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q
heat
SYSTE
M
W
work
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q
heat
SYSTE
M
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W
wor
k
U = q - w
Unuclear
MeV
Uelectronic
: nuclear binding
energy
: electronic energy
Uvibration
: vibration energy
cal/mole
Urotation
: rotation energy
cal/mole
eV
cal/mole
Chemical Energy :
Chemical reactions involve the
rearrangement of atoms. No new
atoms are created or destroyed.
(Daltons Atomic Theory)
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U = q - w
A CONCEPT
unmeasurable
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A PHYSICAL
QUANTITY
measurable
A PHYSICAL
QUANTITY
measurable
U : How to measure?
Considering that mechanical work w is equal
to pV :
U = q - p V
U = q v
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measurable calorimetrically
at constant volume
H = U + pV or H = U + pV
U + p V = qp
H = q p
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measurable calorimetrically
at constant pressure
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10
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11
G =
Net energy
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H - TS
Total
energ
y
Correction
for useless
Energy
12
G = H - T S
Chemica
l
Bonding
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System
Structurin
g
13
CHEMICAL
BONDING : A
Thermodynamic Perspective
+
A
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A B
14
ATRACTIVE ENERGY :
Between nucleus A and
electron B
Between electron A and
nucleus B
Uatt= - Catt/r
REPULSIVE ENERGY :
Between nucleus A and
nucleus B
Between electron A and
electron B
Urep= + Crep/r
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15
U
Urep= + Crep/r
r
Uatt= - Catt/r
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16
Urep= + Crep/r
Uatt= - Catt/r
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17
BOND ENERGY :
The energy required to break down
chemical bond into separate atoms
BOND LENGTH :
The equilibrium distance between two
atoms involving chemical bond.
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18
BOND ENERGY :
The stronger chemical bond would be
formed with larger bond energy
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19
U
rAB : Bond Length
rAB
EAB
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20
21
G = H - TS
The Degree of
Disorder of the
Structure
The Strength
of Chemical Bond
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22
CHEMICAL BONDS
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23
Electrostatic
Approach
Coulombic
Forces
CHEMICA
L
BONDING
Electron
sharing
Approach
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Sharing of
electron pair
24
Electrostati
c Approach
CHEMICA
L
BONDING
Electron
Sharing
Approach
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Ionic Bond
normal
Covalent Bond
Metalic Bond
coordinatio
n
Hydrogen Bond
Inorganic Reaction Slide 02
25
BOND STRENGTH
STRONG
CHEMICAL
BONDS
WEAK
CHEMICAL
BONDS
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LARGE
BOND
ENERGY
SMALL
BOND
ENERGY
~
~
LOW
INTERNA
L
ENERGY
LOW
ENTHALP
HIGH
INTERNA
L
ENERGY
HIGH
ENTHALP
ENTHALP
Y
26
ENTROPY
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27
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28
ENTROPY
EXPERIMENT
P, V, T
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P, V, T
29
MORE ORDRED
LESS DISORDRED
LOWER ENTROPY
LESS ORDERED
MORE
DISORDERED
HIGHER
ENTROPY
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30
Boltzmanns Concept of
Entropy :
S = ln
The Degree of
Disorder
Entropy
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31
Thank You
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32