EQUILIBRIUM
PREPARED BY:
NURUL HIDAYU BT MOHD YUSOF
D20051021999
THEORY DEFINITION
Ka = [A – ] [H3O K b = [BH+ ] ACID BASE
+
] [OH-] ARRE HENIUS
ARREHENIUS A substance thatA substance that
-Analogy contains hydrogencontain hydroxide
[HA] [B] - Analogy
- Equation reaction (H) and produces(OH) and produces
- Equation H+ in aqueoushyroxide ion OH-
reaction solution. in aqueous
solution.
Ka AND Kb VALUES
- Equation DEFINITION
LEWIS
LEWIS Electron pair Electron pair
- Calculation THEORY - Equation
- Equation reactionacceptor donor
SELF reaction
IONIZATION OF BRONSTED-
WATER LOWRY
-Animation
BR ONSTED-
- Equation
Proton donor Proton acceptor
LOWRY
- Equation - Equation reaction
ACID AND pH AND pH =
w = [H3O+] [OH-] = 1.0 x 10-14 BASE pOH SCALE -log[H+]
-Equation
EQUILIBRIUM
- pOH =
ACID BASE Calculation -log[OH-]
INDICATOR BUFFER
SOLUTION pOH = pKb + log [salt]
- Steps pH + pOH =
-Types 14
- Calculation [base]
pH = pKa ± 1
ACID BASE
DEFINITION: DEFINITION:
A substance that contains hydrogen A substance that contain hydroxide
(H) and produces H+ in aqueous (OH) and produces hyroxide ion OH-
in aqueous solution.
solution.
ACID
BASE
Proton donor
Proton acceptor
EQUATION REACTION:
proton acceptor
proton donor
LEWIS THEORY
ACID BASE
Electron pair Electron pair
acceptor donor
:O:
.. .. .. II ..
:O: + :O=C=O: O–C
-O .. :
H H H H
Ka AND Kb VALUES
EQUATION FOR WEAK ACID
(HA) EQUATION FOR WEAK
BASE(B)
HA + H2O H3O+ + A
–
B + H2O BH+ + OH-
Ka = [A – ] [H3O K b = [BH+ ]
+
] [OH-]
[HA] [B]
K b = base dissociation
constant @
K a = acid dissociation Base ionization constant
constant @
acid ionization constant K b bigger, base becomes
stronger
K a smaller, acid become
Example 1
Calculate the concentration of OH- form and percent of
ionization for 0.10M NH3 .(K b = 1.8 x 10 -5 )
Solution
NH3 + H2O NH4+ +
OH-
Initial [ ] , M 0.10 0 0
Equilibrium [ ], M 0.10 – x x x
K b = [x] [x] = 1.8 x
10 -5
[0.10 – x]
% ionization = 1.3 x 10 -3 M X
Using approximation
100%
method:
0.10M
0.10 – x ≈ 0.10
= 1.30 %
So,
x 2 /0.10 = 1.8 x 10 -5
x = [OH- ]= 1.3 x 10 -3 M
Dissociation, self-ionization of
water, Kw
pH = pKa ± 1
4) In the case of phenolphthalein the
colour can only detect by the eyes in
the pH of 9.5 ± 1
That is from pH 8.50 to pH 10.50