1 ) Calculate the frequency and wave number of radiation with wavelength 480 nm.

2 ) Find the quantum numbers of the excited state of electrons in He+ ion which on
transition to ground state and first excited state emit two photons of wavelengths. 30.4
nm and 108.5 nm respectively. (RH = 1.09678 107 m1).
3) Estimate the wavelength of second line in Balmer series.
4) A spectral line in the spectrum of H-atom has a wave number of 82200 cm 1 . What
transition is responsible for this radiation? (Rydberg constant RH=1.096 107 m-1).
5) Calculate the wavelength of light radiation that would be emitted, when an electron
in the fourth Bohrs orbit of He+ ion falls to the second Bohrs orbit. To what transition
does this light radiation correspond in the H-atom ?
6 ) A photon of wavelength 300 nm is absorbed by a gas and then reemitted as two photons.
One photon is red with wavelength of 760 nm. The wave number of the second photon will be
(a) 2.02 106 m-1 (b) 3.02 106 m-1 (c) 1.02 106 m-1 (d) 2.2 106 m-1

7 ) The radius of hydrogen atom in its ground state is 5.3 10 -11 m. After collision with an
electron it is found to have a radius of 21.2 10-11m. The principal quantum number of the final
state of the atom is
(a) 2 (b) 3 (c) 4 (d) 5
8) Which element has a hydrogen like spectrum whose lines have wavelength one fourth of
atomic hydrogen?
(a) He+ (b) Li2+ (c) Be3+ (d) B4+
9) In hydrogen like sample two different types of photons A and B are produced by electronic
transition. Photon B has its wavelength in the infrared region if photon A has more energy than
B, then the photon A may belong to the region
(a) ultraviolet (b) visible (c) infrared (d) none
10) A hydrogen like atom in ground state absorbs n photons having the same energy and it
emits exactly n photons when electronic transition takes place. Then the energy of the
absorbed photon may be
(a) 91.8 eV (b) 40.8 eV (c) 48.4 eV (d) 54.4 eV