Materials
How does corrosion occur?
Which metals are most likely to corrode?
What environmental parameters affect
corrosion rate?
How do we prevent or control corrosion?
Chapter 17 - 1
automobiles and
other equipment
Cost:
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-- the destructive
electrochemical
attack of a material.
-- Ex: Rusting of
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Figure 12.2
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Figure 12.4
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Figure 12.5
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Figure 12.6
ELECTROCHEMICAL CORROSION
Ex: consider the corrosion of zinc in an acid solution
Two reactions are necessary:
-- oxidation reaction:
-- reduction reaction:
H+
Oxidation reaction
Zn
Zn2+
H+
Zinc
H+
H+ +
H
H+
H2(gas)
H+
reduction reaction
Acid
solution
Chapter 17 - 7
H2(gas)
Mn+ H+
ions
H+
e-
25C
e-
ne -
2e -
Mn+
ions
metal, M
metal, M
ne -
e-
Platinum
e-
H+ 2e H+
H2(gas)
Platinum
-- Corrosion
25C
o
Vmetal
0
(relative to Pt)
o
metal
(relative to Pt)
more anodic
more cathodic
EMF series
metal
Au
Cu
Pb
Sn
Ni
Co
Cd
Fe
Cr
Zn
Al
Mg
Na
K
o
Vmetal
+1.420 V
Ex: Cd-Ni cell
+0.340
o
o
V
<
V
Cd corrodes
Ni
Cd
- 0.126
- 0.136
+
- 0.250
V o =
- 0.277
0.153V
- 0.403
- 0.440
Cd
Ni
25C
- 0.744
- 0.763
- 1.662
1.0 M
1.0 M
- 2.363
Cd 2+ solution Ni 2+ solution
- 2.714
Adapted from Fig. 17.2,
Data based on Table 17.1,
Callister & Rethwisch 9e.
- 2.924 Callister 9e.
Chapter 17 - 9
GALVANIC SERIES
more anodic
(active)
more cathodic
(inert)
Chapter 17 - 10