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2/15/2012

TEKNIK REAKSI KIMIA II


http://blog.its.ac.id/mahfud/ mahfud@chem-eng.its.ac.id

Materi
Disain Reaktor Non Isotermal
Pengaruh suhu dan tekanan terhadap Performance reaktor ideal, Perancangan reaktor ideal non isothermal

Aliran non ideal dalam Reaktor


Pola aliran non ideal Distribusi waktu tinggal, Model-model reaktor non ideal

Reaktor Heterogen
Reaktor gas-padat, Reaktor gas-padat katalitik Reaktor gas-cair Bio Reaktor

2/15/2012

Pustaka
Octave Levenspiel, Chemical Reaction Engineering, Edisi 3, 1997. Scott Fogler, Elements of Chemical Reaction Engineering, 3ed, 1999. Froment G, Bishop, Chemical Reaktor, 3ed. Villermaux, Genie de la Reaction Chimique, 2nd ed 1992

About Chemical Reaction Engineering & Engineer

One feature that distinguishes the education of Chemical Engineer from that of other Engineer is an exposure to the basic concepts of Chemical Reaction Engineering

Charles Hill, An Introduction to Chemical Engineering Kinetics and Reactor Design

2/15/2012

About Chemical Reaction Engineering & Engineer

Chemical Reaction Engineering is that engineering activity which is concerned with the exploitations of Chemical Reactions on a Commercial Scale
Octave Levenspiel, Chemical Reaction Engineering

About Chemical Reaction Engineering & Engineer Typical tasks of Chemical Engineer are :
Design of Chemical Processes Maintain and Operate a process Fix some perceived problems Increase capacity or selectivity at minimum cost

Lanny Schmidt, The Engineering of Chemical Reactions

2/15/2012

Scope of Chemical Reaction Engineering


petroleum refining, petrochemicals,chemicals, and pharmaceuticals biotechnology, microelectronics, advanced materials, and energy from non-fossil resources environment, pollution prevention, sustainable development

Chemical Reaction Engineering New frontiers New analytical instrumentation providing quantitative information on species and mechanisms New computational resources hardware and software Multiscale approach

2/15/2012

Top Global Players in 2008


No 1 2 3 4 5 Rank Company BASF (Germany) DOW (U.S.) Lyondal Basell Sales ($ bn) 70.5 57.5 38.4

Exxon Mobile Chemicals (US) 38.4 Ineos (UK) 36


Chemical & Engineering News, August 2009

Narrowing In

Chemical & Engineering News, July 2007

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Chemical Industry Sectors


Category Petroleum Refining Commodity chemicals Fine chemicals Foods Materials Pharmaceuticals Typical Plant (TPA) 106 - 108 104 - 106 102 - 104 Price ($/kg) 0.05 0.05 - 1 1-5 0.5 - 25 0 - .... 10 - ...... E-Factor (Kg/Kg) 0.1 1-3 2 - 10

10 - 103

10-100

Lanny Schmidt, The Engineering of Chemical Reactions

What do you we need to know about chemical processes?

Chemistry is important A+B C + D is not a real reaction Example: Ammonia synthesis N-N + 3 H-H 2 N-H3 Example: aspirin synthesis

Lanny Schmidt, The Engineering of Chemical Reactions

2/15/2012

What do you we need to know about chemical processes?

Single reaction in an ideal single phase isothermal reactor is hardly encountered. Real reactors are extremely complex with multiple reactions multiple phases and intricate flow patterns Example: Ethylene synthesis
C2H6 C2H4 + H2 C2H6 C2H2 + H2 3 C2H6 C6H6 + 6 H2 C2H6 2 C + 3 H2
Lanny Schmidt, The Engineering of Chemical Reactions

What do you we need to know about chemical processes?

Example: Ammonia synthesis CH4 + H2O CO + 3 H2 N2 + 3 H2 2 NH3

2/15/2012

What do you we need to know about chemical processes?

Reactions with simple kinetics are extremely rare. Example: Ammonia synthesis CH4 + H2O CO + 3 H2 N2 + 3 H2 2 NH3

Most industrial processes are heterogeneous

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Transport processes are important


Ammonia Reactor - 1500 t NH3/day, 100 m3 volume, 250 t of catalyst.

Catalyst - Fe with K and Al2O3

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