Mobility
On/off
Threshold voltage
Organic FET Applications
pixel drivers for
active-matrix
displays and
detectors
Philips Research Penn State Univ.
Univ. Tokyo
Radio-frequency
Identification tags
Wireless power
transmission Electronic paper
Organic Semiconductors
Polymers Small-molecule materials
p-type
p-type
N N
N
N Cu N
S N N N
n
S
S S S S
S S S
n
F F
F F
n-type n-type F N F
N N
F F
O O F F F F F N Cu N
F F F F
N N N
N N F F
F F
N N F F
F F F F F
n
F F
Requirements for FET materials
• Largeπ-Conjugation
• Planar
• Strongly π- π interaction
• Crystal
Organic semiconductors
Carbon
Linear Planar Cyclic Nanotubes
R R
S S N N
N
N HN
S S S
N Cu N NH
. H2SO4
HN
N N N NH HN
S
NH N
R R
R R
S S
R S S S S R
N
S S S S
R R
N
O
- conjugation
S S
Dibenzotetrathiafulvalene Bisimides:
S S
TTF New Building Blocks for Organic Electronic Materials
HOMO
Advanced Materials. 2007, 19, 3037.
(a)
(
b) (c)
Backgroud:
• Fundamental aspects of
carrier transport, especially
the role of solid-state
packing, still remain unclear
• Studies on micro- and
nanomaterials, including
fibers, ribbons, and wires are
few perylo[1,12-b,c,d]thiophene (PET )
and its crystal packing
-6
-8 10 4.0x10
-3
-60 V
-6 10
-7
3.0x10
-3
-4 -3
10
-8
2.0x10
-40 V
-2 -3
-9 1.0x10
10
-20 V
0 0V
-10
0.0
10
0 -20 -40 -60 -80 0 -20 -40 -60 -80 -100
Drain voltage (V) Gate voltage (V)
Transistors based
on an individual
single-crystalline
micrometer wire
of PET have been
fabricated with a
gold wire as
mask.
W: 1.8 µ m
L: 55 µ m
mobility : 0.8 cm2/Vs, an on/off ratio: 1.7×103, threshold voltage : -6 V,
Accepted
2TFMPOIND
F 3C
C8H17
N
N
C8 H17
CF3
L = 68 µ m, W = 1.2 µ m
µ = 0.084 cm2/Vs, on/off = 104
VT = −8.7 V
Stored at ambient for 32 days retained almost identical mobility
高迁移率材料与场效应晶体管
S S
S S S
J. Am. Chem. Soc., 2005, 127, 13281 Adv. Funct. Mater., 2006, 16, 426
N
N
O
J. Am. Chem. Soc., 2006, 128, 15940 J. Am. Chem. Soc., 2006, 128, 13058
电极修饰
Al2O3/CNT
-2
1.2x10
CuPc
1 1µ m
µ m
CuTCNQ
Adv. Mater.,
Adv. Mater., Adv. Mater., 2006, 18, 3010
2006, 18, 6568
2005, 17, 2953 5µ m
100-400 nm
500 nm
5µ m
111
011
Adv. Mater., Adv. Mater.,
J. Am. Chem. Soc.,
2007, 19, 2624 2008, 20, 1511
2006, 128, 12922
Research Roadmap of OFETs
Funding:
NSFC, MOST, CAS
Daoben Zhu, Wenping Hu, Jingui Qin, Deqing Zhang,
Zhaohui Wang, Zhigang Shuai, Wei Xu, Gui Yu, Buxing Han,
Kai Xiao, Yanming Sun, Ying Wang, Lei Fu, Chongan Di,
Hengjun Zhang, Xike Gao, Xianglong Li