in Oil Field
By:
Alok Dwivedi
AEE(P)
Corrosion & Scale Management Deparatment-IOGPT
Objective
Concept of Scale in oil field
Identifying the scale
Causes of Scale Deposition
Commonly Encountered form of
Scale
Mechanism of scale deposition
Chemistry of CaCO3 Scale
Chemistry of SrSO4 Scale
Various Scale Removal
Techniques
Information Analysis
Plugged Wells
Deposit
Organic Deposit
Prediction:
PVT
Asphaltenes Solubility
Inorganic DepositCharacterization
Paraffins
Scale
Asphaltenes
Sand
% Asphaltene
(Each 2 Months)
% Asphaltene
Reduction
SCALE
Scale is a deposit that plugs or fouls
equipments & systems.
Inorganic mineral constituents of water
that precipitate to form hard, adhere
deposits.
Scale begins to form when the state of
any natural fluid is perturbed in such a
way that solubility limit for one or more
5
SCALE
Scale formation is a dynamic process
and changes in magnitude during the
life cycle of a field as the composition of
produced water changes.
Problems due to
Scale
Restricts Flow
Reduce Production
Reduce Injectivity
Catastrophic Failure
Can Be Radioactive
7
Types of Waters
Formation Water: Water present in hydrocarbonproducing formation or related rock layers and is found
in the pore spaces of rock.
Produced Water: Formation or condensed waters, or
both, in various combinations and salinities that are
received topside with the oil and gas being produced.
Water Chemistry
Produced/Formation water is analyzed to
determine the concentration of following species
(In General)
Major Ions:
SO42-, OH-
s:
Dissolved
Gases:
O2,Dependent
CO2, H2S, CH
4, C2H6 etc..
igrams
per Litre:
Temp.
Unit
m: Temp. Independent Unit = 1 mg of solute in 1000 g of sol
ppm=(mg/L)/(Sp.Gr)
Concept of Solubility
Product
The equilibrium constants for saturated solution and solid
formation (precipitate) are called solubility product, Ksp. For
unsaturated and supersaturated solutions, the system is not at
equilibrium, and ion products, Qsp, which have the same expression
as Ksp is used.
Equilibrium Expression for Ksp and Qsp
[Li+]2
Diagnosing Scale
Scale formation can be predicted from water
chemistry and system physical conditions.
Diagnosing Scale
Diagnosing Scale
Scale In
tubing
Well
stimulat
ions not
effectiv
e
Predictio
n from
water
chemist
ry
Evidence
of
Producti
on
Decline
Well or
field
history
Diagnosing Scale
Types Of Scales
Types of Inorganic Scales:
Water Soluble
Deposits
Acid Soluble
Deposits
Acid Insoluble
Deposits
Salt
Calcium
Carbonate
Calcium Sulfate
Calcium
Chloride
Dolomite
Barium Sulfate
Chemical
Deposits
Iron Sulfide
Strontium
Sulfate
Iron Oxide
Iron Carbonate
15
Scale
Identification
Start
Organ
ic
Yes
Floats
in
Water
No
Solubl
e in
H2O
Yes
FeS
(Probably)
No
Soluble
in
Na4ED
TA
Yes
No
Solubl
e in
hot
HCl
No
Soluble
in HCl
Yes
NaCl
(Probably)
Yes
Yes
Odor of
rotten
egg
No
Iron Oxide
SrSO4
CaSO4
BaSO4
Magneti
c
Magnetite
(Fe3O4)
Yes
CaCO3
FeCO3
MgCO3
Cause of Scale
Deposition
Scales are formed by change in water chemistry
causing super saturation
Causes for Scale
Deposition
Change in
pH,
Temperat
ure
Pressure
etc.
Mixing
Incompati
ble
Waters
Water
Evaporati
on
Flashing
Poor or
No
Inhibitor
Treatmen
t
17
Scale Mechanism
Scale Mechanism
Chemistry of
Scale Formation
Reactions involved
Effect of CO2
CO2 + H2O
H2CO3
H2CO3
H+ + HCO3HCO3H+ + CO3- -
Chemistry of
Scale Formation
The Equilibrium will shift to
right if:
An increase in temperature
Decrease in pressure
Loss of dissolved CO2
An increase in pH
Parameters Affecting
Carbonate Scaling
Parameters Affecting
Carbonate Scaling
Contd
Effect of CO2
pH
of
water
increases
with
decrease in CO2 concentration
Decrease in CO2 partial pressure
gas over water results in CaCO3
precipitation.
Partial
Pressure
=
Pressure*Mole Fraction
Total
23
Parameters Affecting
Carbonate Scaling
Contd
of Operating Temperature
Parameters Affecting
Carbonate Scaling
Contd
25
Parameters Affecting
Carbonate Scaling
Contd
Effect of pH
Parameters Affecting
Carbonate Scaling
Contd
Effect of TDS
Solubility of CaCO3 increases
27
with increase in salt content.
In Summary
CaCO3 precipitation increases as
SrSO4
Occurs as Mineral
Celestine or Celestite
Poorly soluble in water
( 1 part in 8,800 part of water)
Formation
Water
Sea Water
Sodium
31,275
10,890
Potassium
654
460
Magnesium
379
1368
Barium
269
Strontium
771
Sulfate
2960
Chloride
60,412
19,766
Calcium
5038
428
Software/Empirical
Tech. to predict Scaling
Link
Scale Management
Change/Optimize Process Parameters
Prevent deposition by using scaleinhibitors etc
Allow scale to form, but periodically
remove it.
Use pretreatments that remove
dissolved & suspended solids.
Combating Scale
Combating Scale
Combating Sulphate Scales.
Scale Inhibitors
Inorganic Polyphosphates
Organic phosphate esters
Organic phosphonates
Organic polymers
phosphonates,
polyacrylic acids (PAA)
phosphinopolycarboxylic acids (PCA) and
polyvinylsulphonic acids (PVS).
How do Antiscalants
Work
How do Antiscalants
Work
Antiscalants
Mechanisms
Popular Scale
Inhibitors
Scale Inhibitors
An ideal Scale Inhibitor should have
following properties
Effective scale control at low inhibitor
concentration
Compatibility with sea water &
formation water
High thermal stability
Low toxicity & high biodegradability
Low Cost
Scale Removal
Sequestration using Co-ordinate complex
Co-ordination
Complex
A co-ordinate complex is the product of Lewis
acid-base reaction in which neutral molecules
or anions (Ligands) bonds to a central metal
atom by coordinate covalent bonds.
Ligands are Lewis base.
Metal atoms/ions are Lewis acids.
Coordination complexes are distinct chemical
species: Their properties and behaviour are
different from the metal atom/ion and Ligands
from which they are composed.
Typical examples: [Ag(NH3)2]+ , [Zn(CN)4]2etc.
EDTA
DTPA
DTPA , Diethylene triamine pentaacetic acid.
A Polyamino carboxylic acid
8-active metal-complexing sites, octadentate
ligand
Chelating agent
Used to sequester metal ions, Ba++, Sr++
Oxallic acid can be added as a synergists
Srskill
Srskill
Effect of Oxallic Acid additive
Srskill
IOGPT developed & Patented Recepie,
Srkill is an effective and fast way to
remove SrSO4 scales.
DTPA+KOH+Oxallic acid at a pH>12
Implemented in many wells of MH
Asset.
Increased liquid production
Minimize tubing intervention
Minimize the production loss
Increased safety
Any Questions???
hbti03.alok@gmail.com
Thank You