Anda di halaman 1dari 48

Assignment 1 Presentation

CHEMICAL PLANT DESIGN

PRELIMINARY DESIGN OF
POTASSIUM CHLORIDE
PRODUCTION FROM
OIL PALM EMPTY FRUIT
BUNCHES ASHES

GROUP 26
Amirah Amatullah
(1206262071)
Farisa Imansari

(1206212426)

Nurhayati
(1206246616)
Osvaldo Sahat

(1206247796)

Shella

(1206238721)

BIOPROCESS ENGINEeRING /DEPARTMENT OF chemical ENGINEERING


/faculty of engineering UNIVERSITas indonesia

Outline
CHAPTER I
Background
Literature overview
Raw Material Analysis
Market and Production Capacity
Analysis
Plant Location Analysis
CHAPTER III
Mass Balance
Energy Balance

CHAPTER II
Process Selection
Process Description
Block Flow Diagram
Process Flow Diagram

CHAPTER IV
Conclusion

Chapter

{ Background }
Indonesia
Currently
Oil
palm empty
the
is the
oilfruit
largest
palmbunch
empty
producer
usually
ash
fruit
known
and
bunch
used
exporter
toby
ash
have
the
just
of
high
CPO
used
palm
potassium
oil worldwide.
levels.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


EMPTY FRUIT BUNCHES ASHES group 26

{ Literature overview }
Properties of potassium chloride

Chemical formula

KCl

Molar mass

74.5513 gmol1

Appearance

white crystalline solid

Odor

odorless

Density

1.984 g/cm3

Melting point

770C (1,420F; 1,040K)

Boiling point

1,420C (2,590F; 1,690K)

Solubility in water

281g/L (0C)
344g/L (20C)
567g/L (100C)

Solubility

soluble inglycerol,alkalies
slightly soluble inalcohol,
insoluble inether

Acidity(pKa)

~7

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


EMPTY FRUIT BUNCHES ASHES group 26

(Source: various

Properties
Potassium chloride is a colorless or white, cubic, crystalline compound
that closely resembles sod

{ Raw material analysis }


The main raw material of potassium chloride plant is oil palm empty fruit bunch
ash, which often used as fertilizer. Oil palm empty fruit bunch ash has high
potassium levels. The chemical composition of oil palm empty fruit bunch ash is:
(Source: Nurhayati Abdullah and Fauziah Sulaiman, 2013)

The ash composition of the oil palm empty fruit bunch

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


EMPTY FRUIT BUNCHES ASHES group 26

{ Raw material analysis }


Availability and potential of oil palm empty fruit bunch ash can be seen from the
CPO plant production capacity data. Here is palm oil production data from 2007
until 2015:
Palm oil production and export

2007

2008

2009

2010

2011

2012

2013

2014

2015

Production
(million metric
tons)
Export
(million metric
tons)
Export
(in USD billion)

16.8

19.2

19.4

21.8

23.5

26.5

27.0

31.0

31.5

n.a

14.2

15.5

15.6

16.5

18.1

21.2

20.0

19.5

n.a

15.6

10.0

16.4

20.2

21.6

19.0

18.4

(Source : Food and Agriculture Organization of the United Nations, Indonesian Palm Oil Producers
Association (Gapki) and Indonesian Ministry of Agriculture, 2015)

The CPO industry will obtain oil palm fruit empty bunch waste around 1.2-1.4
tons for each ton CPO production
PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM
EMPTY FRUIT BUNCHES ASHES group 26

{ Market and Production Capacity Analysis }


KCl is currently produced from
three major production regions;
Canada, Russia,
and Belarus
(together account 60% of global
production)
Global potash consumption is
currently 60 million tons, and
expected to grow to 70 million
tons by 2020 and 80 million tons
by 2025 according to Fertecon
Forecast of global KCl deliveries to 2017
According to CRU, 91 percent of all
Source: (CRU, 2012)
KCl used in fertilizers
Together, the U.S., Brazil, China and India represent about two-thirds of world potash
consumption

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


EMPTY FRUIT BUNCHES ASHES group 26

{ Market and Production Capacity Analysis }

In this
For
The
market
analysis
share
wewe
will
only
usetake
the 2%
global demand of potassium chloride data as our reference to determine the capacit

Market analysis of potassium chloride

Parameter
Global demand of potassium chloride in Southeast
Asia, 2015
Global demand of potassium chloride for nonfertilizer
Global demand of potassium chloride for industrial
Market share
Production capacity for Southeast Asia
Production capacity of our plant (Just to meet the
demand of 4 countries)
Production capacity / day

Quantity

Unit

Source

6 million

Tons/year

CRU

540000

Tons/year

CRU

54000
2%
1080

Tons/year
%
Tons/year

K+S Group
Assumption
Calculation

390

Tons/year

Calculation

1,2

Tons/day

Assumption: 330
work day

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


EMPTY FRUIT BUNCHES ASHES group 26

{ Plant Location Analysis }

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


10
EMPTY FRUIT BUNCHES ASHES group 26

{ Plant Location Analysis }

(Source: Googlemaps.com, 2015)

We decided to built our plant beside PT Agronusa Investama in Sambas, West


Kalimantan, which has the production capacity of up to 60 tons/day CPO

Place of Sambas, near Malaysia, Singapore, and Brunei Darussalam

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


11
EMPTY FRUIT BUNCHES ASHES group 26

{ Plant Location Analysis }


is
near
from
the
the
harbor
source
raw material,
TheItClose
advantages
to of
build
potassium chloride plant near PT.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


12
EMPTY FRUIT BUNCHES ASHES group 26

Chapter

II

Process Selection

Neutralization

Material

Purification

Equipment

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


14
EMPTY FRUIT BUNCHES ASHES group 26

{ Neutralization }
Neutralization is used to separate Potassium from the other logam ,
such as calcium and magnessium to form potassium chloride (KCl)
Neutralization reactions involve the reaction of an acid with a base (hydroxide).
This separation using precipitation method, where strong acids reacted with salts
of strong acids so the solution not dissolve

1 .NaCl + K + KCl + Na+

2. HCl + K+ KCl + H+

15 FROM OIL PALM


PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION

{ Material Selection }
Ksp

HCl + K+ KCl + H+

Reactivity

Lattice
enthalpy

HCl selected because Ksp values


of HCl is higher than NaCl, so
neutralization will work faster when
using HCl solution.

Potassium is more reactive than the


sodium, the potassium is easier
ionizing and become soluble so that
it will not happen precipitation
reaction.

Lattice enthalpy NaCl > Lattice


enthalpy KCl, so K+ ion tends to
be more soluble in concentrated

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


16
EMPTY FRUIT BUNCHES ASHES group 26

Table Comparison between sodium chloride and


hydrochloride acid for neutralization

Parameter

Percentage

Time needed during the


process

NaCl

HCl

Rating

Scoring

Rating

Scoring

15%

0.3

0.75

CAPEX and OPEX

25%

1.25

0.75

Solubility

25%

0.75

1.25

Energy needed for


neutralization process

10%

0.2

0.4

11

2.5

18

3.15

TOTAL

65%

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


17
EMPTY FRUIT BUNCHES ASHES group 26

{ Purification }
There are two general purification process to separate
potassium and other ions.

Mixing
Mixing boiling
boiling water
water

Evaporation
Evaporation

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


18
EMPTY FRUIT BUNCHES ASHES group 26

{ Equipment Selection }
Mixing boiling water
The energy thermal of boiling water
came from boiler.
The type of boiler used is thermal liquid
heater
The most common heat sources are gas
and oil fuels, and electricity.
But, thermal fluids typically do not
transfer heat as well as water, serious
containment problems with thermal
fluids at high temperatures, including
corrosion, erosion, and freezing.
The cost production of this process is
expensive

Evaporation

The energy of evaporator using


steam.
The purity of the evaporator has a
higher purity level than mixing boiling
water up to 96.5%,
Heat energy from the evaporator only
from steam
Evaporator no need to use distilled
water in the process.
Capital cost evaporator is smaller than
the mixing boiling water from the
energy, utility, and equipment.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


19
EMPTY FRUIT BUNCHES ASHES group 26

{ Table Comparison between mixing boiling water and


evaporation for purification }
Evaporator

Mixing Boiling Water

Parameter

Percentag
e

Rating

Scoring

Rating

Scoring

Purity

25%

1.25

0.75

Energy
requirement

25%

1.25

0.75

Utility for water

25%

1.25

0.5

CAPEX and OPEX

25%

1.25

0.75

TOTAL

25%

11

2.5

18

1.5

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


20
EMPTY FRUIT BUNCHES ASHES group 26

{ Storage of OPFEB Ashes }


Main Raw Material: Ash from oil palm fruit empty fruit
bunches

Silo Tank: A vessel or a container which is specifically


functioned to safe raw materials in bulk.

Silo Tank

It enables an easy and significant way of raw


materials storing.
It might increase the production capacity.
It can provide a higher quality of raw materials since
it is highly impenetrable by pollutants.
It provides a cleaner working environment because
the raw materials used is measured and transferred
to the next equipment process automatically
through a safe and enclosed tube.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


21
EMPTY FRUIT BUNCHES ASHES group 26

{ Solid-Liquid Separation }
Leaching: an operation where the two
phases involved, solid and liquid, are in
intimate contact. The solutes are able to
diffuse from the solid to the liquid phase,
causing a separation of the components
originated in the solid.
Water leaching: construed as the
removal of water soluble and ionexchangeable inorganic constituents from
solid substrate with water. It is an
inexpensive
method
to
decrease
inorganic constituents in the biomass
content.

Except KCl, there would still be some other


constituents
dissolved.
Counter-current
leaching is applied in this leaching process to
increase the potassium chloride concentration
in the leaching liquor.

Countercurrent Leaching. (A) Launder; (B) Rake; (C) Pump

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


22
EMPTY FRUIT BUNCHES ASHES group 26

{ Solid-Liquid Separation }
PROCESS OPERATION CONDITIONS
Ratio of the liquid and solid fed to the unit 10:1
Stirring speed 550 rad/min
Time 30 minutes
Temperature 35oC
Pressure 1 bar
Inlet per day 7 tons of ashes, 70 tons of water
Liquid out 70.7161 tons/day
Solid out 6.2839 tons/day

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


23
EMPTY FRUIT BUNCHES ASHES group 26

{ Neutralization with Hydrochloric Acid }


The liquid containing potassium that is generated from water leaching is
transferred to a batch reactor vessel where it is subjected with hydrochloric
acid to form a neutralization reaction.
Objective: to precipitate potassium chloride by
reacting potassium ion from the leached ashes
with hydrochloric acid.
The reaction between potassium and hydrochloric
acid has the lowest Ksp value compared to the
other compounds if reacted with said acid.
Since it has the lowest Ksp value, potassium
chloride is more likely to precipitate first
before the other precipitation that can occur
(calcium chloride or magnesium chloride).

Batch Reactor Illustration

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


24
EMPTY FRUIT BUNCHES ASHES group 26

{ Neutralization with Hydrochloric Acid }


PROCESS OPERATION CONDITIONS
Temperature 27oC
Pressure 1 bar of
Time 1 hour
Inlet per day 70.7161 feed, 1.26817 HCl
Outlet 71.98427 tons/day

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


25
EMPTY FRUIT BUNCHES ASHES group 26

{ Filtration }
Filtration: the process of separating suspended solid matter from a liquid, by
causing the latter to pass through the pores of some substance called a filter. The
liquid that passes through the filter is called the filtrated.

Objective: the removal of the residual liquid that wets the potassium chloride
produced after the neutralization process. The liquid from wet potassium chloride
formed from the neutralization process is full of Calcium and Magnesium ions which
could affect the purity of potassium chloride needed.
Microfiltration: a common form of
physical filtration process where a
contaminated fluid is flown through an
exclusively
specific
pore-sized
membrane to separate the solid and
suspended particles from process liquid.

Doesnt need additional cleaning chemicals, generates


high flow throughput and dry concentrate
Needs low operation costs
Uses pressure less than 4 bar
Fully automatic
Constructed from stainless steel
Provides a process as sterile as possible.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


26
EMPTY FRUIT BUNCHES ASHES group 26

{ Filtration }
PROCESS OPERATION CONDITIONS

Time 30 minutes
Temperature 27oC
Pressure 1 bar
Membrane size 0.1 m
Feed Inlet 71.98427 tons/day
Filtrate 63.75 tons/day
Concentrate 8.24 tons/day

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


27
EMPTY FRUIT BUNCHES ASHES group 26

{ Evaporation }
Falling
film
evaporator
is
constructed with vertical shell-andtube heat exchanger, with a laterally
or
concentrically
arranged
centrifugal separator.

Typical Falling Film Evaporator


Configuration

Objective: to produce a more moistureless final


product.
Evaporation: the process by which
changes from a liquid to a gas or vapor.

water

Provides a higher product quality due to the gentle


evaporation and extremely short residence times in
the falling film evaporator.
Caters high energy efficiency, due to the multipleeffect arrangement or heating by thermal or
mechanical vapor recompressor.
Requires simple process control and automation.
Reacts quickly to changes in energy supply, vacuum,
feed quantities, concentrations, etc. (Important for a
uniform final concentrate).

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


28
EMPTY FRUIT BUNCHES ASHES group 26

{ Evaporation }
PROCESS OPERATION CONDITIONS

Temperature 95oC
Time 30 minutes
Pressure 1 bar
Feed is heated in advance with a heater until it reaches 95oC.
Requires a steam generator
Feed inlet 8.246 tons/day
Gas out 7.071 tons/day
Solid out 1.165 tons/day

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


29
EMPTY FRUIT BUNCHES ASHES group 26

{ Crystallization }
Crystallization: chemical solidliquid separation technique, where mass transfer of a solute
from the liquid solution to a pure solid crystalline phase occurs; the formation of solid crystal
precipitating from a solution, melt or more rarely deposited directly from a gas.

Objective: to form potassium chloride with more pure and more uniform-sized.

Draft-Tube Crystallizer with DirectContact Cooling

Draft-tube (DT) crystallizer uses direct-contact


cooling, evaporation, or adiabatic evaporative
cooling to generate supersaturation.
It provides a mixed suspension as the active volume
for relieving the supersaturation.
This type of crystallizer employs internal magma
recirculation to control supersaturation generation.
It usually provides a mechanism for classified
product removal.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


30
EMPTY FRUIT BUNCHES ASHES group 26

{ Crystallization }
PROCESS OPERATION CONDITIONS

Temperature 18oC
Pressure 1 bar
Time 30 minutes
Feed inlet 1.165 tons/day
Solid Outlet 1.165 tons/day
Requires a chiller for the cooled water as cooling agent
Feed is cooled in advance with a cooler until it reaches 18oC.

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


31
EMPTY FRUIT BUNCHES ASHES group 26

{ Block Flow Diagram }


Water

EPOFB
Ashes

Storage

EPOFB
Ashes

Leaching

Leached
Liquid

Leaching Residual

HCl

Neutralization
Mineral Residue

Steam
KCl (Wet)

Microfiltration

KCl Cake

Evaporation

KCl (Dry)

Crystallization

Residue
KCl

Packaging

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


32
EMPTY FRUIT BUNCHES ASHES group 26

{ Process Flow Diagram }

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


33
EMPTY FRUIT BUNCHES ASHES group 26

Chapter

III

{ Mass balance }
EPOFB Ash Input
Stream
(Ton/day)
Component
Outpu
Input
t
Ash
7
7
(Biomass)
Water
-
K+
Ca2+
Mg2+
HCl
KCl
Total
7
7
PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM
35
EMPTY FRUIT BUNCHES ASHES group 26

{ Mass balance }
Mass Balance of Leaching Process
Componen
Solid
t
In
Ash
(Biomass)
Water
K+
Ca2+
Mg2+
HCl
KCl
Total

Stream (Ton/day)
Liquid Liquid
Solid
In
Out
Out

6.23

-
7

70
-
70

70
0.603
0.100
0.013
-70.72

0
0
0
0
--
6.23

Mass Balance of Acid Base


Neutralization Process
Componen
t
Ash
(Biomass)
Water
K+
Ca2+
Mg2+
HCl
KCl
Total

Stream (Ton/day)
HCl
Input
Output
37%
-

70
0.603
0.100
0.013
70.72

0.706
0.563
-
1.27

70.71
0
0.100
0.013
0
1.16
71.98

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


36
EMPTY FRUIT BUNCHES ASHES group 26

{ Mass balance }
Mass Balance of Microfiltration Process Mass Balance of Evaporation
Process
Stream (Ton/day)
Stream (Ton/day)
Componen
t

Feed

Filtrate

Concentrat
e

Ash
(Biomass)
Water

70.71

63.63

7.070

K+

Ca2+

0.100

0.100

Mg2+

0.013

0.013

HCl

KCl

1.165

1.165

Total

71.98

63.75

8.236

Componen
t
Ash
(Biomass)
Water
K+
Ca2+
Mg2+
HCl
KCl
Total

Feed

Vapor

Liquor

7.070
0
0
0
0
1.165
8.236

7.070
0
0
0
0

7.070

0
0
0
0
0
1.165
1.165

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


37
EMPTY FRUIT BUNCHES ASHES group 26

{ Mass balance }
Mass Balance of Crystallization ProcessMass Balance of Filling Process
Componen
t
Ash
(Biomass)
Water
K+
Ca2+
Mg2+
HCl
KCl
Total

Stream (Ton/day)
Feed

Vapor Product

1.165
1.165

0
0

1.165
1.165

Componen
t
Ash
(Biomass)
Water
K+
Ca2+
Mg2+
HCl
KCl
Total

Stream (Ton/day)
Input

Output

1.165
1.165

1.165
1.165

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


38
EMPTY FRUIT BUNCHES ASHES group 26

{ Energy balance }
Energy Balance of Water Leaching Process
Input (kJ)
Ash
Water
K+
Ca2+
Mg2+
Total

205800
10265500
10471300

Output (kJ)
Ash
Water
K+
Ca2+
Mg2+
Total

184746.66
10265500
11391.03
2207.205
488.775
10464333.67

Heat Loss
(kJ)

6966.33

Energy Balance of Neutralization Process


Input (kJ)
Water
K+
Ca2+
Mg2+
HCl
37%
KCl
Total

Output (kJ)

7998918.532
8787.366
1702.701
377.055

Water
K+
Ca2+
Mg2+

7998918.532
1702.701
377.055

47699.17794

HCl 37%

8057484.832

KCl
Total

21709.96749
8022708.256

Heat Loss
(kJ)

34776.58

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


39
EMPTY FRUIT BUNCHES ASHES group 26

{ Energy balance }
Energy Balance of Filtration Process
Input (kJ)
Water
Ca2+
Mg2+
KCl
Total

7998918.5
1702.701
377.055
21709.967
8022708.26

Output (kJ)
Water
Ca2+
Mg2+
KCl
Total

7998918.53
1702.701
377.055
21709.967
8022708.26

Heat Loss
(kJ)

0.00

Energy Balance of Evaporation Process


Input (kJ)
Water
Vapor
KCl
Total

2814434
76386.92
2890821

Output (kJ)
Water
Vapor
KCl
Total

1266160
76386.92
1342547

Heat Loss
(kJ)
1548275

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


40
EMPTY FRUIT BUNCHES ASHES group 26

{ Energy balance }
Energy Balance of Evaporation Process
Input (kJ)
Wate
r
Vapor
KCl
Total

Output (kJ)

2814434

Water

76386.92
2890821

Vapor
KCl
Total

1266160
76386.92
1342547

Heat Loss
(kJ)
1548275

Energy Balance of Crystallization Process


Input (kJ)
KCl

14473.31

Output (kJ)
KCl

Heat Loss
(kJ)

14473.31
0

Total

14473.31

Total

14473.31

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


41
EMPTY FRUIT BUNCHES ASHES group 26

{ Overall Total Input and Output Energy of Raw Material


and Product }
Raw Material Input (kJ)
Material

Energy

Ashes

205800

Total

205800

Product Output (kJ)


Material

Energy

KCl

21709.967

Total

21709.967

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


42
EMPTY FRUIT BUNCHES ASHES group 26

Chapter

IV

{ conclusion }
Potassium Chloride is a useful material that can be used in many industries such as
drilling industry.
Potassium chloride can be obtained from Oil Palm Empty Fruit Bunches which is usually
useless and is considered as waste in CPO industry.
Our raw material is Oil Palm Fruit Empty Bunches (OPFEB) ashes.The availabilty of this
material in is so high Indonesia because there are so many CPO industries in Indonesia.
Our plant will be built in Sambas, West Kalimantan. The plant located in Sambas,
because of the source of material and targeted market is near from our plant location
with production capacity of KCl is around 390 ton/year
The process includes water leaching, neutralization using HCl, microfiltration,
evaporation, and crystallization.
The mass efficiency is 16.647% because to produce KCl, we need a lot of ashes
because the content of K+ in ashes is small.
The energy efficiency is 10.549%

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


44
EMPTY FRUIT BUNCHES ASHES group 26

THANK
YOU

{ References }
Abdullah, N., Sulaiman, F., & Gerhauser, H. (2011). Characterisation of oil palm empty fruit bunches for fuel application. Journal of
Physical Science, 22(1), 124.
Berge, M. (2012). Global Fertilizer Supply / Demand Five-Year Market Outlook ( 2012-2017 ).
Cargill (n.d). Potassium Chloride 101: The Basics. https://cargillsaltinperspective.com/potassium-chloride-101-the-basics/ [16
September 2015, 18.22]
CDMI Consulting (2014). Potensi Bisnis dan Pelaku Utama Industri CPO di Indonesia, 2014-2017. Jakarta: PT Central Data Mediatama
Indonesia
Elemental Minerals Limited (2015). About Potash. http://www.elementalminerals.com/Projects/Potash [17 September 2015, 21.00]
Furmaski, P. (1995). THERMAL AND RADIATIVE PROPERTIES OF ASH DEPOSITS ON HEAT TRANSFER SURFACES OF BOILERS, (79).
Indonesia Investments (2015). Palm Oil Industry Update Indonesia: CPO Production at 40 Million by 2020?. http://www.indonesiainvestments.com/news/todays-headlines/palm-oil-industry-update-indonesia-cpo-production-at-40-million-by-2020/item5822 [14
September 2015, 20.09]
Kcl, C., Potassium, M., Cl, M., Sea, D., Lake, G. S., & Union, F. S. (1997a). 1 . Production and use of potassium chloride
Luo, Z., Yang, J., Ma, H., Liu, M., & Ma, X. (2015). Recovery of magnesium and potassium from biotite by sulfuric acid leaching and
alkali precipitation with ammonia. Hydrometallurgy, 157, 188193. http://doi.org/10.1016/j.hydromet.2015.08.01

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


46
EMPTY FRUIT BUNCHES ASHES group 26

{ References }
Mutu Certification International (2012). Assessment Report of PT. Agronusa Investama. Indonesia: Mutuagung Lestari
Nelson, B. P. N., Rhebergen, T., Berthelsen, S., Webb, M. J., Banabas, M., Oberthr, T., Lubis, A. (2002). Soil Acidification under Oil
Palm: Rates and Effects on Yield. Slides, 2225.
Nurhayati Abdullah and Fauziah Sulaiman (2013). The Properties of Washed Empty Friut Bunches of Oil Palm. Journal of Physical
Science, Vol. 24(2), 117-137, 2013
Peng, C., Zhang, F., & Guo, Z. (2009). Separation and Recovery of Potassium Chloride from Sintering Dust of Ironmaking Works. ISIJ
International, 49(5), 735742. http://doi.org/10.2355/isijinternational.49.735
PotashCorp (2014). Overview of PotashCorp and Its Industry. http://www.potashcorp.com/overview/nutrients [11 September 2015,
15.00]
Udoetok, I. (2012). Characterization of ash made from oil palm empty fruit bunches (oefb). International Journal of Environmental
Sciences, 3(1), 518524. http://doi.org/10.6088/ijes.2012030131033
Yanni

Sudiyani
(2015).
Info
Maksi:
Potensi
Tinggi
Bio
Etanol
Generasi
http://www.infosawit.com/mobile/index.php/news/detail/info-maksi---potensi-tinggi--bio-etanol-generasi-kedua [14
2015, 21.10]

Kedua.
September

Yoeswono, Triyono, and Iqmal Tahir (2008). Pemanfaatan Limbah Abu Tandan Kosong Sawit Sebagai Katalis Basa pada Pembautan
Biodiesel dari Minyak Sawit. Jurnal Manusia dan Lingkungan, Vol. 14, No. 2, Juli 2007; 55-62

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


47
EMPTY FRUIT BUNCHES ASHES group 26

{ DISCUSSION }

PRELIMINARY DESIGN OF POTASSIUM CHLORIDE PRODUCTION FROM OIL PALM


48
EMPTY FRUIT BUNCHES ASHES group 26

Anda mungkin juga menyukai