Multiple Reactions
A. SARATH BABU
Scope:
Limited to Qualitative treatment
Design aspects not included
Selectivity:
A R (desired reaction)
A S (undesired reaction)
Selectivity = rdesired/rundesired
The selectivity should be maximum for the
chosen reactor.
Yield = rdesired /-rA
Parallel reactions
Series reactions
Series-Parallel reactions
Parallel reactions
A R (desired reaction)
A S (undesired reaction)
dCR
rR
k1C A
dt
dCS
rS
k 2C A
dt
dCR k1
S
CA
dCS k 2
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Case 1: ED > EU
High temperature is desirable as it
maximizes the selectivity.
Case 2: ED < EU
Low temperature is desirable as it
maximizes the selectivity.
Case 3: ED = EU
Temperature level does not affect
the selectivity.
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Conclusions:
For parallel reactions, the concentration level of
the reactants is the key to control product
distribution.
High reactant concentration favors the higher
order reaction
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Series reactions:
A R S (I order at constant density)
Batch Reactor:
topt
ln( k 2 / k1 )
1 / klog mean
k 2 k1
CR ,max
C A0
k1
k2
k2
( k 2 k1 )
opt
ln( k 2 / k1 )
1 / k log mean
k 2 k1
CR ,max
C A0
k1
k2
k2
( k 2 k1 )
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CSTR:
C A0 C A C A0 C A C A 1 k
1
C A0
rA
k1C A
Material balance for species R:
vCR0 = vCR + (-rR)V
0 = vCR + (-k1CA+ k2CR)V
0 = CR + (-k1CA + k2CR)
CR(1 + k2) = k1CA
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k1C A0
k1C A
CR
1 k2 (1 k1 )(1 k2 )
For maximum concentration of R: dCR/d = 0
CR ,max
C A0
opt
k 2 / k1 1
k1k2
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PFR
CSTR
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Conclusions:
For series reactions, the time of reaction /
space time is the key for obtaining the maximum
concentration of the desired product.
For higher order reactions and series-parallel
reactions, such analytical derivations for
optimum space time would be tedious.
In such cases, optimization methods can be used
to find the optimum space time and the
corresponding maximum concentration of the
desired product.
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Assignment:
1. Find expressions for optimum space time and
maximum concentration of R for the following
series reaction, if k1 = k2 in both CSTR and PFR
A R S (I order at constant density)
2. Find expressions for optimum space time and
maximum concentration of R for the following
series reaction, if k1 = 2k2 in both CSTR and
PFR
A R S (I order at constant density)
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ANY CLARIFICATIONS ?
Berrill, N.J.
A great teacher is not simply one who imparts knowledge to his
students but is one who awakens their interest in the subject and
makes them eager to pursue it for themselves. An outstanding teacher
is a spark plug, not a fuel line.
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