Combustible Liquids
Any liquid having a flashpoint at or above 100o F (37.8o C).
Class III - shall include those with flashpoints at or above 140 F (60 C).
Class IIIB - shall include those with flashpoints at or above 200 F (93.3 C).
IIIA
140
Flashpoint (Fo)
II
100 73
IC
IA
100 Boiling Point (F)
IB
Triethalemine 17o F Barsol A-2316 54o F Acetone Solvent 0o F Barsol A-2343 56o F Barsol A-3447 0oF N-Butanol 36o F Sec. Butanol 72o F Glycol Ether 94o F
Enamel Reducer 20o F Isopropyl Alcohol 45oF Methanol 45o F MEK 23o F Xylene 79o F Toluene 45o F Gasoline -50o F 142 Solvent 66/3 610 F
Explosive Limits
Explosive limits involve the concentration level of the given chemical in the air.
In popular jargon, a vapor/air mixture below the flammable limit is too lean to burn or explode. A mixture above the upper flammable limits is too rich to burn.
Most flammable liquids are volatile, meaning they evaporate quickly, and can reach a concentration in air that could lead to an explosion.
Controlling the potential for fire and explosion with flammable liquids is done through safe Storage, Transfer, Use and Disposal!
Eliminating flames, static electricity, & sparks from electrical circuits. Temperature. Proper Ventilation. Grounding/Bonding. Spill Control/Emergency Response. Proper disposal of spent flammable liquids and soaked rags.
Safety Can: An approved red container, of not more than 5 gallons capacity, having a spring-closing lid and spout cover and so designed that it will safely relieve internal pressure when subjected to fire exposure.
Oily Waste Can: A self closing metal container used to store oil soaked rags.
Not more than 60 gallons of Class I and/or Class II liquids, or not more than 120 gallons of Class III liquids may be stored in an individual cabinet.
FLAMMABLE
No open flames, smoking, sparks or welding is allowed in flammable liquid storage areas. Store in a cool location. Not outside in direct sunlight. The warmer the flammable liquid is the more vapors it generates! Storage shall be in an open or well ventilated area. Do not store need oxidizers. Drums of flammable liquid shall be grounded. A 10 lbs. fire extinguisher shall be readily accessible within the storage area.
Flammable or combustible liquid drums shall not be stored so as to limit use of exits, stairways, or areas normally used for the safe egress of people. The storage of flammable or combustible liquids in containers or portable tanks is prohibited in office occupancy areas, except that which is required for maintenance and operation of building and operation of equipment.
Leaking containers shall be removed to a storage room or taken to a safe location outside and the contents transferred to an undamaged container.
Liquids shall be kept in covered/closed containers when actually not in use. Open flame and smoking is strictly prohibited in transferring areas. Liquid transfer shall be through a devise drawing through the top of the drum or by gravity through an approved self-closing valve. Transfer by air pressure is prohibited. Containers from which flammable liquids are dispensed are to be grounded and bonded to avoid fire due to static electricity. Flammable liquids are only to be dispensed into approved safety cans.
Open flames, smoking, welding/brazing is prohibited in areas where flammable liquids are store, transferred, used or disposed of. Keep containers and drums sealed when not in use. Clean up spills! Maintain good ventilation. Mixing of flammable liquids is prohibited!
(Mixing flammable liquids can lower their combined flashpoint.)
Rags used to apply flammable liquids are to be disposed of in a self-closing oily waste can.