GROUP 17 ELEMENT ( HALOGEN GROUP)

The Group 17 elements

WHAT IS THE ELEMNTS IN GROUP 17?????? Complete the blank below: 1. _ l o _ _ _ _ _ 2. C _ _ o _ _ _ _

3. _ _ o _ _ _ _
4. _ _ _ _ _ e 5. _ _ t _ _ _ _ _

Elements :

Flourine Chlorine Bromine Iodine Astatine

Non-metal Known as halogen Exist as diatomic molecule in nature (X2)

PHYSICAL PROPERTIES OF HALOGEN GROUP

Elements

Atomic Numbers

Electron Arrangement 2.7 2.8.7 2.8.18.7 2.8.18.18.7 2.8.18.32.18.7

Fluorine
Chlorine

9
17

Bromine Iodine Astatine

35 53 85

Phase Colour

Physical Properties *things that we can see

Atomic number Atomic radii Electronegativity

Density Melting point Boiling point

Atomic Number

The atomic number can be fined from periodic table Example: Atomic number 17
Cl

Down the group, atomic number will increase

Atomic radii or Atomic Size

Based on atomic number. Example : -F atomic number is 9 so that the electron configuration is 2:7 . This shows that F has 2 shells. -I atomic number is 53, the electron configuration is 2:8:18:18:7. This show that I has 5 shells. -the size of I atom is bigger than F Down the group the atomic radii or size is increase

Electronegativity

Is the power of outer electron attraction to the nucleus Decrease going down a group The large atomic number caused the large size So that the outer most shell is far from the nucleus. Then the electronegativity is lower

Density

All halogens has lower density But density of halogens is increase when going down the group

Melting and Boiling Point.

All halogens has lower melting and boiling point Because of the lower Van der Waals force between the molecule. But the melting and boiling point increase when going down the group. Parallel to the density of each elements.

Phase

The phase changes from gaseous to liquid to solid when going down the group Because the melting and boiling point is increase.

Colour

Every elements has different colours

Pale yellow

Greenish yellow

Deep-red

Bluish black
Iodine

water

alkaline

CHEMICAL PROPERTIES OF HALOGEN GROUPS

metal

Chlorine react with water

KNO
3

Hydrocholoric acid

2 cm3 water

Chemical properties: (a) Reaction with water All the halogens group can dissolve in water to yield acid compound with bleach properties.
X2 + H2O HX + HOX

Cl2 + H2O
Br2 + H2O I2 + H2 O

HCl + HClO
HBr + HBrO HI + HIO

Chemical properties

Bleach properties

(b) Reaction with iron All the Halogens group react with iron to yield ferum halide in reddish brown colour.
HALOGEN + FERUM FERUM HALIDE

2 Cl2 + 2 Fe 2 Br2 + 2 Fe

2 FeCl2 2 FeBr2 2 FeI2

2 I2 + 2 Fe

(c) Reaction with natrium hidroxide Elements Group 17 react with natrium hidroxide to yield salt and water.
X2 + 2NaOH Cl2 + 2 NaOH Br2 + 2 NaOH NaCl + NaOX + H2O NaCl + NaOCl + H2 O NaBr + NaOBr + H2O NaI + NaOI + H2O

I2

+ 2 NaOH

Electron valence group 17 : All elements group 17 have 7 electron valence. When the chemical reaction occur, the atoms this group accept 1 electron to form anion halides. (F, Cl-, Br -, and I-). So that, all the elements have same chemical properties.

Example: Chlorine
Cl + e Cl -

REACTIVITY OF ELEMENTS GROUP 17

. When down to periodic table: Size of atom will increase Electrons valence situated far from nucleus atom. So, The nucleus attraction force on to the electron in electron valence will decrease
F Cl Br I

LESS REACTIVE

REACTIVITY DOWN THE GROUP

F
Fluorine

Cl
Chlorine

LESS REACTIVE

Br
Bromine

I
Iodine

At
Astatine

PRECAUTIONS
Avoid breathing their vapors. Gloves and gogle should always be worn when handling this substances.

Handling in fume cupboard.

Obey the laboratory safety rules.

TAKE A BREAK.

1.) Which one of the statements is true about Group 17 elements.

A. In room temperature, Iodine is exist in liquid state.

C. Chlorine is the most reactive element in Group 17

B. Bromine is more reactive than Chlorine.

D. Astatine is radioactive and non-stable.

2.) Which one will not happen when goes down the Group 17.
A. Decreasing in electronegative.
B. Increasing in molecule size.

C. Decreasing in reactivity
D. Decreasing in melting point.

F Fluorine Cl Chlorine Br Bromine I Iodine At Astatine

3.) Which one at the statements below is true about chlorine and bromine elements.
A. They are group 17 members. C. They have 1 electron in outer shell.

B. They are dissolve in tetrachlorometana to form brown solution.

D. They are gas in room temperature.

SUMMARY

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