Reaction Kinetics Worksheet

Name: __________________________ Date: _____________
Page 1
1. For a reaction:
aAEquation.BREE401050000020000000F0000004571756174696F6E2E4252454534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 2
A)
B)
C)
D)
E)
7.0e2
4.6e3
3.5e2
9.2e3
none of these
Page 3
2. The decomposition of N2O5(g) to NO2(g) and O2(g) obeys first-order kinetics.

Assuming the form of the rate law is
Equation.BREE401050000020000000F0000004571756174696F6E2E4252454534000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 4
A)
B)
C)
D)
E)
3.4e-5 mol/Ls
2.9e6 mol/Ls
4.0e4 mol/Ls
8.4e2 mol/Ls
none of these
Use the following to answer question 3:

A general reaction written as 1A + 2B C + 2D is studied and yields the following data:
[A]0
[B]0
Initial [C]/t
0.150 M 0.150 M 8.00 x 103 mol/L
s
0.150 M 0.300 M 1.60 x 102 mol/L
s
0.300 M 0.150 M 3.20 x 102 mol/L
s
3. Determine the initial rate of B consumption ([B]/t) for the first trial?
A) 8.00 x 103 mol/L s
B) 1.60 x 102 mol/L s
C) 3.20 x 102 mol/L s
D) 4.00 x 103 mol/L s
E) none of these (a-d)
Consider the following data concerning the equation:
H2O2 + 3I- + 2H+ I3- + 2H2O
[H2O2]
[I-]
[H+]
I
0.100 M
5.00 x 10-4 M
1.00 x 10-2 M
-3
II.
0.100 M
1.00 x 10 M
1.00 x 10-2 M
III.
0.200 M
1.00 x 10-3 M
1.00 x 10-2 M
-3
IV.
0.400 M
1.00 x 10 M
2.00 x 10-2 M
Page 5
rate
0.137 M/sec
0.268 M/sec
0.542 M/sec
1.084 M/sec'
4. Two mechanisms are proposed:
A)
B)
C)
D)
E)
Mechanism I with the first step the rate determining step.

Mechanism I with the second step the rate determining step.
Mechanism II with the first step rate determining.
Mechanism II with the second step rate determining.
None of the above could be correct.
Page 6
5. At a particular temperature, N2O5 decomposes according to a first-order rate law with

a half-life of 3.0 s. If the initial concentration of N2O5 is 1.0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 7
A)
B)
C)
D)
E)
1.2e14
3.2e1
1.0e16
1.2e14
2.3e-1

A general reaction written as 1A + 2B C + 2D is studied and yields the following data:
[A]0
[B]0
Initial [C]/t
0.150 M 0.150 M 8.00 x 103 mol/L
s
0.150 M 0.300 M 1.60 x 102 mol/L
s
0.300 M 0.150 M 3.20 x 102 mol/L
s
6. What is the numerical value of the rate constant?
A) 0.053
B) 1.19
C) 2.37
D) 5.63
E) none of these (a-d)
For the reaction 2N2O5(g) 4NO2(g) + O2(g), the following data were collected:
t (minutes) [N2O5] (mol/L)
0
1.24 102
10.
0.92 102
20.
0.68 102
30.
0.50 102
40.
0.37 102
50.
0.28 102
70.
0.15 102
7. The concentration of O2 at t = 10. minutes is
A) 2.0 104 mol/L
B) 0.32 102 mol/L
C) 0.16 102 mol/L
D) 0.64 102 mol/L
E) none of these
Page 8
8. For the reaction A
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 9
A)
B)
C)
D)
E)
0.069
0.11
10.0
4.4e2
none of these
9. Which of the following statements best describes the condition(s) needed for a
successful formation for a product according to the collision model?
A) The collision must involve a sufficient amount of energy, provided from the
motion of the particles, to overcome the activation energy.
B) The relative orientation of the particles has little or no effect on the formation of
the product.
C) The relative orientation of the particles has an effect only if the kinetic energy of
the particles is below some minimum value.
D) The relative orientation of the particles must allow for formation of the new bonds
in the product.
E) The energy of the incoming particles must be above a certain minimum value and
the relative orientation of the particles must allow for formation of new bonds in
the product.
10. The rate constant for a reaction at 40.0oC is exactly 4 times that at 20.0oC. Calculate
the Arrhenius energy of activation for the reaction.
A) 4.00 kJ/mol
B) 11.5 kJ/mol
C) 52.8 kJ/mol
D) 6.36 kJ/mol
E) none of these
The following questions refer to the reaction between nitric oxide and hydrogen
2NO + H2 N2O + H2O
11. What is the rate law for this reaction?

A) Rate = k[NO]
B) Rate = k[NO]2
C) Rate = k[NO]2[H2]
D) Rate = k[NO][H2]
E) Rate = k[N2O][H2O]
Page 10
12. The average rate of disappearance of ozone in the reaction
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 11
A)
B)
C)
D)
E)
1.42e2 atm/s
9.47e3 atm/s
6.31e3 atm/s
4.25e7 atm/s
2.99e5 atm/s
Page 12
13. The reaction
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 13
A)
B)
C)
D)
E)
5.0e2 mol/L s
2.5e2 mol/L s
1.2e2 mol/L s
2.4e3 mol/L s
none of these

The following questions refer to the reaction shown below:
Experiment
1
2
3
Initial [A]
Initial [B]
(mol/L)
0.16
0.16
0.08
(mol/L)
0.15
0.30
0.30
Initial Rate of
Disappearance of
A
(mol/L s)
0.08
0.30
0.08
14. What are the units for the rate constant for this reaction?
A) L/mol s
B) L2/mol2 s
C) mol/L s
D) L3/mol3 s
E) mol3/L
0
1.24 102
10.
0.92 102
20.
0.68 102
30.
0.50 102
40.
0.37 102
50.
0.28 102
70.
0.15 102
15. The half-life of this reaction is approximately
A) 15 minutes
B) 18 minutes
C) 23 minutes
D) 36 minutes
E) 45 minutes
Page 14
16. The decomposition of ozone may occur through the two-step mechanism shown:
step 1
O3 O2 + O
step 2
O3 + O 2O2
The oxygen atom is considered to be an(n)
A) reactant
B) product
C) catalyst
D) reaction intermediate
E) activated complex
Page 15
17. The decomposition of N2O5(g) to NO2(g) and O2(g) obeys first-order kinetics.
Assuming the form of the rate law is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 16
A)
B)
C)
D)
E)
2.0e4 s
1.4e4 s
4.0e8 s
7.2e5 s
none of these
18. Consider a reaction of the type aA Products in which the rate law is found to be
rate = k[A]3 (yes, being it is a termolecular reaction it is improbable but possible). If
the first half life of the reaction is found to be 40 seconds, what is the time for the
second half life?
A) 10 seconds
B) 20 seconds
C) 80 seconds
D) 160 seconds
E) 320 seconds
The oxidation of Cr3+ to CrO42 can be accomplished using Ce4+ in a buffered solution. The
following data were obtained:
Relative
Initial Rate
1
2
4
16
[Ce4+]0
[Ce3+]0
[Cr3+]0
2.0 103
4.0 103
4.0 103
8.0 103
1.0 102
2.0 102
1.0 102
2.0 102
3.0 102
3.0 102
3.0 102
6.0 102
19. Determine the order in the rate law of the species Ce3+.
A) 1
B) 2
C) 3
D) 1
E) 2
20. A first-order reaction is 40.0% complete at the end of 30.9 minutes. What is the value
of the rate constant (in min-1)?
A) 2.97e2
B) 1.65e2
C) 6.05e1
D) 3.37e1
E) none of these
Page 17
21. The experimental rate law for the decomposition of nitrous oxide (N2O) to N2 and O2
is rate = k[N2O]2. Two mechanisms are proposed:
I.
N2O N2 + O
N2O + O N2 + O2
II.
2N2O
N4O2
N4O2 2N2 + O2
Which of the following could be a correct mechanism?
A) Mechanism I with the first step as the rate-determining step.
B) Mechanism I with the second step as the rate-determining step as long as the first
step is a fast equilibrium step.
C) Mechanism II with the second step as the rate-determining step if the first step is a
fast equilibrium step.
D) None of the choices (a-c) could be correct.
E) At least two of the above choices (a-c) could be correct.
The following questions refer to the reaction between nitric oxide and hydrogen
2NO + H2 N2O + H2O
22. What is the order of this reaction?

A) 3
B) 2
C) 1
D) 0
E) cannot be determined from the data
Page 18
23. Two isomers (A and B) of a given compound dimerize as follows:

2A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 19
A)
B)
C)
D)
E)
4.2e2 s
1.0e2 s
1.8e2 s
2.4e3 s
none of these
Page 20
24. The balanced equation for the reaction of bromate ion with bromide ion in acidic
solution is given by:
000000000000000000C0000D0CF11E0A1B11AE1000000000000000000000000000
000003E000300FEFF090006000000000000000000000001000000010000000000000
FFFFFFFFFF52006F006F007400200045006E00740072007900000000000000000000
000000000000000000000000000000000000000000000000000000000000000000000
000000000000000000000008033838A735BC80103000000C00200000000000001004
F006C0065000000000000000000000000000000000000000000000000000000000000
0000000000000000000000000000000000000000000000000000000A000200FFFFFF
00000000000000000000000000000001400000000000000010043006F006D0070004
F0062006A000000000000000000000000000000000000000000000000000000000000
00000000000000000000000000000000000000120002010100000003000000FFFFFF
FF0000000000000000000000000000000000000000000000000000000000000000000
0000001000000B8000000000000004500710075006100740069006F006E0020004E0
061007400690076006500000000000000000000000000000000000000000000000000
Page 21
A)
B)
C)
D)
E)
2.4e3
4.0e3
6.7e3
2.0e3
3.3e3
Page 22

The kinetics of the reaction A + 3B C + 2D were studied and the following results obtained,
where the rate law is
Page 23

Equation.BREE40105000002000
0000F0000004571756174696F6E
2E4252454534000000000000000
000000C0000D0CF11E0A1B11
AE100000000000000000000000
0000000003E000300FEFF09000
600000000000000000000000100
000001000000000000000010000
00200000001000000FEFFFFFF0
000000000000000FFFFFFFFFFF
FFFFFFFFFFFFFFFFFFFFFFFF
FFFFFFFFFFFFFFDFFFFFFFEF
FFFFFFEFFFFFF04000000FEFF
Page 24
For a run where [A]0 = 1.0 103 M and [B]0 = 5.0 M, a plot of ln [A] versus t was found to
give a straight line with slope = 5.0 102 s1.
For a run where [A]0 = 1.0 103 M and [B]0 = 10.0 M, a plot of ln [A] versus t was found to
give a straight line with slope = 7.1 102 s1.
25. Calculate the value of k (ignore units).
A) 2.2 102
B) 1.0 102
C) 5.0 102
D) 1.1 101
E) none of these
0
1.24 102
10.
0.92 102
20.
0.68 102
30.
0.50 102
40.
0.37 102
50.
0.28 102
70.
0.15 102
26. The initial rate of production of NO2 for this reaction is approximately
A) 6.4 104 mol/L min
B) 3.2 104 mol/L min
C) 1.24 102 mol/L min
D) 1.6 104 mol/L min
E) none of these
27. Consider the reaction X Y + Z
Which of the following is a possible rate law?
A) Rate = k[X]
B) Rate = k[Y]
C) Rate = k[Y][Z]
D) Rate = k[X][Y]
E) Rate = k[Z]
Page 25
28. The following data were collected for the decay of HO2 radicals:
Time
[HO2]
Time
[HO2]
0s
1.0 1011 molec/cm3
14 s
1.25 1010 molec/cm3
2s
5.0 1010 molec/cm3
30 s
6.225 109 molec/cm3
6s
2.5 1010 molec/cm3
A)
B)
C)
D)
E)
The decay of HO2 occurs by a first-order process.

The half-life of the reaction is 2 ms.
A plot of ln [HO2] versus time is linear with a slope of k.
The rate of the reaction increases with time.
A plot of 1/[HO2] versus time gives a straight line.

For the reaction A Products, successive half-lives are observed to be 10.0 min and 40.0 min.
At the beginning of the reaction, [A] was 0.10 M.
Page 26
29. The reaction follows the integrated rate law
Page 27
A) [A] = kt + [A]0
B) ln [A] = kt + ln [A]0
Page 28
C) Equation.BREE401050000020000000F0000004571756174696F6E2E425245453
4000000000000000000000A0000D0CF11E0A1B11AE100000000000000000000
0000000000003E000300FEFF09000600000000000000000000000100000001000
00000000000001000000200000001000000FEFFFFFF0000000000000000FFFFF
FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF
FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFDFFFFFFFEFFFFFFFEFFFFFFF
EFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF
FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF5200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 29
D) Equation.BREE401050000020000000F0000004571756174696F6E2E425245453
4000000000000000000000C0000D0CF11E0A1B11AE100000000000000000000
0000000000003E000300FEFF09000600000000000000000000000100000001000
00000000000001000000200000001000000FEFFFFFF0000000000000000FFFFF
FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFDFFFFFFFEFFFFFFFEFFFFFF04
000000FEFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF
FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF52006
F006F007400200045006E00740072007900000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000016000500
FFFFFFFFFFFFFFFF020000001FCE020000000000C0000000000000460000000
00000000000000000E026C18A735BC80103000000400200000000000001004F0
06C00650000000000000000000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000000A000200F
FFFFFFFFFFFFFFFFFFFFFFF0000000000000000000000000000000000000000
00000000000000000000000000000000000000001400000000000000010043006
F006D0070004F0062006A0000000000000000000000000000000000000000000
000000000000000000000000000000000000000000000000000000012000201010
0000003000000FFFFFFFF00000000000000000000000000000000000000000000
000000000000000000000000000001000000B8000000000000004500710075006
100740069006F006E0020004E0061007400690076006500000000000000000000
0000000000000000000000000000000000000000000000000020000200FFFFFFF
FFFFFFFFFFFFFFFFF00000000000000000000000000000000000000000000000
Page 30
E) none of these
The following questions refer to the reaction shown below:
Experiment
1
2
3
Initial [A]
Initial [B]
(mol/L)
0.16
0.16
0.08
(mol/L)
0.15
0.30
0.30
Initial Rate of
Disappearance of
A
(mol/L s)
0.08
0.30
0.08
30. What is the order of this reaction?

A) 4
B) 3
C) 2
D) 1
E) 0
Page 31
Answer Key
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
C
B
B
A
A
C
C
B
E
C
C
A
A
D
C
D
B
D
D
B
C
A
A
A
A
A
A
E
C
A
Page 32

Reaction Kinetics Worksheet

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Name: ______________ Date: _

2. The decomposition of N2O5(g) to NO2(g) and O2(g) obeys first-order kinetics.

Use the following to answer question 3:

4. Two mechanisms are proposed:

Mechanism I with the first step the rate determining step.

5. At a particular temperature, N2O5 decomposes according to a first-order rate law with

Use the following to answer question 6:

8. For the reaction A

11. What is the rate law for this reaction?

12. The average rate of disappearance of ozone in the reaction

13. The reaction

Use the following to answer question 14:

22. What is the order of this reaction?

23. Two isomers (A and B) of a given compound dimerize as follows:

Use the following to answer question 25:

The decay of HO2 occurs by a first-order process.

Use the following to answer question 29:

29. The reaction follows the integrated rate law

30. What is the order of this reaction?

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