T. Vilajuana R&D Lens Business Unit, INDO Salamanca, June 27th 2006
An ideal lens
Light weight Mechanical strength Anti-scratch Photochromic UV-protection
Anti-reflective
Easy-to-clean
1.49 to 1.74
1.1 to 1.3
70-120
Polymer lenses are light but... they are soft and easily scratched A hard coat is applied to many polymeric materials
Light weight
Low density polymers High index materials Aspheric curvatures Thin edge/centre thickness Optimisation of lens geometry according to frame shape
Hydrophobic and lipophobic top coat (5 to 10 nm) Anti-reflective multilayer (250 to 350 nm) Hard Coating (1.800 to 2.000 nm) Polymeric lens (1 to 2.000.000 nm)
Anti-reflection
Benefits of AR lenses
Reflectance vs lens refractive index
20,0%
Reflectance in %
15,0%
10,0%
5,0%
0,0%
1,49
1,52
1,6
1,7
1,8
1,9
Some uncoated lenses may loose up to 20% light, wereas with an AR, reflectance may be as low as 0.5%
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Spectral Refectance
5.0% re flectan ce in % 4.0% 3.0% 2.0% 1.0% 0.0%
400 450 500 550 600 650 700 AR coated Uncoated
Wavelength in nm
How to design an AR
Specify substrate, layers, illuminants, angle and tolerances Calculate reflectance spectra Calculate color coordenates Design objectives
minimise reflectance n layers match target color angular stability
Obtaining a New AR
New AR (objectives and tolerances)
Calculate performance
Check Tolerances
Easy-to-clean lenses
Easy-to-Clean = Hydrophobic & oleophobic + low surface energy + low friction + smooth + anti-static surface
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Hydrophobic surface
Oligomers of large perfluorated carbon chain (silicon base) and high molecular weight (2000 to 5000 uma) [F]/[C] > 2 [F]/[Si] > 3
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Easy-to-clean lenses
115
40
115
d' 1/2
+ 2(LP L'P')1/2
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Easy-to-clean lenses
12
mJ/m2
Lenses do not retain grease easily, and remain cleaner for a longer time
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Easy-to-clean lenses
0.15
Easy-to-clean lenses
0.8
nm
Smooth surface
Lenses are smooth and easy to be cleaned, they suffer less friction so they remain unscratched longer
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Easy-to-clean lenses
<50V
Antistatic Surface
UV and Photochromism
Photochromism is a reversible effect (clear-dark) Equilibrium between UV, visible light and heat
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Photochromic Lenses
UV-Spectral sensitivity of photochrmic dyes
800 700 600 500 400 300 200 100 0 280
Transmittance spectra
100 90
Transmittance in %
300 320 340 360 380 400 420 440 460 480 500
Sensitivity in a.u.
80 70 60 50 40 30 20 10 0
Wavelength in nm
380
480
580 Wavelength in nm
680
780
Spironaphthoxacines and naphtopyran molecules are adjusted to absorb UV-A. Lens transmittance according to outdors light conditions
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An ideal lens
Light weight Mechanical strength Anti-scratch Photochromic UV-protection
Anti-reflective
Easy-to-clean
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Technology
PVD?
Sputtering?
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About Technology
Production on millions of coatings per year must be done with high throughput rates
I.e.: Process with 20 steps at 99% each => 82%
All process parameters should be monitored and tightly controlled An analysis of statistical trends is required in order to identify and prevent process deviations
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Future trends
Development of new materials with better optical and mechanical properties Requires a Tecnology to produce milions of coated lenses... At a competitive cost, and in a personalised basis The challenge of ophthalmic optic companies
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