forces
SUMMARY
CHEMICAL BOND
Highlight:
Covalent bond
Ionic bond
Metallic bond
CONCEPTS
Valence electron
Lewis dot formula
Electronegativity
Polar, non polar bond
Polarity
Dipole, dipole moment
SUMMARY
CONCEPTS
How to draw a LEWIS
structure
Octet rule
VSEPR (Valence-Shell
Electron Pair Repulsion)
theory
Determine the molecular
shape by VSEPR
THIS WEEK
HIGHLIGHT:
Intermolecular
forces: forces that
hold molecules
together
Different types of
forces between the
molecules
CONCEPTS
Types of intermolecular
forces
Bond length
Van der Waals force
Polarity vs. polarisability
H-bond
Dissolution of compounds.
Answer these questions?
1. Why can we dissolve NaCl in water (H2O)?
2. Why can we not do that to Gold?
It is the intermolecular forces that determine the
physical properties.
Molecular Forces
Intramolecular forces (bonding forces) exist within
each molecule and influence the chemical properties
of the substance.
Example:
Cl2 (Chloride)
Molecular Forces
Intramolecular forces are relatively strong
because they involve larger charges that are
closer together.
Intermolecular forces are relatively weak
because they typically involve smaller charges
that are farther apart.
All forces (attractive and repulsive
interaction) between atoms arise from
electrostatic forces
INTRAmolecular Forces
INTERmolecular Forces
INTERmolecular Forces
1. Ion-dipole
2. Dipole-Dipole
3. Ion-induced Dipole
4. Dipole-Induced Dipole
5. Dispersion (London)
1.ION-DIPOLE
Ion-Dipole Forces
FORCES
Ion-Dipole Forces
2.DIPOE-DIPOLE
Dipole-Dipole FORCES
Dipole-Dipole
Solid
Liquid
> bp of nonpolar
Why?
The greater the dipole moment
the greater the dipole-dipole forces
between the molecules
the more energy it takes to separate
them.
Hydrogen Bond
Hydrogen Bond
How to draw a hydrogen bond
Hydrogen Bond:
Draw the H-bond of these compounds?.
Hydrogen Bond
SUMMARY
of INTERMOLECULAR
FORCES
DIPOE-DIPOLE
FORCES
SUMMARY
of INTERMOLECULAR
FORCES
DIPOE-DIPOLE
FORCES
WHY do you think IM Forces also are as
important as Intramolecular forces?
BECAUSE, some physical properties of
substances that are affected by the
strength of the intermolecular force?
Boiling point
Vapour pressure
Heat of vaporisation
Surface tension
Viscosity
SUMMARY
of INTERMOLECULAR
FORCES
DIPOE-DIPOLE
FORCES
BOILING POINT
Dispersions forces
between the
molecules increase
with higher molecular
weigh higher
boiling point
SUMMARY
of INTERMOLECULAR
FORCES
DIPOE-DIPOLE
FORCES
BOILING POINT: Effect of H-BONDS?
SUMMARY
of FORCES
DIPOE-DIPOLE
FORCES