DISTRIBUTION OF
WATER
ON
EARTH SURFACE
WATER DISTRIBUTION
OCEAN
WATER
ICE CAP
AND
GLACIERS
FRESH
WATER
GROUND
WATER
97.23%
2.14%
.01%
.61%
OCEAN WATER
ICE CAPS AND
GLACIERS
FRESH WATER
OTHERS
GROUND WATER
Sources of water
1. Rain Water
2. Ground Water
3. Surface Water
Main Sources
Rain Water:
caused due to evap. of surface
water & subsequent preciptation.
Most purest form
Dissolves Impurities (SPM, CO2,
SO2, NO2) from atmosphere
Can be stored in underground
reservoir tanks
Ground Water:
Largest available source of fresh
water.
Form of rain water falling on earth.
Generally pure because it undergoes
natural filtration during the
percolation through soil pores.
Less likely to be contaminated by
BACTERIA but contains dissolved
salts.
To obtain in large quantity tube wells
Surface Water:
The water that flows over the surface of earth &
is Directly available for use.
It includes
1.River water
2.Lake water
3.Sea water
8
Boilers
Paper Industry
Textile Industry
Sugar Industry
Laundry
Dyeing
Cooking
Boilers:
Water used in boilers should
be free from hardness because
hard water causes sludge and
scale formation which prevent
efficient heat transfer.
Dissolved solids may cause
caustic embrittlement .
(material of boiler becomes
brittle due to accumulation of
caustic substances)
10
Paper Industry:
11
Textile Industry:
Should be free from hardness as
hard water precipitates basic
dyes and decreases the solubility
of acidic dyes.
Presence of Fe, Mn salts causes
uneven dyeing.
Should be free from turbidity,
colour imparting impurities and
organic matter.
12
Sugar Industry:
Should be free from sulphates,
carbonates and nitrates otherwise
crystallization and refining of sugar
becomes difficult and sugar
obtained is deliquescent (absorb
moisture from air).
Laundries:
Hard water increases consumption
of soaps.
Cooking:
Hard water increases fuel
13
Dissolved
Impurities
Suspended
Colloidal
Microorganism
14
Dissolved Impurities
a) Salts:
)Carbonates, Bicarbonates, Sulphates and
chlorides of Ca, Mg, Fe, Na, K.
b) Gases: CO2, O2, N2, H2S.
Suspended impurities
Inorganic-Clay, sand.
Organic- Vegetable, animal matter,
phytoplanktons and zooplanktons.
Colloidal Impurities: Products from organic
waste, finely divided silica and clay etc.
Microorganisms: Bacteria, Fungi, Algae etc.
15
HARDNESS OF WATER
It is the soap consuming capacity of water sample.
It is the property of water which prevents the
lathering of soap.
It is due to the presence of salts of Ca and Mg and
other heavy metal ions like Al3+ , Fe3+ , Mn2+ in water.
Hard water with soap produce white precipitates.
Types of Water
Hard Water
Soft Water
Degree of Hardness
Here CaCO3 is used as reference standard i.e. hardness
of different samples of varying composition is
expressed in terms of equivalents of CaCO3 .
Reason for using CaCO3 as a reference standard:a) It is the most insoluble salt that can be precipitated
in water treatment.
b) Molecular weight of CaCO3 is 100 so calculations
becomes easy.
Equivalents of CaCO3
Mass of
substance
producing
hardness in
mg/l or ppm
Mol. Wt of CaCO3
Mol. Wt. of
hardness
producing
substance
ppm:- ppm is the parts of CaCO3 equivalent hardness present per 106
parts of water.
i.e. 1ppm = 1part CaCO3 equivalent hardness in 106 parts of water.
Degree French ( Fr) :- It is the parts of CaCO3 equivalent hardness present per
105 parts of water.
i.e. 1 Fr = 1part CaCO3 equivalent hardness in 10 5 parts of water.
Degree Clark ( Cl) :- It is the parts of CaCO3 equivalent hardness present per
70000 parts of water.
OR
In english system it is expressed in terms of grains of CaCO 3 equivalent
hardness present per gallon (10 lb) of water.
i.e. 1 ( Cl) = 1part CaCO3 equivalent hardness in 70000 parts of water.
OR
1 grain of CaCO3 equivalent hardness present per gallon of water.
1ppm = 0.1 ( Fr) = 0.07 ( Cl) =1 mg/l
EXTERNAL TREATMENT
It means treatment of hard water before its entry into the
boiler.
This treatment prevents boiler problems arising from hard
water.
These methods are used for the removal of permanent
hardness.
Lime-Soda Process:
The basic principle of this process is to chemically convert all
the soluble hardness causing impurities into insoluble
precipitates which may be removed easily by filtration.
The soluble calcium
chemically converted
calculated amount of
CaCO3 and Mg(OH)2
filtered off.
2CaCO3 + 2H2O
2CaCO3 + Mg(OH)2 + 2H2O
MgCl2 + Ca(OH)2
CaCl2 + Na2CO3
CaCl2 + Mg(OH)2
CaCO3 + 2NaCl
MgSO4 + Ca(OH)2
CaSO4 + Na2CO3
CaSO4 + Mg(OH)2
CaCO3 + Na2SO4
NaAlO2 + 2H2O
Al2(SO4)3 + 3Ca(HCO3)2
NaOH + Al(OH)3
2Al(OH)3 + 3CaSO4+ 6CO2
METHOD OF TREATMENT:
Raw water and calculated quantities of
chemicals (Lime + soda + Coagulants) are fed
from the top into the inner vertical circular
chamber, fitted with a vertical rotating shaft
carrying a number of paddles.
As the raw water and chemicals flow down,
there is a vigorous stirring and continuous
mixing, whereby softening of water takes place.
The softened water comes into the outer coaxial chamber, where it rises upwards.
ZEOLITE PROCESS
Zeolites are a group of
Hydrated crystalline aluminosilicates[Na2O . Al2O3 xSiO2
yH2O] Found in certain volcanic rocks.
Tetrahydrally coordinated aluminium and silicon atoms form
AlO4 and SiO4 tetrahedral groups.
Synthetic Zeolites
Synthetic Zeolites are porous and possess gel
structure. Sodium zeolites are generally used for
softening of water and are simply represented as
Na2Z, where Z stands for insoluble zeolite.
These can be prepared by heating together
sod. Carbonate (Na2CO3 ), alumina (Al2O3)
and silica (SiO2)
Synthetic zeolites have higher ion
exchange capacity than Natural Zeolites
Anion
Exchanger
REGENERATION:
When cation exchanger losses capacity of producing H+ ions
and anion exchanger losses capacity of producing OH- ions,
they are said to be exhausted. The exhausted cation exchanger
is regenerated by passing it through dilute sulphuric acid or
hydrochloric acid.
R2Ca + 2H+
2RH + Ca+2
The exhausted anion exchanger is regenerated by passing a
dilute solution of NaOH.
R2SO4-2 + 2OH2ROH + SO4-2
Internal Treatment
Of
Removing Hardness
Carbonate
Conditionin
g
Calgon
Conditionin
g
Phosphate
conditionin
g
Colloidal conditioing:
Chemical used kerosene, agar
agar
These chemicals get adsorbed over
the scale forming precipitates and
forming non-sticky precipitates which
can be easily removed by blow down
operation.
Scale
precipitates
Non-sticky
Phosphate conditioning
Chemical used: sodium phosphate
It reacts with the hardness producing impurities of water and form easily
removable sludge of calcium and magnesium phosphate, which can be
removed by blow down operation.
3CaCl2 + 2Na3PO4
Ca3(PO4)2 + 6NaCl
Insoluble salts
- Acidic water
Carbonate Conditioning
Chemical used: Sodium carbonate
Sodium carbonate reacts with CaSO4 to form sludge of CaCO3
which can be removed by blow down operation.
CaSO4 + Na2CO3
CaCO3
Na2SO4
Calgon Conditioning
Chemical used: Sodium hexa metaphosphate Na2[Na4(PO3)6]
Brand name is Calgon.
Calgon react with Ca salt and produces soluble complex.
Na2[Na4(PO3)6]
2Na+ + [Na4(PO3)6]2
2CaSO4 + [Na4(PO3)6]2
[Ca2(PO3)6]2 + 2Na2SO4
Soluble
complex
BOILER PROBLEMS
If hard water is used in the boiler a no. of difficulties
may arise which are listed below:A. Scale and Sludge formation
B. Priming and Foaming
C. Caustic Embrittlement
D. Boiler Corrosion
Sludge
Sludge is actually formed by substances
which have greater solubility in the hot
water than in cold water.
e.g. MgCO3, MgCl2, CaCl2, MgSO4 etc.
It is formed at that position of the
boiler , where flow of water is slow and
relatively colder parts of the boiler.
Disadvantages of sludge:
a. It is a poor conductor of heat and
hence lot of time and fuel is
needed.
b. It disturbs the functioning of the
boiler. It settles in the regions of
poor water circulation (such as pipe
connection, plug opening) and may
lead to the choking of pipe.
Scales
It is hard, sticky deposit on inner surface of
boiler.
Formation of scale is due to:1. Decomposition of Ca(HCO3)2 present in water
Ca(HCO3)2
Soft scale is formed in low pressure boilers. But in high pressure boilers, CaCO 3 is soluble
in water.
CaCO3 + H2O
Ca(OH)2 + CO2
Soluble
2. Deposition of CaSO4 :.
It is soluble in the cold water, in the hot
water it
gets ppted as hard scale.
.
It is the main cause of scale formation in
high pressure boilers.
3. Hydrolysis of magnesium salts :MgCl2 + 2H2O
Mg(OH)2 + 2HCl
soft scale
4. Presence of Silica (SiO2) :Silica react with Ca and Mg present in hard water to form
Calcium silicate and Magnesium silicate. These silicates
stick to the inner walls of the boiler.
Removal of scale
a) Using wire brush and scraching the scale.
b) Thermal shocks can be given.
c) Chemicals:
Prevention:
By controlling rapid change in steaming velocities.
The proper design of boiler.
By blowing off sludge or scale time to time.
C.
Caustic Embrittlement
Conc.
NaOH
Dil.
NaOH
Iron
present
at boiler
walls
Anode
Cathode
Dissolution of anodic part takes place.
D. Boiler Corrosion
This leads to the deterioration of the boiler body by chemical
or electrochemical attack by its environment. The main
reason for it are:1. Dissolved O2 (D.O):- Water has 8ml/litre dissolved
oxygen which attack the boiler body as rusting.
2Fe + 2H2O + O2
2Fe(OH)2 + O2
2[Fe2O3.2H2O]
Rust
Removal: i) DO can be removed by adding Sod. Sulphite
(Na2SO3) or Hydrazine (N2H4) or Sod. Sulphide (Na2S)
because all these consume O2.
2Na2SO3 + O2
Na2SO4
N2H4 + O2
N2 + 2H2O
Na2S + 2O2
Na2SO4
2. Dissolved CO2 :
CO2 react with water to form carbonic acid as :CO2 + H2O
H2CO3
Carbonic acid
Removal of CO2
i) By adding ammonia: - It absorb CO2
2NH4OH + CO2
(NH4)2CO3 + H2O
3.Generation of Acids from dissolved salts :Water has dissolved salts which on reaction with water produced
acid as:MgCl2 + 2H2O
Mg(OH)2 + 2HCl
This acid react with boiler bodys iron in a chain reaction to produce
HCl again.
Fe + 2HCl
FeCl2 + H2
FeCl2 + 2H2O
Fe(OH)2 + 2HCl
So, the presence of small amount of MgCl 2 may cause corrosion to
a large extent.
Removal:- Mineral acid can be removed by adding alkali.
Water
for
Domestic
Use
of suspended impurities
3. Filtration
4. Sterilization/Disinfection
5m
Coagulation
Sedimentation removes only 70-75% of the
suspended impurities. So, Sedimentation
with coagulants are required that coagulate
small particles into larger particles, which
settle out of the water as sediment.
Coagulant Used1. Potash Alum [K2SO4 Al2(SO4)3. .24H2O]
2. Sodium aluminate [NaAlO2 ]
3. Ferrous sulphate [Fe2SO4 .7H2O]
Coagulant works in two ways:1. Coagulant reacts with bicarbonates and form form bulky
gelatinous precipitates of Al(OH)3 called flock.
Al2 (SO4)3 + 3Ca(HCO3)2
2Al(OH)3 + 3CaSO4 + 6CO2
Fe SO4 + Mg(HCO3)2
2Fe(OH)2 + MgCO3 + CO2 + H2O
NaAlO2 + H2O
NaOH + Al(OH)3
(Flocculant)
These flocks catch the suspended particles from water and
form bigger flocks and settle down easily.
2. The suspended particles of silica and clay carries ve charge.
So , they repel each other and do not settle down. Then we
add alum . The Al3+ ions of alum neutralize the ve charge
and settle down easily.
Filtration
Sand Filter
Pressure Filter
Sterilization or Disinfection
The process of removing bacteria from water is called
disinfection. The chemicals used for this method are
called disinfectants.
There are mainly five methods
1. Boiling
2. Chlorination
3. Ozonisation
4. U.V rays
5. Aeration
1. Boiling
Boiling water for 10-15 minutes. This kills all the disease
producing bacteria.
But this method is expensive for large amount of water
(municipal water supply) .
2. Chlorination
Chlorinatio
n
By Bleaching
Powder
By Chlorine
gas
By
Chloramines
By Bleaching Powder
About 1 Kg bleaching powder (CaOCl2) is added to
about 1000 litres of water and the reaction occur
as:Here HOCl and [O] are powerful germicides.
CaOCl2 + H2O
Ca(OH)2 + Cl2
Cl2 + H2O
HOCl + HCl
HOCl
HCl + [O]
Germs + [O]
Germs are oxidised
Advantages:
Economical
Little space for storage
It is stable and does not deteriorate
It does not release any salt (Ca, Mg).
Disadvantages:
Excess of chlorine leads to unpleasant taste and
smell to water.
It also have irritating effect on mucous membranes.
Therefore, treated water should not contain more than
0.1-0.2 ppm of free Cl2 .
By using Chloramines
Chlorine and ammonia are mixed in the ratio 2:1 by volume to
produce chloramines
Cl2 + NH3
ClNH2 + HCl
Chloramine (ClNH2 ) reacts with water and give reactions as:ClNH2 + 2H2O
HOCl + NH4OH
HOCl
HCl + [O]
Germs + [O]
Germs are oxidised
Advantages:
1. It removes irritating smell due to
excess of Chlorine
2. It imparts good taste to water.
Break
Point Chlorination
Zone-I :- In the starting all the added chlorine is used up in the oxidation
of reducing agents (NH3, H2S) .
Zone-II :- With further increase in the amount of chlorine, the amount
of residual chlorine increases and formation of chloro-organic
compounds and chloramines takes place.
HOCl + NH3
NH2Cl (Monochloroamine) + H2O
HOCl + NH2Cl
NHCl2 (Dichloroamine) + H2O
HOCl + NHCl 2
NCl3 (Nitrogen trichloride) + H2O
Chloramines formed above act as chlorine reserves
Zone-III :- At this concentration the destruction of chloro-organic
compounds and chloramines takes place, till a minima in the curve is
obtained (Break point Chlorination).
Zone-IV :- Here added chlorine is not used in any reaction called free
residual chlorine. It kills all the bacteria present in water.
3. Ozonisation
By passing silent electric
discharge through cold and dry
O2 , O3 is produced which is an
excellent disinfectant.
3O2
2O3
ozone
4. By U.V. rays
Ultra violet rays are very effective in killing all
types of bacteria. For this purpose U.V. lamps are
used. This method is widely used for the
disinfection of swimming pools because chemicals
may harm to the skin of swimmers.
5.By Aeration
Here water is forced under pressure through a
perforated pipe . As water spray into air , it comes
into contact with oxygen and UV rays. This kills the
bacteria and oxidize organic matters.
Quality of water
Fresh Water-Dissolved salts less
than
1000ppm
Brackish Water- Dissolved salts
1000-3500ppm
Sea Water-Dissolved salts more than
3500ppm
Desalination of Brackish
Water
The water which contain excess salt
concentration is called Brackish water.
The process of removal of dissolved
salts from saline water water is called
desalination or desalting.
The main purpose is to make the
water suitable for drinking, irrigation,
industrial uses.
1.Distillation
2.Freezing
3.Electrodialysis
4.Reverse Osmosis
3. Electrodialysis: