Grafik Intensitas-2theta
Perbandingan
polimer
difraktogram
bahan
Uses: fingerprinting
Single
or multi-phase
Two different crystalline
phases are present in this
pattern one in a very
small amount
kartu Hanawalt
Menggunakan
kartu PDF
Search-Match
Databases
Hanawalt card
PDF Data
Example
ICDD
Good
.
ICDD
Bad.
I/Io
diidentifikasi
d()
I/Io
3.25
10
1.00
20
2.82
100
0.95
2.18
0.94
20
1.99
60
0.89
20
1.71
0.86
1.63
30
0.85
20
1.42
20
0.82
10
1.25
30
0.79
10
1.15
30
0.78
20
1.09
Hanawalt card
QM
STRONGEST REFLECTION
PSC
Chemical
formula
Common
name
2.82X
1.993
3.992
CP5
Ca0.6Sr0.4NbO3
47-35
2.82X
1.999
3.266
CF8
PdO
46-1211
2.829
1.99X
2.306
CP5
KMgF3
18-1033
2.82X
1.996
1.632
CF8
NaCl
2.82X
1.99X
1.998
CP2
BePd
Hallite,syn
PDF#
05-628
18-428
d()
Result
I/Io
d()
I/Io
3.25
10
1.00
20
2.82
100
0.95
2.18
0.94
20
1.99
60
0.89
20
1.71
0.86
1.63
30
0.85
20
1.42
20
0.82
10
1.25
30
0.79
10
1.15
30
0.78
20
1.09
QM
STRONGEST REFLECTION
PSC
Chemical
formula
Common
name
2.82X
1.993
3.992
CP5
Ca0.6Sr0.4NbO3
47-35
2.82X
1.999
3.266
CF8
PdO
46-1211
2.829
1.99X
2.306
CP5
KMgF3
18-1033
2.82X
1.996
1.632
CF8
NaCl
2.82X
1.99X
1.998
CP2
BePd
Hallite,syn
PDF#
05-628
18-428
Analisis Kualitatif
Sampel
2
intensitas
PDF No :
PDF No :
intensitas
PDF No :
intensitas
intensitas
Sampel
2
PDF No :
intensitas
PDF No :
intensitas
PDF No :
intensitas
intensitas
Sampel
2
PDF No :
intensitas
PDF No :
intensitas
PDF No :
intensitas
intensitas
Search-match
Search/Match
Search programs assist in identifying
phase mixtures:
Example: hasil
pengujian xrd
Hasil pengujian
XRD
Talc is a major ingredient in certain cosmetic products. If it contains quartz or other abrasive
minerals, it is unsuitable for cosmetic applications. Chemical analysis cannot differentiate
between SiO2 present as quartz and SiO2 present as talc. X-ray diffraction analysis is an easy and
reliable way to ascertain the presence and quantity of quartz. The peaks in the x-ray pattern below
reveal that a minor amount of quartz (brown), along with some chlorite (green), is present in the
talc (blue). Through special procedures and with the use of quartz and talc standards, the amount
of quartz can be quantitatively determined to levels of less than 1%.
In other industrial mineral applications, health hazards such as respirable silica and asbestos in
dust samples or products of commerce can be determined by x-ray diffraction. Crystallization
chemistry is a complex science used in the production of compounds ranging from table salt and
potash to borax and Epsom salts. Minute changes in the crystallization system can cause
significant changes in the product that may not be detectable by chemical analysis or microscopy.
One project required that we determine quickly whether the particles forming in a sodium
carbonate process were hydrated, anhydrous, or a mixture of the two. The pattern below was
obtained by x-ray diffraction analysis and showed the presence of both forms. This permitted us
to change the process to generate the desired product.
Dust sample
Karakter
Tinggi puncak
(intensitas)
Identifikasi
Komposisi
Hamburan tak-koheren
Extinction
Preferred-orientation
Kesalahan 20
Ketidaktepatan penempatan
sampel
komposisi Wrel,i
s i ZMV i
N
s ZMV
k 1
Menghitung
Menghitung
ukuran kristal
estimasi regangan
rms
H L H L, S
U U S
32 ln 2