Lovely Professional University,Punjab

Format For Instruction Plan [for Courses with Lectures,Tutorials and Labs

Course No CHE158

Cours Title GENERAL CHEMISTRY

Course Planner 11801 :: Sonika

Lectures Tutorial Practical Credits 3 1 3 5

Text Book:

Suba Ramesh S.Varian,Pradya Tej Godbole , Engineering Chemistry , John Wiley , 1st edition. 2011

Other Specific Book:

2 J.Mendham, R.C.Denney, J.D.Barnes Vogel's Text book of Inorganic and organic quantitative chemical analysis 6th Edition 2009. 3 J.D.Lee,Concise Inorganic Chemistry,Fifth Edition , Oxford University Press. 4 B.R.Puri,L.R.Sharma and K.C.Kalia,Priciples of inorganic chemistry,Vishal Publishising Co;2007-08 5 K.L.Kapoor,A text book of Physical Chemistry, Vol.3,Applications of thermodynamics,Mcmillian India Ltd,2nd Edition. 6 J.B.Yadav,Advance Practical chemistry,Krishna Publications, Merrut 12th ,Revised Edition

Other Reading Sr No Jouranls atricles as compulsary readings (specific articles, Complete reference)

Relevant Websites Sr. No. (Web adress) (only if relevant to the courses) Salient Features

7 http://www.tulane.edu/~sanelson/geol212/2compphasdiag.htm Phase, component , degree of freedom l 8 http://www.chem.arizona.edu/~salzmanr/480a/480ants/gibbsp Derivation of Gibb's phase rule, r/gibbspr.html 9 http://intro.chem.okstate.edu/PLE582901/PhaseDiagram.html Phase diagram of one component animation 10 http://serc.carleton.edu/research_education/equilibria/binary_d Phase diagram of two component animation iagrams.html 1 Approved for Autumn Session 2011-12

11 http://demonstrations.wolfram.com/GibbsPhaseRuleForOneA Phase diagram of one and two component animation ndTwoComponentSystems/ 12 http://www.doitpoms.ac.uk/tlplib/phase-diagrams/cooling.php 13 http://www.chemguide.co.uk/physical/phaseeqia/snpb.html Cooling Curves For two component lead silver system

14 http://www.tutorvista.com/content/physics/physics-iii/heat-and- Thermodynamic Processes thermodynamics/thermodynamic-processes-animation.php 15 http://www.tutorvista.com/content/chemistry/generalchemistry/thermodynamics/first-law-of-thermodynamics.php 16 http://www.tutorvista.com/content/chemistry/generalchemistry/thermodynamics/the-second-law-ofthermodynamics.php Ist Law of themodynamics 2nd Law of themodynamics

17 http://www.mhhe.com/physsci/chemistry/essentialchemistry/fla Galvanic cell sh/galvan5.swf 18 http://www.chem.iastate.edu/group/Greenbowe/sections/proje Ph Meter ctfolder/flashfiles/acidbasepH/ph_meter.html 19 http://www.chem1.com/acad/webtext/chembond/cb09.html#S coordination chemistry introduction EC1 20 http://www.materialsworldmodules.org/resources/polimarizatio Mechanism of condensation polymerisation n/4-condensation.html 21 http://www.materialsworldmodules.org/resources/polimarizatio Mechanism of addition polymerisation n/3-addition.html 22 http://www.yteach.co.uk/page.php/resources/view_all? Polymers,thermosetting,elastomer,themoplatics id=polymer_addition_polymerisation_polyethene_hydrocarbon _poly%28propene%29_poly%28phenylethene%29_poly %28chloroethene%29_poly%28tetrafluoroethene%2

Detailed Plan For Lectures

Week Number Lecture Number Lecture Topic Chapters/Sections of Pedagogical tool Textbook/other Demonstration/case reference study/images/anmatio n ctc. planned

Part 1
Week 1 Lecture 1 Phase rule: Statement and meaning of the termsphase, component and degrees of freedom Derivation , advantages and limitations of Gibbs phase rule ->Reference :1,->Animation: Reference 8 >Reference 1Page 235 -238Chapter 6 ->Reference :1,Page 238-238 Chapter 6 Animation:Reference 9

Lecture 2

Approved for Autumn Session 2011-12

Week 1 Week 2

Lecture 3 Lecture 4 Lecture 5

Phase equilibra of one component system-water Phase equilibrium of two component system for eutectic mixtures,cooling curves classius clapeyron equation

->Reference :1,Page 239-242 Chapter 6 ->Reference :1,Page 239-242 Chapter 6 ->Reference :6,->>Reference 6Page 525 -530 ->Reference :1,Page 125-128 Chapter 4 ->Reference :1,Page 134-136 Chapter 4 ->Reference :1,Page 136-138 Chapter 4 ->Reference :1,Page 143-147 Chapter 4 ->Reference :1,Page 150-152 Chapter 4

Animation:Reference 10,11 Animation:Reference 12,13

Lecture 6 Week 3 Lecture 7 Lecture 8 Lecture 9 Week 4 Lecture 10

Thermodynamic system, process , properties, energy of the thermodynamic system first law of thermodynamics and its interpretation and its applications :molar heat capacity Reversible isothermal expansion / compression of an ideal gas , adiabatic expansion of the ideal Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only

Animation:Reference 15 Animation:Reference 16 Animation:Reference 17 Test 1

Part 2
Week 4 Lecture 11 Lecture 12 Week 5 Lecture 13 Lecture 14 Lecture 15 Entropy change for mixing of ideal gases , entropy of physical and chemical changes Gibbs free energy and its physical significance Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity ->Reference :1,Page 153-154 Chapter 4 ->Reference :1,Page 159-163 Chapter 4 ->Reference :1,Page 159-163 Chapter 4 Animation:Reference 18 Animation:Reference 18

Galvanic cells, salt bridge, EMF of the cell and free ->Reference :1,Page energy change 264-266 Chapter 7 Types of electrodes, metal metal ion electrodes, gas ->Reference :1,Page electrodes, metal insoluble metal salt electrodes, 284-286 Chapter 7 oxidation reduction electrodes Single electrode potential, Thermodynamics of reversible cell and reversible electrodes Nernst,s equation and applications Electrochemical series and applications Glass electrode, glass electrode potential ->Reference :1,Page 279-281 Chapter 7 ->Reference :1,Page 267-274 Chapter 7 ->Reference :1,Page 281-284 Chapter 7 ->Reference :1,Page 287-289 Chapter 7

Week 6

Lecture 16 Lecture 17 Lecture 18

Animation:Reference 18 Test 2

Week 7

Lecture 19

Approved for Autumn Session 2011-12

Week 7

Lecture 20

Determination of pH using glass electrode, Electrode concentration cells and electrolyte concentration cells liquid junction potential, applications of concentration cells

->Reference :1,Page 290-294 Chapter 7 ->Reference :1,Page 296-297 Chapter 7

Animation: Reference 19

Lecture 21

MID-TERM Part 3
Week 8 Lecture 22 Lecture 23 Lecture 24 Week 9 Lecture 25 Lecture 26 Lecture 27 Week 10 Lecture 28 Coordination compound terminology, Werners theory Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes ->Reference :1,Page 86-90 Chapter 3 ->Reference :1,Page 91-94 Chapter 3 ->Reference :1,Page 94-96 Chapter 3 Animation:Reference 20

Crystal field splitting in square planar complexes ->Reference :1,Page magnetic properties and color in the transition metal 96101-102 Chapter 3 Factors influencing formation and stability of coordination complexes Types of ligands, Isomerism in coordination compounds( structural isomerism) ->Reference :1,Page 97-101 Chapter 3 ->Reference :1,Page 105-110 Chapter 85

Geometrical isomerism, optical isomerism, ->Reference :1,Page stereoisomerism isomerism, ionization isomerism, 110-115 Chapter 3 hydrate isomerism, linkage isomerism, coordination isomerism

Part 4
Week 10 Lecture 29 Lecture 30 Week 11 Lecture 31 Lecture 32 Lecture 33 Week 12 Lecture 34 Lecture 35 Cleavage of covalent bond , electrophile and nuclephile , inductive effect Electromeric effect, resonance effect Hyper conjugation, reaction intermediates( free radicals) Reaction intermediate( carbocations, carbanions carbenes) Introduction, Types of polymerization Mechanism of addition polymerization Thermo set polymer, elastomer, Conducting polymers, and its applications ->Reference :1,Page 341-344357 Chapter 9 ->Reference :1,Page 345-348 Chapter 9 ->Reference :1,Page 348-351 Chapter 9 ->Reference :1,Page 352-356 Chapter 9 ->Reference :1,Page 524-530 Chapter 13 ->Reference :1,Page 530-533 Chapter 13 ->Reference :1,Page 583-587 Chapter 13 Animation:Reference 21 Animation:Reference 22 Animation:Reference 23 Test3

Approved for Autumn Session 2011-12

Week 12

Lecture 36

spill over

Revision

Spill Over
Week 13 Lecture 37 Lecture 38

Details of homework and case studies

Homework No. Objective Topic of the Homework Nature of homework (group/individuals/field work Individual Evaluation Mode Allottment / submission Week 3/3

Class test based to evaluate on homework 1 students on class teaching

Phase rule: Statement and meaning of the terms- phase, component and degrees of freedom Derivation , advantages and limitations of Gibbs phase rule Phase equilibra of one component system-water Phase equilibrium of two component system for eutectic mixtures,cooling curves classius clapeyron equation Thermodynamic system, process , properties, energy of the thermodynamic system first law of thermodynamics and its interpretation and its applications :molar heat capacity

test based performance

Class test based to evaluate on homework 2 students on the basis of there class teaching performance

Reversible isothermal expansion / compression of an ideal gas , Individual adiabatic expansion of the ideal gases Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only ,Entropy change for mixing of ideal gases , entropy of physical and chemical changes Gibbs free energy and its physical significance,Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity Galvanic cells, salt bridge, EMF of the cell and free energy change Types of electrodes, metal metal ion electrodes, gas electrodes, metal insoluble metal salt electrodes, oxidation reduction electrodes Single electrode potential Nernst,s equation and applications,

evauation on the basis of indiviual performance in test

6/6

Approved for Autumn Session 2011-12

Class test based to evauate on homework 3 students on CA

Nernst,s equation and applications, Individual Electrochemical series and applications Glass electrode, glass electrode potential, Determination of pH using glass electrode, Electrode concentration cells and electrolyte concentration cells liquid junction potential, applications of concentration cells,Coordination compound terminology, Werners theory Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes Crystal field splitting in square planar complexes magnetic properties and color in the transition metal complexes Factors influencing formation and stability of coordination complexes Types of ligands, Isomerism in coordination compounds( structural isomerism) Geometrical isomerism, optical isomerism Cleavage of covalent bond , electrophile and nuclephile , inductive effect Electromeric effect, resonance effect

evatuation will be test based performance

11 / 11

Scheme for CA:out of 100*

Component Class Test Frequency 2 Total :Out Of 3 Each Marks Total Marks 10 10 20 20

* In ENG courses wherever the total exceeds 100, consider x best out of y components of CA, as explained in teacher's guide available on the UMS

Plan for Tutorial: (Please do not use these time slots for syllabus coverage)
Tutorial No. Lecture Topic Type of pedagogical tool(s) planned (case analysis,problem solving test,role play,business game etc)

Tutorial 1

Phase rule: Statement and meaning of the termsphase, component and degrees of freedom, Derivation of Gibbs phase rule

Problem solving

Approved for Autumn Session 2011-12

Tutorial 2

phase equilibria of one component system-water. Phase equilibria of two component system, classius clapeyron equation

Problem solving

Tutorial 3

Thermodynamic system, process , properties, energy of Problem solving,Test the thermodynamic system, first law of thermodynamics and its interpretation and its applications :molar heat capacity, Reversible isothermal expansion / compression of an ideal gas , adiabatic expansion of the ideal gases, Thermo chemistry laws, bond energy Entropy, entropy change for isolated system, for ideal gas system only, Entropy change for mixing of ideal gases , entropy of physical and chemical changes, Gibbs free energy and its physical significance Gibbs Helmholtz equation ,application of free energy ,concept of spontaneity, Galvanic cells, salt bridge, EMF of the cell and free energy change, Types of electrodes, metal metal ion electrodes, gas electrodes, metal insoluble metal salt electrodes, oxidation reduction electrodes Nernst,s equation ,electrochemical series and applications Glass electrode, glass electrode potential, Determination of pH using glass electrode Problem solving

Tutorial 4

Tutorial 5

Problem solving

Tutorial 6 Tutorial 7

Problem solving,Test Problem solving

After Mid-Term
Tutorial 8 Electrode concentration cells and electrolyte Problem solving concentration cells,liquid junction potential, applications of concentration cells, Coordination compound terminology, Werners theory, Sidwick and valence bond theory, crystal field theory Crystal field splitting in octahedral complexes, Tetrahedral complexes, Crystal field splitting in square planar complexes magnetic properties and color in the transition metal complexes, Factors influencing formation and stability of coordination complexes Problem solving

Tutorial 9

Tutorial 10 Tutorial 11 Tutorial 12

Types of ligands, Isomerism in coordination compounds Problem solving Electromeric effect, resonance effect, Hyper conjugation, reaction intermediates Introduction, Types of polymerization, Mechanism of addition polymerization, Conducting polymers, and its applications Problem solving,Test Problem solving

Approved for Autumn Session 2011-12

*Each experiment of the lab will be evaluated using following relative scheme:
Component J/E WR VIVA % of Marks 20 50 30

List of experiments :Lecture Number Lecture Topic Pedagogical Tools Or Equipment Planned Glass Apparatus lab Manual Not Applicable

Expremental Determine the strength of given solution of ferrous and D\Group w ammonium sulphate(Mohrs salt) by titrating against 1 potassium dichromate solution Expremental To find the order of the reaction using Iodine Clock and D\Group w method. 2 Expremental To estimate the amount of copper and zinc in a given and D\Group w sample of Brass. 3

Glass Apparatus

Not Applicable

Glass Apparatus

Not Applicable

Expremental To study the hydrolysis of methyl acetate catalyzed by Thermostat water bath and D\Group w HCl at room temperature kinetically. 4 Expremental To determine the equivalence conductance of a weak and D\Group w electrolyte at infinite dilution using kohlraush law 5 Conductivity meter

Not Applicable

Not Applicable

Expremental To calibrate pH meter. To prepare buffer solution and pH meter and D\Group w to determine the pH of buffer solutions. To prepare and 6 describe titration curve for hydrochloric acid- sodium hydroxide titration using pH meter.

Not Applicable

Mid Term
Expremental To verify the Beers-Lambert law for solution of and D\Group w CoCl2.6H2O (in water) and K2Cr2O7 (in water). 7 Expremental To draw a cooling curve of a pure compound and and D\Group w mixture. 8 Colorimeter Not Applicable

Glass Apparatus

Not Applicable

Approved for Autumn Session 2011-12

Expremental Separation of given organic compound using thin layer Glass Apparatus and D\Group w chromatography, and calculate it retention factor. 9 Expremental To detect the functional group of the given compound and D\Group w and prepare it derivative. 10 Glass Apparatus

Not Applicable

Not Applicable

Spill Over
Expremental and D\Group w 11 Not Applicable

Approved for Autumn Session 2011-12