Chapter 15
Acid-Base Titration
and pH
Sections 1 & 2
Aqueous Solutions and the Concept of pH
Determining pH and Titrations
Chapter 15 Sec 2 Determini
ng pH & Titration p. 511-5
Determining pH
and
Titration
Chapter 15 Vocabulary
Self Ionization
pH
pOH
Acid-base indicator
Transition interval
Titration
Equivalence Point
Endpoint
Standard
Solution
Primary
Standard
Standardization
p. 511
Indicators
Acid-base indicators- compounds
whose colors are sensitive to pH
HIn
H+ + In-
Indicators
Transition Interval the pH range over
which an indicator changes color
p. 513
p. 513
p. 513
p. 512
pH of Common Materials
pH Meter
Determines the pH of a solution by
measuring the voltage between two
electrodes that are placed in a
solution
10
11
Titration
The controlled addition and
measurement of the amount of a
solution
of known concentration
required to react completely with a
measured amount of a solution
of unknown concentration.
A quantitative lab procedure to
determine concentration or amount.
Chapter 15 Sec 2 Determini
ng pH & Titration p. 511-5
12
Doing a Titration
p. 518
13
Doing a Titration
p. 518
14
Doing a Titration
p. 518
15
Doing a Titration
p. 519
16
Doing a Titration
p. 519
17
Doing a Titration
p. 519
18
Titration Video
Glencoe Disc 3
19
Titration
Equivalence point the point at which
the two solutions in a titration are
chemically equivalent.
M
=
MOLESbase = MOLESacid
mol/L
mol =
If the coefficients are all 1 MxL
then the
mole ratio has no effect so
M B x LB = MA x LA
Chapter 15 Sec 2 Determini
ng pH & Titration p. 511-5
20
STANDAR
D
SOLUTION
ANALYTE
Titration
IN BURETTE
TAmL of base
2
A
D
5 known
0.2M
concentration
of base
mL of acid
1 unknown
0
X
M concentration
IN FLASK
of acid
Chapter 15 Sec 2 Determini
ng pH & Titration p. 511-5
21
Equivalence Points
Titration Combination
STRONG acid + STRONG
base
STRONG acid + WEAK base
WEAK
Equivalen
ce Point
pH=7
pH<7
pH>7
22
23
Titration Curve
p. 517
24
Titration Curve
p. 517
25
Standardization
Standard solution a solution that
contains the precisely known
concentration of a solute.
The standard solution has be
standardized (determined its
concentration) with a primary
standard (a solution with a known
concentration).
26
1.
2.
3.
M=
mol/L
MOLESbase = MOLESacid
mol
=
Calculate the moles of the substance
MxL and
in which you know the molarity
concentration.
Use the mole ratio to convert these
moles to moles of the other
substance.
Now that you have moles of the
other substance divide by liters of
Chapter 15to
Sec get
2 Determini
27
that substance
molarity.
ng pH & Titration p. 511-5
28
29
(aq)
BaCl2 (aq) +
x
2 mole HCl
1 moles Ba(OH)2
MOLE RATIO
(coefficients)
30
31
32
Ch 15 Sec 2 Homework
Titration Calculations Worksheet
34