http://teacherweb.com/CA/NovatoCharterSchool/Betz6thGrade/gallery1.aspx
Chapters
14.1-14.2
14.5-14.9
14.11
Pages
526-531
536-553
557-560
Chapters
17.1-17.2
17.5-17.9
17.11
Pages
656-661
668-689
694-696
Brnsted-Lowry
Acid is a proton donor
Base is a proton acceptor
Arrhenius
Acid produces H+(aq)
Base produces OH-(aq)
Brnsted-Lowry:
Based on proton-transfer reactions
H 2 SO4 H 2O HSO4 H 3O
acid
base
base
HSO4 H 2O
SO42 H 3O
H 2 SO4
H 3O +
!! Acid is a substance that donates a
proton
Base is a substance that accepts a
proton
HSO4H 2O
SO42-
acid
H 2 SO4
H 2 PO4 H HPO42
HPO42 H PO43
oxalic acid
H 3 PO4 3H PO43
citric acid
Amphoterism
A substance that is able to donate and accept a proton is amphoteric
H 2O, HSO4 , H 2 PO4 , HPO42 , HCO3 , ...
CH 3COOH H 2O CH 3COO H 3O
conjugate pair 1
conjugate pair 2
!!
The position of equilibrium
favours transfer of the
proton to the stronger bas
CH 3CH 2 NH 2 H 2O CH 3CH 2 NH 3 OH
conjugate pair 1
Acid dissociation
(always written as the donation of a proton in forward reaction)
HA H 2O A H 3O
A H 3O
Kd Ka
HA
HA OH
A H 2O HA OH
HA H 2O A H 3O
Kb
A H 2O HA OH
A H 3O
Ka
HA
Kb
HA OH
H 2O H 2O H 3O OH
K K a K b K w
K a , HA
Kw
K b , A
For acids
The acid-dissociation constant Ka
(also called as a constant of acidity
is the same as the dissociation
constant Kd of that acid
Base dissociation
B H 2O BH OH
BH OH
K d Kb
B
B H 3O
BH H 2O B H 3O
B H 2O BH OH
Ka
BH
BH OH
Kb
B
B H 3O
BH H 2O B H 3O
Ka
H 2O H 2O H 3O OH
K K b K a K w
BH
Kb,B
Kw
K a , BH
For bases
The base-dissociation constant Kb
(also called as a constant of basicity
is the same as the dissociation
constant Kd of that base
pK a log K a
For bases:
Strength expressed as the dissociation constant
i.e., as the constant of basicity
Or as a weakness of conjugate acid,
Kb K d
pKb log K b 14 pK a ,conj
K a ,conj
Kw
Kb
K a ,stronger K a ,weaker
pK a pK b 14
pK a ,stronger pK a ,weaker
!!
cdissociated
cbulk
cbulk
cbulk
cundissociated
cbulk
-1.E-04
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
7.E-20
1.E-04
c
2.E-04
3.E-04
Equilibria calculations
Weak acid dissociation
HA A H
A
{EN } H
cHA HA A
simplification
{SB}
cHA
H
Ka
cHA
HA cHA
H K a cHA
HA H A
A
cHA
H 2O H OH
H H
Equilibria calculations
Weak acid dissociation HA A H
2. The simple method (low concentration of the acid)
H A
Ka
HA
A
{EN } H
cHA HA A
{SB}
HA cHA
A cHA H
K a H
K
H a
2
HA H A
H 2O H OH
H
Ka
cHA H
H
H H
K a cHA 0
4cHA
1
Ka
Equilibria calculations
Weak acid dissociation HA A H
3. The rigorous method (all concentrations of the acid)
H A
Ka
HA
A OH
{EN } H
{SB} cHA HA A
K w H OH
Ka
Kw
Kw
cHA H
H
3
K a H
K a cHA K w H
H solved numerically
K
w K a
(22/3 3 9cK a 2
9cK
2
a
2 K a 3 18 K a K w 4 3cK a K a 2 3K w 2 K a 3 18K a K w
2
2 3 2 3cK a K a2 3K w
9cK a
2
9cK
2
a
2 K a 18 K a K w 4 3cK a K a 3K w 2 K a 18 K a K w
3
2Ka ) / 6
1.E-04
1.E-05
[H+]
1.E-06
Metho
d 1
Metho
d 2
1.E-07
1.E-08
1.E-09
1.E-07
1.E-05
cHA
1.E-03
1.E-01
pKa=0
pKa=1
1.E-01
pKa=2
pKa=3
1.E-02
pKa=4
pKa=5
1.E-03
pKa=6
pKa=7
[H+]
1.E-04
pKa=8
pKa=9
pKa=10
1.E-05
1.E-06
1.E-07
1.E-08
1.E-09
1.E-07
1.E-05
1.E-03
cHA
1.E-01
1.E+01
pKa=0
pKa=1
10
pKa=2
pKa=3
% of dissociation
1
pKa=4
pKa=5
pKa=6
0.1
pKa=7
pKa=8
0.01
pKa=9
pKa=10
0
1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00
cHA
Equilibria calculations
Weak base dissociation
B H 2O BH OH
B H 2O BH OH
OH
{EN } BH
cB B BH
{SB}
B cB
BH cB OH
H 2O H OH
OH OH
OH
Kb
cB OH
OH
Kb OH
K
OH b
2
K b cB 0
4cB
1
K b
Equilibria calculations
pH of salts
Rule of thumb:
K a Kb
pH 7
K a Kb
pH 7
A salt of a weak
A salt of a strong acid and a weak base will be acidic (pH < 7)acid
and a weak
NH 4OH HCl NH 4Cl H 2O
base :
(NH4CN)
A salt of a weak acid and a strong base will be basic (pH > 7)
Depends on
NaOH HCN NaCN H 2O
mutual
size of Ka & Kb
Equilibria calculations
pH of salts
A salt of a weak acid and a strong base will be basic (pH > 7)
(fully dissociated)
CH 3COO H 2O CH 3COOH OH
(hydrolysis)
Equilibria calculations
pH of salts
A salt of a weak acid and a strong base will be basic (pH > 7)
(fully dissociated)
CH 3COO H 2O CH 3COOH OH
(hydrolysis)
5 equations to solve
{SB1}
Na cCH3COONa
{SB 2}
CH 3COOH CH 3COO
{EN }
H Na
CH 3COO
OH
CH 3COO H
Ka Kd
CH 3COOH
K w H OH
cCH3COONa
Quite messy
calculation
c K a H
K w H
K a Kw
2.E-07
pKa=0
2.E-08
pKa=1
pKa=2
2.E-09
pKa=3
pKa=4
[H+]
pKa=5
2.E-10
pKa=6
pKa=7
2.E-11
pKa=8
pKa=9
2.E-12
1.E-09
pKa=10
1.E-07
1.E-05
1.E-03
csalt
1.E-01
1.E+01
c K a H
K a K w
c Ka
K w H
K a K w
c
K a K w 0
pH
1
14 pK a log c
2
2.E-07
2.E-07
2.E-08
2.E-08
2.E-09
2.E-09
[H+]
[H+]
2.E-10
2.E-10
2.E-11
2.E-12
2.E-11
2.E-12
1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00
csalt
c K b OH
OH
K b K w
c Kb
K w OH
K b K w
c
K b K w 0
pOH
1
14 pKb log c
2
2.E-07
2.E-07
2.E-08
2.E-08
2.E-09
2.E-09
[OH-]
[OH-]
2.E-10
2.E-10
2.E-11
2.E-12
2.E-11
2.E-12
1.E-10 1.E-09 1.E-08 1.E-07 1.E-06 1.E-05 1.E-04 1.E-03 1.E-02 1.E-01 1.E+00
csalt
(fully dissociated)
NH 4 H 2O NH 3 H 3O
CN H 2O HCN OH
2 H 2O H 3O OH
six unknowns
K a , NH 4
K b ,CN
Kw
NH 4 NH 3 csalt c
{SB 2} CN HCN csalt c
Ka
Kw
K a , HCN
NH 4 , CN , NH 3 , HCN , H 3O , OH
{SB1}
{EN }
Kw
K b , NH3
NH 4 H
CN
OH
H CN
HCN
NH 4 OH
Kb
NH 3
K w H OH
K a x K w
x H
K b x K w
K b x 3 K a K w x
x2
pH f c, K a , K b
csalt=10-5 mol/L
csalt=10-4 mol/L
csalt=10-3 mol/L
pH=4
pH=5
pH=3
pH=10
pH=9
pH=11
11
11
11
pKa=3,
pKb=4
6.0
pKa=3,
pKb=5
5.5
pKa=3,
pKb=6
pH 5.0
pKa=3,
pKb=7
4.5
pKa=3,
pKb=8
4.0
pKa=3,
pKb=9
3.5
pKa=3,
pKb=10
3.0
-8
-7
-6
-5
-4
-3
-2
-1
-log(csalt)
pKa=3,
pKb=4
6.0
pKa=3,
pKb=5
5.5
pKa=3,
pKb=6
pH 5.0
pKa=3,
pKb=7
4.5
pKa=3,
pKb=8
4.0
pKa=3,
pKb=9
3.5
pKa=3,
pKb=10
3.0
-8
-7
-6
-5
-4
-3
-log(csalt)
-2
-1
K a x K w
K b x K w
x2
K b x3 K a K w x
x H
K a K w
Kb
K b x 3 K a K w x 0
K b x 3 K a K w x
1
log H log K a log K w log K b
2
pH =
1
pK w + pK a - pK b
2
pH 7
pK a pK b
2
K b x 2 K a K w
x2
K a K w
Kb
pH log H
ACID
OH
pOH log
pH 14 pOH
None
Weak
Strong
H2 O
HCN
HCl
H K w
H K a c
H c
NH4OH
NH4CN
NH4Cl
OH K b c
K
H K w a
K
NaOH
NaCN
BASE
None
Weak
Strong
OH c
K a K w
c Ka
OH
K b K w
c Kb
NaCl
H K w
. the bulk concentration (what has been put into the water) of acid/base/salt
pK b 4.8
c 0.25 mol/L
None
Weak
Strong
H2 O
HCN
HCl
pH 7
pH 4.9
pH 0.6
NH4OH
NH4CN
NH4Cl
pH 11.3
pH 9.2
pH 4.9
NaOH
NaCN
NaCl
pH 13.4
pH 11.3
pH 7
BASE
None
Weak
Strong
. the bulk concentration (what has been put into the water) of acid/base/salt
None
Weak
Strong
BASE
HBr
None
NH4OOCH
Weak
KOH
Strong
. the bulk concentration (what has been put into the water) of acid/base/salt
H :N H H
|
N H
|
NH
H B :N H H B N H
involved
No protons
H :N H H
|
N H
|
NH
H B :N H H B N H
involved
No protons