Li gh t!
Light
• The study of light led to the development of
the quantum mechanical model.
• Light is a kind of electromagnetic radiation.
• Electromagnetic radiation includes many kinds
of waves.
• All waves move at 3.00 x 108 m/s (abbreviated
with a “c”) when in a vacuum (actually 2.9979
x 108 m/s).
Parts of a Wave
Crest
Wavelength
(λ )
Amplitude
Origin
Trough
Frequency
• The number of waves that pass a
given point per second.
• Units are cycles/sec or hertz (hz)
• Abbreviated with the Greek letter nu
(ν)
Frequency & Wavelength
• Are inversely related
• As one goes up the other goes down.
c=λ ν
• Different frequencies are different colors of
light.
• There is a wide variety of frequencies.
• The whole range is called the spectrum
Practice
What is the wavelength of radiation
whose frequency is 1.50x10 /s?15
∆ E=nhν
6.626 x 10-34 Js,
which is now known as
Planck’s constant and
has the symbol, h.
Introducing Mr. Albert
Einstein
The Photoelectric Effect
It was determined experimentally that light
shining on a metal surface will eject electrons
from the metal surface.
c=ν λ
E=mc 2 ∆ E=nhν
c
ν = ___ E photon=hν
m= E
c2 λ Ephoton=hc
λ
m= E Ephoton=hc
c2 λ
m= hc/
cλ2
m= h
cλ
• Does this mean that photons have mass?
– yes, in some sense, but only when it is moving
• But isn’t light a wave?
– yes, some times it is Huh?
Wave/Particle Duality
Some times you feel like a nut, sometimes you don’t.
Wave-Particle Duality
Atomic
Spectrum
So how does color tell us about
atoms, I mean really, get on with
it! XD
A Prism
• White light is made up
of all the colors of the
visible spectrum.
• Passing it through a
prism separates it
because the different
wavelengths bend at
different angles when
entering and leaving the
substance.
If the light is not white
• By heating an element with
electricity or heat, a characteristic
color of light is given off. When
this light is passed through a
spectrum, there are distinct
wavelengths of light present and
nothing in between!
• This unique fingerprint, can be
used to identify elements present in
suns, other planets, unknown
samples, etc.
• mercury (Hg)
• sodium (Na)
• neon (Ne)
Nothing bohring about Niels
Bohr
• In 1913, Niels Bohr developed a theoretical
explanation for the observed emission spectra
of the Hydrogen Atom.
• Bohr Assumed that electrons were orbiting the
nucleus and from classical physics, he
assumed that they traveled in a circular path
much like planets did around the sun.
• Bohr borrowed the idea of quantized energy
from our good friend Maxwell Planck.
Niels Bohr
Bohr proposed that only orbits of certain radii,
corresponding to defined energies are
“permitted.”
An electron orbiting in one of these “orbits”
has…
1. A defined energy state.
2. Will not radiate energy
3. Will not spiral into the nucleus.
Excited Energy States
If you add energy to an electron it can jump from one
energy level to another producing an excited state.
Ground State
H: 1st level Excited State
H: 2nd level
1
H
Atomic Emission
A photon of light is emitted when the electron returns
to it’s ground state and releases the previous quantum
amount of energy absorbed.
1
H
There are many energy levels
and many transitions that
Balmercan
Series: occur
(visible) Paschen series:
(infrared)
Lyman Series:
(ultraviolet)
n =7 6 5 4 3 2 1
1
H
Review: Bohr’s Model
Electrons exist in specific energy levels outside the
nucleus, can move from one level to another, and
occupy the “lowest” energy levels possible under
stable conditions.
When exposed to energy (electrical current, flame,
etc.), electrons absorb a quantum of energy and
move to an “excited” state. Energy is released in the
form of light when the electrons return to the
“ground” state.
The further an electron “jumps” the more energy is
absorbed or released when it returns to it’s ground
state.
To Review: Light
Properties
• Light has a dual nature. It behaves as both a particle
and a wave. Electromagnetic radiation, which was
previously thought to exhibit only wave properties,
seems to show characteristics of particulate matter
as well and can be considered as a stream of
photons.
• Energy is quantized, it seems to occur only in
discrete units called quanta. Light energy depends
on it’s frequency as shown on the next slide.
To Review: Energy is
Quantized
•The Quantum of Energy was equal to…
∆ E = nhν
E is the energy of the photon
ν (nu) is the frequency
h is Planck’s constant = 6.626 x 10 -34 Joule
sec
n is an integer (1, 2, 3, etc.)
•A Joule is the metric unit of Energy
Review of Joules
• Energy is a force moving through a distance. Force is
equal to mass times acceleration. Therefore…
• Force = ma (mass times acceleration)
Acceleration = meter/s2
Mass is measured in kilograms…
• And so a Force = kilogram ⋅ meter/s2
Which, incidentally is called a Newton.
• Joule = Force times a distance
• Therefore, Joule = (kg ⋅ m2)/s2
• And now you have units for Energy!
The End!!