r
H
0
= -3167Kj/mole
hesss law of constant
heat summation
If a reaction takes place in more than one step then
total enthalpy change in each step is equal to sum of
standard enthalpy in each step at same temperature
r
H = H
1
+ H
2
+ H
3
+H
4
Standard enthalpy of
combustion
Enthalpy change during combustion of one mole
substance at specific temperature. It is denoted by
cH
0
Enthalpy of atomization: aH
o
Enthalpy change to
get atom is gaseous state.
H
2
2H aH
o
436KJ/mole
Bond enthalpy
Enthalpy change during the formation of bond or
dissociation of bond of one mole substance is called
bond enthalpy.
Bond enthalpy = Hr Hp
Enthalpy of solution
Enthalpy change when one mole of solute dissolve in
specific amount of solvent
If more the lattice enthalpy the solute will not
dissolve CaF
2
is less soluble than CaCl
2
. Since, lattice
enthalpy of CaF
2
is high.
Lattice Enthalpy
Enthalpy change in ionic compound when one mole of
ionic compound dissociate into its ion in gaseous
state. It cannot be measured directly. So it is
determined by Born Habber cycle.
f
H
0
=
sub
H
0
+
ion
H
0
+
diss
H
0
+
EG
H
0
+
Latti
H
0
Na(s)
sub H0
Na (g)
IE H0
Na
+
Na
+
+ Cl
-
LatticeH0
NaCl
Cl
2
dissH0
Cl
egH0
Cl
-
Spontaneous Process
The process which occur naturally i.e. no external
energy is supplied to carry spontaneous process.
Physical spontaneous
processes
Flow of water from high level to low level, mixing of
ink in water, free expansion of ideal gas.
Chemical spontaneous
process
They are generally exothermic.
C
8
H
18
+ O
2
CO
2
+ H
2
O
Endothermic
spontaneous process
2Na
2
O
5
4NO
2
+ O
2
H = -1095KJ/mol
Non spontaneous
Process
The process which needs external energy to carry out
is called non spontaneous process.
Eg- Flow of water from low level to high level
Entropy [s]
It measures degree of randomness. S = q
reversible/T
S = Sp Sr
S
total
= S
system
- S
universe
gibbs free energy
Max available energy of system that can be converted into useful
work.
G = H Ts
G = H TS
G = Gp Gr
To show G
system
= -TS
total
S
total
= S
system
+ S
surrounding
= S
system
- H
system
/T
or, TS
total
= TS
system
- H
system
H
system
- TS
system
= -TS
total
Therefore G
system
= -TS
total
If G < 0(-ve) process is spontaneous, G > 0 (+ve) process in non-
spontaneous and if G=0 Equilibrium
relation between g
0
and Kc
We know that G = G
0
+ 2.303RTlog
e
Qc
At equilibrium G = 0, Qc = Kc
Therefore, G
0
= -2.303RTlog
e
Kc
Thermodynamical
Laws
First law of thermodynamics :- Energy of isolated
system remains constant.
Second law of thermodynamics :- Entropy of the
system increase during every spontaneous process
S > 0 and at equilibrium S =0
Third law of thermodynamics :- Entropy of perfect
crystalline system at absolute zero (0) is zero.
Formulae
U = q + w
H=U + PV
for gas H=U + nRT
r
H = Hp - H
r
S = q/T
S = Sp Sr
G = H TS = Gp Gr
G = G
0
+ 2.303RTlog
e
Qc
G
0
= -2.303RTlog
e
Kc
Cp Cv = R C
m
= c/n
f
H
0
=
sub
H
0
+
ion
H
0
+
diss
H
0
+
EG
H
0
+
Latti
H
0