SYSTEMS: An overview
BY
Prof. S.C.Kaushik*
If
Ex W
Exergy transfer with heat interaction, (Thermal
exergy) :
Wmax ExQ Q 1 Ta T
Exergy associated with mass transfer or flow. (flow
exergy) : o
h To s
The first law of thermodynamics or equation of energy
balance for steady flow process of an open system is
given :
n
E Q E
in
i 1
i out W
in Exout ExW I
Ex Ex Q
OR
I Exin Exout Ex Q ExW
Destruction of availability = irreversibility
Exergy
Exergy in Exergy out product
Waste
Exergy Loss
Exergy and Anergy
Energy inputs
Useful outputs
Transformation
Material inputs
process
Wastes & emissions
1. Law of Thermodynamics:
Conservation of energy
In non-nuclear processes energy can neither be created nor destroyed. Energy can only
be transformed from one form into another. The total amount of energy input to a non-
nuclear transformation process is thus equal to the total amount of energy output.
Conservation of mass
The total mass of material inputs into a (non-nuclear) material transformation process is
equal to the total mass of material outputs.
2. Law of Thermodynamics
Short form:
In a closed system, entropy (disorder) will increase with time until it reaches
its highest possible value.
What does this mean for material transformation processes (which are open systems):
Space conditioning 30
Refrigeration 25
Water Heating 15
Lighting 10
Cooking 7
Entertainment (T.V. etc) 5
Grinding 5
Washing and others 3
Desired output energy
I
Input energy supplied
Desired output energy
II
Maximum possible output energy
η II = Amin A
Wmax E Q Q 1 To T
in Eout EW I
E E Q
Exergy of steady stream of matter is sum of kinetic, potential and physical exergy.
The physical exergy is given by β − β 0 ,where β = h − To s
And I = To S gen
To , Qo
Surrounding
EW
Qi ,Ti
Reservoirs
First and Second law efficiencies for energy conversion systems
By input A = Wi
Amin = Wo
Shaft work
η I = Wo Wi
Wi Wo
η I = η II Motor
i
Electric motor
Wi
Produce work Wo
Qf
A = Q f ( 1 − To T f )
heat Amin = Wo
Tf
input η I = Wo Q f
from Qf
Wo
reservoir
η II = η I (1−To
Tf ) E
(Heat engine cycle) Qo
at
To
Tf
A = Wi
By input Amin = Qu ( 1 − To Tu ) Tu
Qu
Shaft work η I = Qa Wi Wi
P
η II = η I ( 1 − To Tu )
Wi Qo
Add Carnot heat pump
To
heat Qu
to a
Qf
A = Q f ( 1 − To T f )
heat
Reservoir
input from
at Tu Amin = Qu ( 1 − To Tu )
reservoir at Space at
Tf
η I = Qu Q f
Tf Tu
η II = η I { ( 1 − To Tu ) (1−T
o
Tf )}
Water heater To
By input
A = Wi To
Amin = Qc ( To Tc − 1)
Shaft work Qo
Wi R
Extract η I = Qc Wi
Wi Qc
heat Qc η II = η I ( To Tc − 1)
Tc
from a Carnot refrigerator
cold
Qf heat
reservoir
At Tc input
A = Q f ( 1 − To T f )
from Generator Condensor
Amin = Qc ( To Tc − 1) Tf To
reservoir
η I = Qc Q f Qf Qc
at E P
Tf η II = η I { ( To Tc − 1) ( 1 − To Tf )} W
Qo, Qo''
Absorber Evaporator
Vapour absorption system
To Te
It is apparent that demand of energy is growing steadily which
is being fulfilled by conventional sources.Among all
sectors,major consumption is in domestic& industrial. [1].
In these sectors, maximum consumption is in space
conditioning, refrigeration,water heating and process heating.
Energy conservation and replacement of existing energy
sources with renewable energy should be the present need.
As the Extraction cost of fossil fuels is sky rocketing so
switching over to solar energy is need of today.
It is shown by Petla that sun’s radiation is exergy rich but for
higher collection temperature it will not be economical.
1 cos
14
ex q * 1
3 Ts 3 Ts
For
2 rad ,
ex 0.931q *
To
ex q 1 *
T*
300
0.931q* q* 1
T*
T* 4350o K
An illustration:-For the building space heating
II I 1 To T 1 To T
u f
II .6 1 283 298 1 283 4350 0.0323
For solar collector heating source at 45o C
Temperature in
o
C η II % Solar radiation η II % Using fossil fuel η II % Solar collector
Tu Source
T f = 23000 K
Source
T f = 43500 K T f = Tu + 20
35 1.67 2.68 18.25
50 4.58 7.37 34.08
70 8.07 12.97 43.34
85 10.44 16.76 47.10
100 12.61 20.25 49.62
125 15.86 25.48 52.33
150 18.74 30.09 54.04
190 22.68 36.43 55.74
230 26.00 41.77 56.78
250 27.47 44.13 57.16
270 28.84 46.31 57.47
Solar heat is unique in that its temperature can be obtained by
choosing suitable collector to provide an excellent second law
match between the resource collection and end-use temperatures.
From an end use point of view, solar thermal energy finds its
application as given below.
2. Water heating:-Use of 1000 water heater can save 1 MW power.
3. Cooking :- Saving of fire wood and LPG, saving to consumer
and nation.
4. Industrial applications :--In Food, Textile, Pulp and
Paper,Rubber, Glass and Chemical industries for process heat
application at various temperatures.
5. Power generation [7]:-- Solar farm systems and feed water
heating in place of bleed steam ( Jodhpur )
The use of solar heat can conserve the high quality fossil fuel and
increases the efficiency of energy use.
Second law efficiency of various applications using other sources and solar thermal sources
Application Temperatures Other source Solar collection case
ηII %)
(
ηII %)(
Space heating
By fossil fuels T0 = 283o K ( 10o C ) 4.0 24.4
( ηI = .7 ) [T f = 50o C ]
Tu = 298o K ( 25o C ) 1.5
By electricity ηI = .6
( ηI = .9 )
Space cooling
By electricity T0 = 318o K ( 45o C ) 5.2
(Vapour compression system) 27.33
( ηI= 2) [T f = 110o C ]
Tu = 295o K ( 22o C ) 7.23
By fossil fuels ηI = .6
(Vapour absorption system)
( ηI = .8 )
Water heating
By fossil fuels T0 = 283o K ( 10o C ) 12.39 55.55
( ηI = .7 )
4.66 [T f = 67 o C ]
By electricity Tu = 335o K ( 62o C )
( ηI = .9 ) ηI = .6
Cooking 55.66
By fuels To = 298o K ( 25o C ) [T f = 130o C ]
( ηI = .6 ) 16.67
ηI = .6
Tu = 393 K ( 120 C )
o o
( η I = .8)
Application Temperatures Other source Solar collection case
η II %)
(
η II %)
(
Water heating
By fossil fuels T0 = 283o K ( 10o C ) 12.39 55.55
( ηI = .7 )
4.66 [T f = 67o C ]
By electricity Tu = 335 K ( 62 C )
o o
( ηI = .9 ) η I = .6
Cooking 55.66
By fuels To = 298o K ( 25o C ) [T f = 130o C ]
( ηI = .6 ) 16.67
η I = .6
Tu = 393 K ( 120 C )
o o