BAHAN TEKNIK 1
KOROSI
Korosi : Peristiwa
perusakan atau
degradasi material
logam akibat
bereaksi secara
kimia dengan
lingkungan
Fenomena Oksidasi
Tingkat keasaman
Laju Korosi
Galvanis series
Macam-macam Korosi
Macam-macam Korosi
Macam-macam Korosi
Pencegahan Korosi
Degradasi Polimer
Degradasi Elastomer
TANK LOCATION:
Careful consideration should be given to locating the bulk tank. Tank bottom elevation is
important.
Ideally, the best location is at the same elevation as the delivery vehicle and within 200
feet of the delivery location.
An area that is heated and has potable water and drains (for washdown) available is
best.
If caustic soda is to be maintained and stored at 50% a source of heat (electrical or
steam) must be also considered
TANK SIZING:
Storage Tanks should be sized for 1.5 times the maximum expected delivery size. This
extra capacity is required due to the swelling experinenced on delivery.
For tank truck deliveries of ~4000 USgallons, a 6000-7000 USgallon tank is acceptable.
For larger capacity, a 12,000 gallon tank is a good size.
For railcar deliveries,
A balance must be struck between delivery that is too frequent and the cost of
continuous heating of caustic.
For most users of 50% caustic, a four to 14 day periodic delivery schedule is attractive.
MATERIALS OF CONSTRUCTION:
Bulk Storage tanks of 50% caustic can be made from mild steel (if iron "pick-up" is not a
concern to the process). Stainless steel and other alloys can also be used.
Tanks of mild steel with internal/external epoxy coatings have been used in cases where
iron pick-up is unacceptable.
Tanks made from mild steel must not exceed 125F to prevent caustic corrosion cracking.
Polypropylene can also be used for smaller day tanks. FRP is not recommended without
PE/PVC or PTFE linings.
TANK DESIGN:
-- General
Tanks should be specified, designed and constructed to API-650, API-620 or
ASME Section VIII.
Because tanks in caustic soda service will have a specific gravity greater
than 1.0, the UL-142 code is not acceptable.
For 50% caustic storage, a design specific gravity of 1.6 is recommended
Because caustic soda is difficult to pump when the temperature gets to
~60F, Storage tanks must be heated or kept in a warm room.
Electric pad heaters set at 80F are easy to control and maintain. A shell
mounted temperature gauge is useful.
A periodic cleaning schedule of 2 to 4 years is suggested.
Calcium/magnesium hydroxide and other compounds will collect as
sediment inside the tank.
Overflow:
Bulk caustic storage tanks should have a weir type overflow that is seperate from
the vent.
If possible, the overflow should flow to a sump location that is obvious to the person
filling the tank.
-- Outlet (Pump Suction):
The tank outlet should be no smaller than 3" NPS
For vertical tanks, the centerline of the pump suction nozzle should be located no
closer than 12 inches from the tank bottom.
This is to ensure that "iron rich" caustic and any debris stays in the tank
For horizontal tanks, the pump suction nozzle should protrude 3 inches into the tank
-- Level Indication:
Gauge glasses are not recommended due to clogging and difficulty keeping warm.
Ultrasonic level detection has been widely used
Some companies install a small gauge hatch on the tank roof for manual gauging
Alarms:
A high level alarm (float switch) mounted on the tank shell at the 95% level
is suggested.
Some companies tie the level alarm to automated closure of a control valve
on the inlet
-- Manways:
As a minimum, a roof mounted 24 inch manway is suggested. Tanks larger
than 10,000 gallons should consider both a roof and shell manway.
Consider a tank mounted ladder to the tank roof for manway/tank roof
access
-- Insulation:
Two inches of polyurethane or cellular glass is acceptable for keeping the
tank below 125F
PIPING SYSTEMS:
Piping systems should be seamless carbon steel, but stainless steel and other materials
are acceptable, but more expensive.
The entire piping system should be sloped to be free draining.
Consider adding valved air-purge connections to promote easy cleaning
-- Flanges and pipe joints:
Butt welded and socket welded joints are recommended. Flanges and uniouns should be
kept to a minimum.
Flange guards (splash shield inserts) should be used.
PUMPS:
Centrifugal pumps with packing or mechanical seals are often used.
Pumps with packing will become a maintenance item as the packing will allow buildup
of NaOH at the shaft.
Mag-drive pumps have also been used.
Rotary pumps are an acceptable alternative.
Pump motor sizing must consider the higher specific gravity of the liquid.
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- OTHER CONSIDERATIONS:
1)Document the tank thickness upon installation for use later
2)Ensure that all personnel protective equipment is used during offloading and
maintenance.
3)Safety showers,eyewash stations and potable water supply are recommended at
the offload location and at transfer/metering pumps.