The Reactions
of Alkynes
An Introduction to
Multistep Synthesis
Nomenclature of Alkynes
An alkyne is a hydrocarbon that contains a carboncarbon triple bond.
General formula: CnH2n2 (acyclic)
CnH2n4 (cyclic)
Nomenclature of Alkynes
Addition of an electrophile
to an alkene
Addition of an electrophile
to an alkyne
Formation of a -Complex
A primary vinylic cation is less sable than a primary alkyl cation.
Acid-Catalyzed Addition of
Water to an Alkene
Acid-Catalyzed Addition of
Water to an Alkene
KetoEnol Interconversion
HydroborationOxidation
BH3 Is an Electrophile
9-BBN or R2BH
HydroborationOxidation
Lindlar Catalyst
Syn Addition
Why Cis?
The catalyst delivers the hydrogens to one side of the triple bond.
2014 Pearson Education, Inc.
Anti Addition
Why Trans?
Two Steps
Synthesis
Designing a Synthesis
Designing a Synthesis
Designing a Synthesis
Designing a Synthesis
Designing a Synthesis
Designing a Synthesis
Designing a Synthesis