remain after 16 minutes? Correct answer: 0.00562593 M. Explanation: t1/2 = 5 min t = 16 min 0.517 mol [N2O5 ]0 = 10.00 L Since we know the half-life of the reaction, we can determine its rate constant by k= ln 2 . t1/2

The rst order integrated rate equation is [N2 O5 ]0 = akt [N2 O5 ]t ln[N2 O5 ]0 ln[N2 O5 ]t = a k t ln ln[N2 O5 ]t = ln[N2 O5 ]0 a ln 2 t t1/2