STATE OF WAER IN FOODS EFFECTS OF DRYING ON PRODUCT QUALITY MOISTURE SORPTION AND DESORPTION RATE OF DEHYDRATION FACTORS THAT INFLUENCE DRYING DRYING METHODS SPRAY DRYING FREEZE DRYING
Vocabulary
Drying, dehydrate, rehydrate, equilibrium relative humidity, water activity, isotherms sorption desorption hysteresis behavior hypothesis capillary semiempirical empirical, critical moisture content
DEHYDRATION
Drying of foods is an important food processing operation used to preserve foods. The distinguishing features between drying and concentration are the final level of water and nature of the product. Concentration leaves a liquid food, whereas drying typically produces product with water content sufficiently low to give solid food.
There are many methods and technologies by which we can dehydrate foods. We must first understand the nature of water in food products to appreciate the difficulties in producing high-quality dried products. Removal of water from foods is not a difficult task. However, removing the water in such a way that the product regains its initial form when rehydrated is not so easy.
Water activity
Water activity (aw)is defined as the ratio of the vapor pressure of water measured at the food surface (Pw)to the saturation vapor pressure of pure water at the same temperature (Pw)
Pw aw o Pw
Water activity
For a cup of water, the vapor pressure over the surface is measured as the saturation vapor pressure, and aw is 1. When there are solutes in the water such as sugars, salts, etc. the vapor pressure over the water surface is lower than the saturation vapor pressure, and aw is reduced to some value less than 1. The reduction in water activity depends on the type of solutes present and their levels.
Water Activity
For food products, the water activity is generally less than 1. aw is related to the moisture content of the food, the types and concentrations of different solutes, and the structure or physical characteristics of the food.
Free water is relatively easy to remove from a food product while bound water takes more energy to release from the food. Thus, the latent heat required to remove a molecule of water from a food increases as the water activity decreases. This is important to those who design drying operations, since the energy requirement to provide sufficient driving force for drying is related to the latent energy of vaporization.
physical changes
As a food product dries out and the water molecules become less mobile, physical changes also occur in the food. As water is removed, the remaining product generally becomes increasingly viscous. The product may go through several regions of properties, where viscosities are intermediate between a pumpable liquid and a stationary solid.
For example, powdered milk products remain dry and stable when maintained below the glass transition temperature. However, if the powder picks up moisture from the air or experiences elevated storage temperature, it may exceed the glass transition curve and be less stable. In this case, powdered milk would be likely to get sticky, and the powder would cake together.
Effect on flavor
One problem with dried foods is that the flavor of the rehydrated product is not the same as that of the original. During drying, flavor compounds that are typically more volatile than water are removed in the drying process. The physical forces that cause water molecules to be removed from the food during drying also cause volatile compounds (alcohols, aldehydes, ketones, etc.) to be removed.
burnt flavor
Dried products have less of these volatile flavoring compounds than the original starting material. In addition, the rates of chemical reactions are enhanced at the elevated temp., and many of these reactions generate undesired flavor compounds. For example, the browning reaction (between reducing sugars and proteins) is enhanced and generates a burnt flavor. (reconstituted milk from a dried powder)
Browning
Other chemical reactions may also take place during drying. Browning occurs in many foods which results in color changes. Protein denaturation can occur during drying, which causes increasd viscosity, Thermal degradation of vitamins and proteins may also influence the nutritional status of dried products.
The extent of these changes depends on the nature of the drying process. Some types of dryers produce products having superior properties on reconstitution. The instant coffee spray-dried and freeze-dried is different. Since freeze-drying does not involve a vapor-liquid interface, the volatile flavor and aroma compounds are not lost during drying, and freeze-dried products have higher quality
Isotherms
By holding a food product in air at different relative humidities and measuring the equilibrium water content, the curve of water content and water activity can be obtained. Its nature depends on whether the food product is being dried or allowed to pick up moisture from the air. The direction of the experimental measurement affects the relationship between water content and water activity. Isotherms
RAT E OF DEHYDRATION
In drying, water molecules must make their way through the food to the surface (internal resistance to drying) in contact with drying air. Once at the surface, water molecules are transfered into the air (external resistance to drying) based on the difference in vapor pressure between the air and the surface. When the vapor pressure in the air reaches the same value as the vapor pressure of water at the surface of the food, drying ceases.
The rate of drying may be limited by either the rate of internal migration of water molecules to the surface or the rate of evaporation of water molecules from the surface into the air, depending on the conditions of drying. In fact most foods switch from an external drying process during initial stages to an internal drying process as the product dries out.
RAT E OF DEHYDRATION
Drying Curves
Drying Curves
A curve of loss of moisture during drying of a food product are typically generated by weighing a sample of food undergoing drying and relating weight loss to moisture content. Moisture content is most often expressed as kg of water per kg of dry product (or matter).
The kg of dry matter (initial product weight minus weight from water) are always constant during drying, so a constant reference point is used when referring to drying in kg water/kg dry matter.
The shape of the drying curve is similar for many food products. After short initial equilibration period (for thermal equilibration), the moisture content decreases rapidly, and almost linearly, with time. This initial drying period is followed by a much slower rate of drying as the moisture content of the product decreases. The rate of drying is the slope of the moisture content change with time, expressed in kg water/kg dry matter-minute.
Energy equation
For the simplest case, where only convective heat transfer occurs, all of the heat energy goes into vaporizing moisture during the constant rate period. That is, the rate of heat transfer into the product is balanced by the rate of energy removal due to the vaporizing moisture. The rate of energy removal with vaporized water can be found as the product of the rate of drying and the latent heat of vaporization. That is, for each molecule of water vaporized at the surface (liquid to vapor), an amount of energy equivalent to the latent heat of vaporization is required.
The constant rate drying period lasts as long as the rate of moisture migration from the interior of the product to the surface is sufficiently rapid that the moisture content at the surface is constant. At the point where moisture migration from the interior is slower than the surface vaporization, the constant rate period ends and the time for constant rate drying, tCRP can be found as:
Liquid diffusion. Vapor diffusion. Capillary flow. Pressure flow. Thermal flow.
DRYING METHODS
1.Direct Contact Dryers
Sun Dryer/Bin Dryer/Kiln Dryer/ Tray or Cabinet Dryer/Tunnel Dryer/Belt or Conveyor Dryer/ Fluidized Bed Dryer/Rotary Air Dryer/Spray Dryer.
2.Indirect Contact Dryers
Drum Dryer
3.Infrared or Dielectric Dryers
Tunnel Dryer
The food product is loaded onto trays that are placed into carts. The carts are input at one end of the tunnel dryer and move through to the outlet. Air blowing within the tunnel causes drying at a specified rate, so that the food product reaches the exit on completion of drying. (1) cocurrent; (2) countercurrent; or (3) mixed flow,
Vocabulary
Spray drying, high pressure nozzle, droplet atomization, centrifugal atomizer, spinning disk, dryer chamber, ambient air, accelerate, cyclone separator, tangentially, segregate, conical, stickiness and agglomeration, reconstitution, dispersability
SPRAY DRYING
Atomization Air Handling Dryer Chamber Powder Separation
Atomization
Atomization produces a cloud of droplets with very large surface area for drying. High pressure nozzle: droplet size is controlled by pressure of the fluid food against the nozzle. Centrifugal atomizer: Liquid food is pumped into a spinning disk, where it is accelerated by centrifugal force and expelled from the ends of the disk-shaped atomizer, become a cloud of droplets .
Air Handling
Ambient air is taken in through a vent and heated prior to circulation into the drying chamber. Heating can be accomplished in several ways. Air can be passed either through steam coils or an electric heater to attain elevated temperatures, typically between l50 and 500.
Dryer Chamber
In the residence time of droplets in the spray drying chamber, the droplets go from a moisture content in the range of about 40% to only about 5-10%. The food droplets are sprayed at the top of the chamber and fall down to the bottom by gravity. Both air and food droplets enter the chamber at the top and fall to the bottom of it, where air is separated from dry powder and the product is removed from the dryer.
Powder Separation
Primary separation of powder is accomplished by gravitational setting of the heavier powder particles. Separation of air and finer powder particles is usually accomplished in a cyclone device. The stream is circulated tangentially into the cyclone separator. Centrifugal force causes the particles to segregate from the air and settle to the bottom of the conical separator. A textile or bag filter is sometimes used.
Product Quality
The ability to be wetted by water during reconstitution, dispersability of the powder into water and solubility in water. Changes in product attributes, particularly at the casehardened surface of the droplets, decreases the ability of a powder to be wetted and dispersed into water. Agglomeration of particles may also influence the amount of surface available for wetting.
Vocabulary
Freeze drying, sublimation, sublimation front, primary and secondary drying stages, radiation collapse, ice crystals, pore, porous channels, diffuse, stress cracking, rehydrate
FREEZE DRYING
Moisture is removed from the solid state (ice) directly to the vapor state by sublimation. Drying actually occurs in two steps, primary and secondary drying stages. It is in the primary stage that water is removed by sublimation, whereas vaporization of unfrozen liquid water molecules occurs in the secondary stage of drying.
Primary Drying
Sublimation of ice is accomplished by controlling the vacuum level in the freeze dryer and through careful heat input. A high vacuum is desired to enhance sublimation rate. Introduction of heat is to supply energy to a plate on which the food is sitting (conduction heating), while also providing a radiation source above the product.
Sublimation Front
The ice recedes into the food product as drying occurs. This boundary between frozen and dried product is called the sublimation front. Heat must be transfered into the product to this front to promote sublimation, and water vapor must then be removed by mass transfer through the dried product
Secondary Drying
Once all the ice is sublimed out of the frozen food, the secondary drying process begins. Heat is continually added, but at a slower rate since moisture loss occurs only by diffusion of water molecules out of the freeze--dried matrix.
Collapse Behavior
Rapid heat addition causes the temperature of the product to exceed its collapse temperature. product becomes suffiiently flowable that it "collapses!' During collapse, the pockets where ice crystals have sublimed disappear as the food slowly flows into these regions. This causes product to have higher density and reduces its ability to be rehydrate.
Vapor Condensor
A condensor collects the vapors as they exit the freeze dryer to enhance efficiency and prevent fouling of the vacuum pump.
Trays
Vacuum System
7500
F
7500 3500
7500 M-5
7500 M-5
22500 7500
7500 M-5
7500
7500
7500 2500
2500 2500
3000
3000
2500
2500 2500
7000
12500 4000
2500
2000 2000
3000
8000
5000
2500 4500
5400
9600
5400
13000
5500
6000
M-1
M-1 2700 2700 M-2 6600 M-2 2700 2700 M-2 4300
23500 11500
2000
1500
M-3
FD
3500
4#
3#
2#
1#
M-3 M-3
2500
11000
2500
FD
3500
9000 7500
1 2
4200 7500
3
4200 7500
5
4200 7500
4200 7500
7 8
7500
4
7500
7500
9
7500
10
7500
11
Problems
Describe the definition of water activity. Describe the relationship between water activity of foods and the relative humidity of environment . What are the CRP & FRP? Describe the cause of them and the differences between them. Describe principles of tunnel dryer and spray dryer.
Problems
Describe the principles of freeze drying. How to understand the concept of collapse during freeze drying. What are the purposes of each step in freeze drying.