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Molecular
formula
Name
CH3OH
methanol
C2H5OH
ethanol
C3H7OH
propanol
C4H9OH
butanol
C5H11OH
pentanol
C6H13OH
hexanol
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Naming alcohols
Alcohols with three or more carbon atoms display
positional isomerism. The number of the carbon to which
the hydroxyl groups is attached is written before the ol.
propan-1-ol
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propan-2-ol
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Industrial fermentation
Industrially, sugar cane,
molasses (a product of refining
sugar cane) or starch (from
potatoes or corn) can be used
for fermentation.
The product is a mixture of
water and about 15% ethanol
by volume. No more alcohol is
produced because the yeast is
denatured by the alcohol.
Distillation can be used to
remove most of the water
from the ethanol.
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Synthesis of aldehydes
mixture of
alcohol,
dilute sulfuric
acid and
potassium
dichromate(VI)
heat
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water in
aldehyde
ice
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propanone
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Esterification
Esterification involves refluxing a carboxylic acid and an
alcohol with a concentrated sulfuric acid catalyst.
R1COOH + R2OH R1COOR2 + H2O
The names of esters have
two parts: the first is an
alkyl group (from the
alcohol) and the second is
a carboxylate group (from
the carboxylic acid).
from
alcohol
from
carboxylic acid
Oxidation of alcohols
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ethene gas
aluminium
oxide
water
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Combustion of alcohols
Alcohols undergo complete combustion to form carbon
dioxide and water.
CH3CH2OH + 3O2 2CO2 + 3H2O
Denatured alcohol is ethanol that has been made toxic and
undrinkable by the addition of other chemical additives.
A traditional additive was methanol, which formed
methylated spirits (meths): 90% ethanol and 10% methanol.
Denatured alcohol is a useful portable fuel (e.g. for camping
stoves) as, unlike LPG, it does not need to be transported in
heavy, specialized containers. It is also used as a solvent.
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Alcohol reactions
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Glossary
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Multiple-choice quiz
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