Phosphoric Acid
Process Selection/Narrative/Evaluation
Market Feasibility Study
Group 2
Balana, James
Barallas, Jomed
Carlos, Ralph
de Asis, Suzanne
Fajilan, Krizzanne
Langas, Jan Carlo
Saladaga, Maureen
Phosphoric Acid
Historical Demand
Projected Demand for 10 Years
PROCESS 1
Manufacture of Phosphoric Acid
through Acid Hydrolysis
Swine Bones
The availability of this raw material is based on the production data
of swine in the Philippines which produces a swine bone wastes
product of about 11.4% of a given amount of swine supplied. The
swine production is widely available in every region of the country. Out
of the total swine supply, 29% is being consumed by meat industry.
Swine bone wastes will be collected from San Miguel Pure foods
Company Inc. being the pioneer manufacturer of meat products in the
country that holds the 51% of the total process meat products supplied
across the country.
the corresponding swine bones produced from the average annual
swine supplied in San Miguel Pure foods Company Inc. amount to 31
892 MT.
Sulfuric Acid
There are a number of manufacturing plants of sulfuric acid in the
Philippines. One is Chemphil Manufacturing Corporation. Based on UN
Comtrade, the import and export of sulfuric acid have decreased in
the past year (UN Comtrade, 2015):
Total of almost 3 000 MT of Sulfuric Acid are in the Philippine Trading
market.
Reactions Involved
Acidulation Rxn:
Ca10(PO4)6(OH)2+ 10 H2SO4 + 18 H2O 6 H3PO4 + 10
CaSO42H2O
Number Of Equipment
Materials Cost
12
TOTAL
Ball Mill
Screener
Grinder
Rotary Kiln
Water Cooler
DissolutionTank
Acid Reactor
Filter Press
Evaporator
Washing Tank
Raw
Swine Bones
8.22/kg
Sulfuric Acid
11.23/kg
Product Yield
Wet process phosphoric acid normally contains 26 to 30 percent P2O5.
In most cases, the acid must be further concentrated to meet phosphate
feed material specifications for fertilizer production. Depending on the
types of fertilizer to be produced, phosphoric acid is usually
concentrated to 40 to 55 percent P2O5 by using 2 or 3 vacuum
evaporators (EnvironmentalProtectionAgency).
By-product
The production of Phosphoric Acid via Wet Process has 1 by-product,
namely, gypsum (EssentialChemicalIndustry, 2013).
Process Capability
known to be the most economical way to produce
Phosphoric Acids mainly because 1 reactor and 1
evaporator is only needed;
energy consumption is low and operating temperatures
are low.
It is also known to be environmental friendly compared to
other processes such as Blast and Electric Furnaces.
By-product, gypsum, which can also be sold and add
profit to the company (Patel, Lecture 21: Phosphoric Acid)
PROCESS 2
Manufacture of Phosphoric Acid via
Blast furnace
Import
30,000,000
Export
20,000,000
10,000,000
0
2006 2008 2010 2012 2014 2016
YEAR
Silica Sand
There are certain companies that manufacture silica sand
here in the Philippines, one of them is JFMF Retail &
Trading located at Lapu-lapu City. Graphical representation
of import and export
is as follows: (UN Comtrade)
200,000,000
180,000,000
160,000,000
140,000,000
120,000,000
Import
80,000,000
Export
60,000,000
40,000,000
20,000,000
0
2006
2008
2010
YEAR
2012
2014
2016
Powder Coke
. The main importer and supplier here in the
Philippines is India Phil Minerals & Gen, Trade, Inc.
located at Binondo, Manila. China is the major
country the imports the Silica sand. Graphical
representation of the import of powder coke is as
follows:
70,000,000
60,000,000
50,000,000
40,000,000
WEIGHT (KG)
30,000,000
Import
20,000,000
10,000,000
0
2006 2008 2010 2012 2014 2016
YEAR
Reactions Involved
Phosphorus pentoxide, P2O5, is being produced.
(The Essential Chemical Industry Online, 2013)
2P + 5CO + 5O2 P2O5 + 5CO2
The second process is the conversion of P2O5 to
Phosphoric acid by hydration.
P2O5 + 3H2O 2H3PO4
Number Of Equipment
RawQuantity
Materials Cost
Equipment
Raw Material
Blast Furnace
Dust Collector
Phosphate
rock
Silica sand
Boiler
Powder coke
Php 4,500
Hydrator
Php 22,050
Blast Stove
Charcoal
Briquette
Briquetic Press
Precipitator
Compressor
TOTAL
Php 1,575
Product Yield
75% to 85%P2O5. (Walton, 1993)
By-product
Carbon Monoxide and Carbon Dioxide
Process Capability
Phosporic Acid produced via thermal process is
highly concentrated and contains fewer to almost
Process Usage
Process was used by the Victor Chemical works
in 1929 to 1938, now Stauffer Chemical Company.
The plant was located at Nashville, Tennessee
(Gilmour, 2014)
PROCESS 3
Manufacture of Phosphoric Acid via
Electric Furnace
Import
30,000,000
Export
20,000,000
10,000,000
0
2006 2008 2010 2012 2014 2016
YEAR
Silica Sand
There are certain companies that manufacture silica sand
here in the Philippines, one of them is JFMF Retail &
Trading located at Lapu-lapu City. Graphical representation
of import and export
is as follows: (UN Comtrade)
200,000,000
180,000,000
160,000,000
140,000,000
120,000,000
Import
80,000,000
Export
60,000,000
40,000,000
20,000,000
0
2006 2008 2010 2012 2014 2016
YEAR
Powder Coke
. The main importer and supplier here in the
Philippines is India Phil Minerals & Gen, Trade, Inc.
located at Binondo, Manila. China is the major
country the imports the Silica sand. Graphical
representation of the import of powder coke is as
follows:
70,000,000
60,000,000
50,000,000
40,000,000
WEIGHT (KG)
30,000,000
Import
20,000,000
10,000,000
0
2006 2008 2010 2012 2014 2016
YEAR
Reactions Involved
Ca3(PO4)2 + 3SiO2 + 5C 2P + 5CO + 3CaSiO3
2P+5CO+5O2 P2O5 + 5CO2
P 2O 5 +
3H2O 2H3PO4
Number Of Equipment
Raw
Materials Cost
Quantity
1
1
1
1
1
1
1
1
1
1
1
11
Equipment
Roll
Compactor
Electric Furnace
Breaker
Screen
Grate Calciner
Rotary Kiln
Flourine Scrubber
Cooler
Dust Separator
Phosphorus Sump
Phosphorus
Condenser
Total
Raw material
Cost (Php)
Phosphate rock
4950 /ton
Silica sand
1575/ton
Powder coke
4500/ton
TOTAL cost
11025
Product Yield
87-92%. (Patel, Lecture 21: Phosphoric Acid)
By-product
-Carbon Monoxide
Process Capability
The electric current that is supplied to the
furnace through carbon or graphite electrodes
fuses the rock and silica, and the carbon in the
coke reduces the phosphate. (Center, 1998)
Process Usage
Tennessee Valley Authority (TVA), FMC,
Monsanto, Occidental Chemical to produce
phosphoric acid. (Center, 1998)
DEMAND
ANALYSIS
Historical Demand of
Phosphoric Acid
Historical Demand of
Phosphoric Acid
An average of
12.02% increase
in demand
annually.
Annual increase in
percent will be the
same in the future
although increase in
percent will decrease
with time.
Rate of increase in
the projected values
is constant; however,
the amount of change
keeps on increasing.
The
change
in
percentage
of
the
data for the year is
decreasing.
SUPPLY ANALYSIS
Historical Supply of
Phosphoric Acid
Local Supplier:
An average of
10.33% increase
in supply annually.
Annual increase in
percent will be the
same in the future
although increase in
percent will decrease
with time.
Rate of increase in
the projected values
is constant; however,
the amount of change
keeps on increasing.
The
change
in
percentage
of
the
data for the year is
decreasing.
Conclusion of Historical
Demand and Supply
Conclusion of Projected
Demand and Supply
Conclusion of Projected
Demand and Supply
Final Conclusion
The projected supply and demand in the next ten
years show a constant increase. Therefore
marketing of phosphoric is plausible and
sustainable.
PROCESS
EVALUATION